Materials for engineering, 3rd Edition - (Malestrom)
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Metals and alloys 95<br />
Table 3.5 Typical mechanical properties of some titanium alloys<br />
Alloy Condition Density Young’s Proof UTS Elongation<br />
(Mg m –3 ) modulus stress (MPa) (% in 50 mm)<br />
(GPa) (MPa)<br />
Commercially Annealed 4.51 ~105 540 640 24<br />
pure Ti (α)<br />
(IMI155)<br />
Ti–6Al–4V(α/β) Annealed 4.46 ~106 925 990 14<br />
(IMI318)<br />
Ti–13Mo–11Cr– Aged 4.87 ~106 1200 1280 8<br />
3Al (β)<br />
so, <strong>for</strong> a given component, a designer can select an alloy be<strong>for</strong>e deciding on<br />
the manufacturing process. We will consider this family in three groups: the<br />
grades of copper itself, then the high-copper alloys and, finally, the alloys<br />
containing larger quantities of alloying elements.<br />
Grades of copper<br />
Tough pitch copper contains residual oxygen from the refining process,<br />
including oxide particles, which makes it unsuitable <strong>for</strong> tube manufacture or<br />
<strong>for</strong> welding. Deoxidized copper is more appropriate <strong>for</strong> such applications<br />
and small additions of phosphorus or another deoxidizer is made <strong>for</strong> this<br />
purpose. If residual deoxidizer remains in solid solution, the electrical<br />
conductivity of the copper is impaired, so high conductivity copper is refined<br />
and deoxidized to a high degree of purity <strong>for</strong> use in electrical applications.<br />
Copper alloys of low solute content<br />
Arsenical copper contains up to 0.5% As, which has the effect of reducing<br />
the tendency of the metal to scale when heated and also gives a slight<br />
increase in high-temperature strength through solute hardening.<br />
Free-cutting copper contains ~0.5% Te which gives rise to the presence<br />
of second-phase particles of a telluride phase. During machining, these particles<br />
cause the swarf and chippings to break up into small fragments allowing the<br />
cutting fluid access to the interface between the workpiece and the tool. This<br />
increases tool life <strong>for</strong> a given rate of machining; sulphur-bearing alloys are<br />
also available <strong>for</strong> the same purpose.<br />
Copper–beryllium alloys are age-hardenable, as suggested by the phase<br />
diagram of Fig. 3.14. Alloys contain typically 1.9% Be and are subjected to<br />
the normal sequence of solution treatment at 800 °C, quenched and artificially<br />
aged in the range 300–320 °C to precipitate the intermetallic phase CuBe.<br />
The alloys also normally contain