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Materials for engineering, 3rd Edition - (Malestrom)

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Metals and alloys 91<br />

Table 3.4 Typical mechanical properties of some magnesium alloys<br />

Alloy Condition Density Young’s Proof UTS Elongation<br />

(Mg m –3 ) modulus stress (MPa) (% in 50<br />

(GPa) (MPa) mm)<br />

Mg–6Al–3Zn– Sand cast ~1.8 ~45 75 180 4<br />

0.3Mn (AZ63) Peak aged 110 230 3<br />

Mg–9.5Al– Cast and ~1.83 ~45 127 239 2<br />

0.5Zn–0.3Mn peak aged<br />

(AZ91)<br />

Mg–6.5Al–1Zn– Extruded ~1.8 ~45 180 260 7<br />

0.3Mn (AZ61)<br />

At room temperature, titanium has a hexagonal crystal structure (α) and<br />

this changes to a body-centred cubic structure (β) at 882 °C, staying the<br />

same up to the melting point. There are, thus, three types of Ti alloy<br />

microstructure, namely those with α, β and mixed α/β structures.<br />

α-alloys<br />

α-alloys can be divided into three subgroups:<br />

(i) single-phase α-alloys, which owe their strength to solute hardening,<br />

(ii) near-α alloys which contain up to 2% of some β-stabilizing elements<br />

and may thus be <strong>for</strong>ged and/or heat-treated in other phase fields, and<br />

(iii) alloys which respond to conventional age-hardening treatment.<br />

Single-phase α-alloys<br />

The most widely used single-phase α material is in fact Commercially Pure<br />

(CP) titanium, which is essentially a Ti–O alloy, solution-hardened by adding<br />

a controlled amount of oxygen, which dissolves interstitially in the metal.<br />

Higher strengths are achieved by substitutional solid solution hardening, of<br />

which Ti–5Al–2.5Sn is an example.<br />

Near-α alloys<br />

The near-α alloys show the greatest creep resistance above 400°C of all Ti<br />

alloys and have attractive properties <strong>for</strong> use as a compressor disc alloy in gas<br />

turbines. A typical example is Ti–6Al–5Zr–0.5Mo–0.25Si, known as IMI 685.<br />

Single-phase α- and near-α-alloys have phase diagrams of the <strong>for</strong>m shown<br />

in Fig. 3.11.<br />

Age-hardening alloys<br />

Ti–2.5Cu may be strengthened by a classical age-hardening heat-treatment,

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