1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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S. Jasinski, N. Jux, “Investigations on Novel Inherently Chiral Tetraphenylporphyrins”, poster contribution at the 2 nd Erlangen Symposium on Redox-Active Metal Complexes – Control of Reactivity via Molecular Architechture, 2006, Erlangen. S. Jasinski, “Novel Cyclo-Keto-Porphyrins – Activation of Molecular Oxygen”, talk at the colloquium of the SFB583, 2006, Erlangen. S. Jasinski, E. A. Ermilov, N. Jux, B. Röder, “Novel Cycloketo-Porphyrin Systems”, poster contribution at the Tetrapyrrole Discussion Group meeting, 2008, Dublin. S. Jasinski, “Novel Cycloketo-Porphyrin Systems – Promising Photoactive Materials”, talk at the Tetrapyrrole Discussion Group meeting, 2008, Dublin. 198
Acknowledgements (Danksagung) In this case in German: An dieser Stelle möchte von ganzem Herzen all denjenigen danken, ohne deren Hilfe und Unterstützung diese Arbeit nicht möglich gewesen wäre. Zunächst danke ich meinen Doktorvätern Prof. Dr. Andreas Hirsch und P. D. Dr. Norbert Jux für das Interesse an der Arbeit. Vor allem meinem Betreuer und Mentor P. D. Jux gilt der Dank für die umfassende Betreuung, die Unterstützung (24-7) und das entgegengebrachte Vertrauen. Ein besonderer Dank gilt auch den Kooperationspartnern, die großes Interesse und viel Initiative gezeigt haben und damit wesentlich zu den hier erzielten Ergebnissen beigetrugen: Prof. Dr. Gerhard Bringmann (Universität Würzburg; chirale HPLC & CD-Spektroskopie), Prof. Dr. Christel Marian (Universität Düsseldorf; Theroretische Chemie), Prof. Dr. Beate Röder (Humboldt-Universität zu Berlin; Photophysik) und Prof. Dr. Klaus Schomäcker (Universität Köln; Nuklearmedizin). Vor allem möchte ich Frau Prof. Röder für die konstruktiv-kreativen Gespräche und die hervorragende Zusammenarbeit über den gesamten Zeitraum und auch darüber hinaus herzlich danken. Ferner danke ich Prof. Dr. Rudi van Eldik und Prof. Dr. Ivana Ivanovic-Burmazovic für die umfangreichen Nutzungsmöglichkeiten des CV-Equipments. Ein ganz großer Dank gilt vor allem den Mitgliedern der Arbeitskreise der oben genannten Professor(inn)en. Dr. Martin Kleinschmidt (AK Marian) gilt der Dank für die high-level Rechnungen, Daniel Götz (AK Bringmann) für die extensiven HPLC-Versuche (tja, in good old Ireland war’s noch chilliger…) und Bettina Büge (AG Röder), die während ihrer Diplomarbeit wichtige Beiträge erarbeitete. Ein ganz besonderer Dank gilt Dr. Eugeny Ermilov (AG Röder), der immer mit Rat und Tat zur Seite stand und viel Energie und Kreativität in das gemeinsame Projekt investierte. Ferner möchte ich den übrigen „Berlinern“ für die nette Aufnahme und die schöne Zeit in Berlin danken, v. a. Dr. Steffen „Hacky“ Hackbarth, Lutz Jäger und Dr. Christian Litwinski. 199
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Semi-Natural and Synthetic Chiral C
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Die vorliegende Arbeit entstand in
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Table of Contents 1 Introduction 1
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n J j-coupling (constant) with n in
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1 Introduction characteristics. For
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1 Introduction 1.1 Porphyrins - A G
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1 Introduction Especially interesti
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1 Introduction 8 [H] 4 + 4 O H O H
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1 Introduction complexes are usuall
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1 Introduction transitions as it is
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1 Introduction 1.2 Photodynamic The
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1 Introduction Certainly, Photofrin
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1 Introduction intact membranes bei
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1 Introduction components, the limi
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2 State of The Art & Aims They were
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2 State of The Art & Aims 2.2 Aim o
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3 Discussion and Results encapsulat
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3 Discussion and Results diastereot
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3 Discussion and Results 30 E ½ Re
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3 Discussion and Results irradiatio
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3 Discussion and Results 34 R 1 O N
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3 Discussion and Results 3.2.2.1.2
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3 Discussion and Results Table 4. S
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3 Discussion and Results 3.2.2.2 FR
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3 Discussion and Results 3.2.2.3 Ac
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3 Discussion and Results 3.2.3.1 IR
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3 Discussion and Results 3.2.3.2 NM
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3 Discussion and Results 3.2.3.3 Va
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3 Discussion and Results Obviously,
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3 Discussion and Results Like Figur
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3 Discussion and Results utilizatio
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3 Discussion and Results has been d
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3 Discussion and Results other TPP
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3 Discussion and Results (being sup
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3 Discussion and Results other band
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3 Discussion and Results Table 10.
