1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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7 References 131 (a) J. Perdew, Phys. Rev. B 1986, 33, 8822-8824. (b) J. Perdew, Phys. Rev. B 1986, 34, 7406. (c) A. D. Becke, Phys. Rev. A 1988, 38, 3098-3100. (d) A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571-2577. 132 M. Zerner, Reviews in Computational Chemistry, Vol. 2, K. B. Lipkowitz, D. B. Boyd (Eds.), Wiley VCH, New York, 1991. 133 G. Bringmann, S. Busemann, in Natural Product Analysis: Chromatography, Spectroscopy, Biological Testing, P. Schreier, M. Herderich, H.-U. Humpf, W. Schwab (Eds.), Vieweg, Wiesbaden, 1998. 134 T. Laue, A. Plagens, Namen- und Schlagwortreaktionen der organischen Chemie, 5 th edition, Teubner Verlag, Wiesbaden, 2006. 135 G. Vargas Hernandez, Mex. Pat. Appl. 2005, 2003PA11108. 136 Spartan® 04 V100, WaveFunction Inc., www.wavefun.com. 137 (a) C. Frixa, M. F. Mahon, A. S. Thompson, M. D. Threadgill, Org. Biomol. Chem. 2003, 1, 306-317. (b) N. Malatesti, K. Smith, H. Savoie, J. Greenman, R. W. Boyle, Int. J. Oncol. 2006, 28, 1561-1569. 138 (a) H.-B. Fa, L. Zhao, X.-Q. Wang, J.-H. Yu, Y.-B. Huang, M. Yang, D.-J. Wang, Eur. J. Inorg. Chem. 2006, 21, 4355-4361. (b) R. F. Kelly, M. J. Tauber, M. R. Wasielewski, J. Am. Chem. Soc. 2006, 128, 4779-4791. 139 C. Brückner, M. O. Senge, B. Röder, E. A. Ermilov, personal communications, 2008. 140 calculated via http://pages.unibas.ch/mdpi/ecsoc/e0002/calelecg.htm based on PAULING’s electronegativity scale and “super-atom” approximations, 2008. 196
Appendix Publications Articles & Patents Appendix S. Jasinski, H. Mansour, N. Jux, “Investigations on Novel Inherently Chiral meso- Tetraphenylporphyrins“, J. Porphyrins Phthalocyanines 2006, 10, 689. B. Röder, E. Ermilov, N. Jux, S. Jasinski, “Porphyrin Derivatives and Their Use as Photosensitizers in Photodynamic Therapy”, Eur. Pat. Appl. 2007, EP 1 834 955 A1. S. Jasinski, E. A. Ermilov, N. Jux, B. Röder, “Novel Synthetic Cycloketo- Tetraphenylporphyrins”, Eur. J. Org. Chem. 2007, 7, 1075-1085. E. A. Ermilov, S. Jasinski, N. Jux, B. Röder, “Novel Cycloketo Tetraphenylporphyrins: Spectroscopic Study of Structure-Properties Relationships”, Proceedings of SPIE 2008, Vol. 7049 (Linear and Nonlinear Optics of Organic Materials VIII), 1-11. E. A. Ermilov, B. Büge, S. Jasinski, N. Jux, B. Röder, “Spectroscopic Study of NH-Tautomerism in Novel Cycloketo-Tetraphenylporphyrins”, J. Chem. Phys. 2009, 130, 134509. S. Jasinski, E. A. Ermilov, D. Götz, G. Bringmann, N. Jux, B. Röder, “Novel Bis-Cycloketo- Tetraphenylporphyrins”, in preparation. Poster Contributions & Talks S. Jasinski, N. Jux, “Inherently Chiral meso-Tetraarylporphyrin Systems”, poster contribution at the Chemistry Symposium Erlangen-Rennes, 2004, Erlangen. S. Jasinski, H. Mansour, N. Jux, “Investigations on Novel Inherently Chiral meso- Tetraphenylporphyrins“, poster contribution at the International Conference of Porphyrins and Phthalocyanines, 2006, Rome. 197
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Semi-Natural and Synthetic Chiral C
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Die vorliegende Arbeit entstand in
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Table of Contents 1 Introduction 1
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n J j-coupling (constant) with n in
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1 Introduction characteristics. For
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1 Introduction 1.1 Porphyrins - A G
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1 Introduction Especially interesti
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1 Introduction 8 [H] 4 + 4 O H O H
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1 Introduction complexes are usuall
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1 Introduction transitions as it is
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1 Introduction 1.2 Photodynamic The
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1 Introduction Certainly, Photofrin
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1 Introduction intact membranes bei
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1 Introduction components, the limi
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2 State of The Art & Aims They were
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2 State of The Art & Aims 2.2 Aim o
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3 Discussion and Results encapsulat
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3 Discussion and Results diastereot
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3 Discussion and Results 30 E ½ Re
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3 Discussion and Results irradiatio
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3 Discussion and Results 34 R 1 O N
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3 Discussion and Results 3.2.2.1.2
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3 Discussion and Results Table 4. S
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3 Discussion and Results 3.2.2.2 FR
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3 Discussion and Results 3.2.2.3 Ac
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3 Discussion and Results 3.2.3.1 IR
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3 Discussion and Results 3.2.3.2 NM
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3 Discussion and Results 3.2.3.3 Va
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3 Discussion and Results Obviously,
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3 Discussion and Results Like Figur
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3 Discussion and Results utilizatio
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3 Discussion and Results has been d
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3 Discussion and Results other TPP
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3 Discussion and Results (being sup
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3 Discussion and Results other band
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3 Discussion and Results Table 10.
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3 Discussion and Results voltammogr
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3 Discussion and Results 3.2.5 Inhe
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3 Discussion and Results effects 12
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3 Discussion and Results 74 Δθ [m
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3 Discussion and Results 3.2.6.2 10
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3 Discussion and Results vibration
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3 Discussion and Results 3.2.6.4 Sy
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3 Discussion and Results cyanomethy
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3 Discussion and Results 3.2.6.5 Co
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3 Discussion and Results phenyl sub
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3 Discussion and Results 90 5 μA -
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3 Discussion and Results 3.2.7 Appr
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3 Discussion and Results (75 eq.) w
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3 Discussion and Results 3.2.7.2 Sy
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3 Discussion and Results of rotatio
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3 Discussion and Results Thus, the
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3 Discussion and Results Time-resol
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3 Discussion and Results first redu
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3 Discussion and Results correspond
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3 Discussion and Results The remain
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3 Discussion and Results 3.2.8.1 Us
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3 Discussion and Results With all t
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3 Discussion and Results The interm
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3 Discussion and Results 116 HO 2 C
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3 Discussion and Results nitro comp
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3 Discussion and Results The effect
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3 Discussion and Results 3.2.9 Pote
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3 Discussion and Results peak at m/
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3 Discussion and Results Table 25.
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3 Discussion and Results 130
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4 Summary As the characterization d
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5 Zusammenfassung 5 Zusammenfassung
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5 Zusammenfassung Da in guten Ausbe
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6 Experimental Section UV/Vis spect
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6 Experimental Section 6.2 Studied
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6 Experimental Section 13 C NMR (10
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6 Experimental Section (cyanomethyl
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Page 196 and 197: 6 Experimental Section broad signal
Page 198 and 199: 7 References 16 H. Fischer, K. Zeil
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Page 202 and 203: 7 References 89 (a) R. C. Fuson, J.
Page 206 and 207: S. Jasinski, N. Jux, “Investigati
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1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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