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Materials for engineering, 3rd Edition - (Malestrom)

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Metals and alloys 85<br />

At% Al<br />

0 10 20 30 40 50 60 70 80 90 100<br />

1500<br />

1412<br />

1400<br />

1300<br />

1200<br />

Liquid<br />

1100<br />

Temperature (°C)<br />

1000<br />

900<br />

800<br />

700<br />

600<br />

500<br />

Si<br />

Liquid + Si<br />

577<br />

Liquid + Al<br />

Al<br />

660<br />

400<br />

300<br />

Si + Al<br />

200<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Wt% Al<br />

3.9 The silicon–aluminium phase diagram.<br />

ductility. The binary Al–Si alloys are generally used where strength is not a<br />

primary consideration, e.g. pump casings and automobile engine manifolds.<br />

Copper and magnesium additions are made to enhance the strength of such<br />

alloys and more complex compositions (e.g. including nickel additions) lead<br />

to improved elevated temperature properties <strong>for</strong> such applications as piston<br />

alloys <strong>for</strong> internal combustion engines.<br />

Small additions of magnesium allow significant age-hardening of the<br />

castings through precipitation of Mg 2 Si in the aluminium matrix. Doubling<br />

of the yield strength may be achieved in this way, and such alloys find use<br />

in aircraft and automotive applications.<br />

Aluminium–copper alloys, although less easily cast than Al–Si alloys,<br />

respond well to age-hardening heat treatments. Several compositions have<br />

been developed with enhanced elevated temperature properties, <strong>for</strong> example<br />

<strong>for</strong> use as diesel engine pistons.

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