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3 Discussion and Results voltammogr
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3 Discussion and Results 3.2.5 Inhe
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3 Discussion and Results effects 12
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3 Discussion and Results 74 Δθ [m
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3 Discussion and Results 3.2.6.2 10
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3 Discussion and Results vibration
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3 Discussion and Results 3.2.6.4 Sy
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3 Discussion and Results cyanomethy
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3 Discussion and Results 3.2.6.5 Co
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3 Discussion and Results phenyl sub
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3 Discussion and Results 90 5 μA -
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3 Discussion and Results 3.2.7 Appr
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3 Discussion and Results (75 eq.) w
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3 Discussion and Results 3.2.7.2 Sy
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3 Discussion and Results of rotatio
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3 Discussion and Results Thus, the
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3 Discussion and Results Time-resol
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3 Discussion and Results first redu
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3 Discussion and Results correspond
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3 Discussion and Results The remain
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3 Discussion and Results 3.2.8.1 Us
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3 Discussion and Results With all t
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3 Discussion and Results The interm
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3 Discussion and Results 116 HO 2 C
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3 Discussion and Results nitro comp
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3 Discussion and Results The effect
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3 Discussion and Results 3.2.9 Pote
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3 Discussion and Results peak at m/
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3 Discussion and Results Table 25.
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3 Discussion and Results 130
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4 Summary As the characterization d
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5 Zusammenfassung 5 Zusammenfassung
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5 Zusammenfassung Da in guten Ausbe
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6 Experimental Section UV/Vis spect
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6 Experimental Section 6.2 Studied
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6 Experimental Section 13 C NMR (10
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6 Experimental Section (cyanomethyl
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6 Experimental Section 6.2.4 AB3-Ty
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Page 164 and 165: 6 Experimental Section 6.2.4.11 10
Page 166 and 167: 6 Experimental Section EA: C57H56N4
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Page 170 and 171: 6 Experimental Section 6.2.5 A2B2-T
Page 174 and 175: 6 Experimental Section 6.2.5.5 αβ
Page 176 and 177: 6 Experimental Section 6.2.5.7 αβ
Page 178 and 179: 6 Experimental Section 6.2.5.9 αα
Page 180 and 181: 6 Experimental Section 6.2.5.11 α
Page 182 and 183: 6 Experimental Section 6.2.5.13 α
Page 186 and 187: 6 Experimental Section 6.2.6 AB2C-T
Page 190 and 191: 6 Experimental Section UV/Vis (CH2C
Page 194 and 195: 6 Experimental Section UV/Vis (CH2C
Page 196 and 197: 6 Experimental Section broad signal
Page 198 and 199: 7 References 16 H. Fischer, K. Zeil
Page 200 and 201: 7 References 57 S. Schwartz, K. Abs
Page 202 and 203: 7 References 89 (a) R. C. Fuson, J.
Page 204 and 205: 7 References 131 (a) J. Perdew, Phy
Page 208 and 209: Ein großer Dank gilt auch den Ange
Page 210 and 211: Cirruculum vitae Stefan Jasinski Ge
Page 212 and 213: 204 56 57 58 59 60 61 62 63 64 65 6
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1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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