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Materials for engineering, 3rd Edition - (Malestrom)

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Metals and alloys 101<br />

700<br />

600<br />

500<br />

660<br />

At% Zn<br />

10 20 30 40 50 60 70 80 90 100<br />

Liquid<br />

Temperature (°C)<br />

400<br />

300<br />

200<br />

α 419<br />

382<br />

351.5<br />

α′ 82.8 95<br />

275<br />

98.86<br />

β<br />

31.6<br />

78<br />

99.3<br />

100<br />

4.0<br />

0<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Wt% Zn<br />

3.19 The Al–Zn phase diagram.<br />

with zinc-rich dendrites, whereas the hypereutectic contain Al-rich dendrites.<br />

The commercial alloys contain strengthening additions of copper and<br />

magnesium, but the greatest care has to be taken to prevent excessive pickup<br />

of harmful impurity elements such as lead, cadmium, tin and iron. The<br />

alloys themselves are prepared from high-purity components, otherwise<br />

intergranular embrittlement of the castings develops over a period of time.<br />

The properties of some lead, zinc and nickel alloys are presented in<br />

Table 3.7.<br />

3.2.7 Nickel alloys<br />

Commercially pure nickel offers excellent corrosion resistance to reducing<br />

environments (in contrast to those metals and alloys which owe their resistance<br />

Table 3.7 Typical mechanical properties of some lead, nickel and zinc alloys<br />

Alloy Condition Density Young’s Yield UTS Elongation<br />

Mg m –3 modulus stress MPa (% in<br />

GPa MPa 50 mm)<br />

Lead >99.99% 11.68 16.1 – 168 –<br />

Zn–8.5Al–1Cu (ZA8) Die cast 6.3 86 290 375 6–10<br />

Ni–30Cu–1.5Fe–1Mn Hot rolled 8.83 180 230 560 45<br />

Ni–20Cr–2Ti–1.5Al Fully aged 8.19 222 780 1220 30<br />

Nimonic 80A

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