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Aluminium Design and Construction John Dwight

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Table 4.8 Nominal composition of weld filler alloys<br />

Note. * The use of these fillers may lead to corrosion problems under prolonged exposure in a hot<br />

environment<br />

Atmospheric corrosion of aluminium is by a process of pitting. Often<br />

referred to as ‘weathering’, this is radically different from the rusting<br />

of steel. Air-borne pollutants, such as sulphuric acid <strong>and</strong> sodium chloride,<br />

cause local pits to form, the depth of which may be used as a measure<br />

of the severity of the attack. In the first year, the pit depth increases<br />

relatively quickly, but with the passage of time the corrosion products<br />

effectively stifle the process. Eventually, after five years or so, further<br />

corrosion almost stops. This pattern of behaviour is illustrated in Figure<br />

4.12, which shows the likely variation of average pit depth with time for<br />

3103 sheet in an outdoor industrial location [32].<br />

The severity of pitting depends on the alloy <strong>and</strong> the environment. For<br />

a very durable alloy, such as 3103, the worst pits may have a depth after<br />

five years of roughly 0.04 mm in a rural location, 0.08 mm in an inl<strong>and</strong><br />

industrial one <strong>and</strong> something like 0.16 mm at an industrial site by the sea.<br />

The surface of weathered aluminium always looks much worse than<br />

it really is, <strong>and</strong> the immense volume of the corrosion products (some 200<br />

Figure 4.12 Pitting corrosion. Typical growth of average pit depth with time for exposed<br />

3103 sheet in an inl<strong>and</strong> industrial location (Alcan.)<br />

Copyright 1999 by Taylor & Francis Group. All Rights Reserved.

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