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Materials for engineering, 3rd Edition - (Malestrom)

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3<br />

Metals and alloys<br />

3.1 General strengthening mechanisms: the effect<br />

of processing<br />

The strength of a crystal may be assessed either by its resistance to cleavage,<br />

by the application of normal stresses across the cleavage plane, or by its<br />

resistance to shear under the action of shear stresses on the slip plane. It is<br />

possible to make an estimate of these strengths <strong>for</strong> ideal, or perfect crystals,<br />

but a large discrepancy is found between these values and those measured<br />

experimentally. In pure materials, real strengths are several orders of magnitude<br />

lower than their theoretical strengths – cleavage occurs due to the presence<br />

of cracks in brittle solids and shear occurs due to the presence of mobile<br />

dislocations in ductile solids. The local displacement (b) associated with a<br />

given dislocation is known as its Burgers vector.<br />

Dislocations are linear defects which are always present in technical<br />

materials, usually in the <strong>for</strong>m of a three-dimensional network. Dislocation<br />

density (ρ) is usually expressed as the length of dislocation line per unit<br />

volume of crystal or, its geometrical equivalent, the number of dislocations<br />

intersecting the unit area. In a reasonably perfect crystal, the value of ρ<br />

might be of the order 10 9 m –2 . Their number per unit length will there<strong>for</strong>e be<br />

ρ 1/2 and their average separation will be the reciprocal of this quantity,<br />

giving ~30 µm <strong>for</strong> the dislocation density considered.<br />

3.1.1 Work hardening<br />

As a crystal is de<strong>for</strong>med, dislocations multiply and the dislocation density<br />

rises. The dislocations interact elastically with each other and the average<br />

spacing of the dislocation network decreases. The shear yield strength (τ) of<br />

a crystal containing a network of dislocations of density ρ is given by:<br />

τ = αGb(ρ 1/2 ) [3.1]<br />

71

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