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Materials for engineering, 3rd Edition - (Malestrom)

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Metals and alloys 99<br />

1100<br />

At% Zn<br />

10 20 30 40 50 60 70 80 90100<br />

1000<br />

900<br />

Liquid<br />

Temperature (°C)<br />

800<br />

700<br />

600<br />

500<br />

α<br />

520<br />

798<br />

β<br />

586<br />

ζ<br />

γ<br />

γ<br />

δ<br />

755<br />

δ<br />

ε<br />

640<br />

ε + liquid<br />

400<br />

350<br />

415<br />

300<br />

η<br />

227<br />

200<br />

189 η′<br />

186<br />

150<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Wt% Zn<br />

3.17 The Cu–Sn phase diagram.<br />

3.2.5 Lead alloys<br />

The most significant applications of lead and lead alloys are lead-acid storage<br />

batteries, and they are also widely used <strong>for</strong> building construction materials<br />

such as sheet because of their relative inertness to atmospheric attack. Lead<br />

is also finding increased application as a material <strong>for</strong> controlling sound and<br />

mechanical vibration, due to its high damping capacity.<br />

Because of its low melting point (327.5 °C), pure lead undergoes creep at<br />

room temperature, so it usually strengthened by small additions of solute.<br />

Thus, 1.5 to 3% antimony or traces of calcium are often present in the plates<br />

of car batteries, and different manufacturers may use different solutes.<br />

The important families of more concentrated alloys are the lead–tin solders<br />

(see Section 3.3.2) and lead-based bearing alloys, which may contain antimony,<br />

tin and arsenic, <strong>for</strong> use in internal combustion engines.<br />

3.2.6 Zinc alloys<br />

The main uses of zinc are as an alloying element (e.g. in copper as already<br />

discussed) and as a protective coating <strong>for</strong> steel (galvanizing). However, zinc-

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