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Materials for engineering, 3rd Edition - (Malestrom)

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72<br />

<strong>Materials</strong> <strong>for</strong> <strong>engineering</strong><br />

where G is the shear modulus, b the dislocation Burgers vector and α is a<br />

constant of value about 0.2.<br />

As plastic de<strong>for</strong>mation continues, there<strong>for</strong>e, the increase in dislocation<br />

density causes an increase in τ – the well-known effect of work hardening,<br />

Fig. 2.3.<br />

As a technical means of producing a strong material, work hardening can<br />

only be employed in situations where large de<strong>for</strong>mations are involved, such<br />

as in wire drawing and in the cold-rolling of sheet. This <strong>for</strong>m of hardening<br />

is lost if the material is heated, because the additional thermal energy allows<br />

the dislocations to rearrange themselves, relaxing their stress fields through<br />

processes of recovery and being annihilated by recrystallization (see below).<br />

3.1.2 Grain size strengthening<br />

Metals are usually used in polycrystalline <strong>for</strong>m and, thus, dislocations are<br />

unable to move long distances without being held up at grain boundaries.<br />

Metal grains are not uni<strong>for</strong>m in shape and size – their three-dimensional<br />

structure resembles that of a soap froth. There are two main methods of<br />

measuring the grain size:<br />

(a) the mean linear intercept method which defines the average chord length<br />

intersected by the grains on a random straight line in the planar polished<br />

and etched section, and<br />

(b) the ASTM comparative method, in which standard charts of an idealized<br />

network are compared with the microstructure. The ASTM grain size<br />

number (N) is related to n, the number of grains per square inch in the<br />

microsection observed at a magnification of 100×, by:<br />

n<br />

N = log<br />

log 2 + 1.000<br />

Thus, the smaller the average grain diameter (d ), the higher the ASTM<br />

grain size number, N.<br />

The tensile yield strength (σ y ) of polycrystals is higher the smaller the grain<br />

size, these parameters being related through the Hall–Petch equation:<br />

σ y = σ o + k y d –1/2 [3.2]<br />

where k y is a material constant and σ o is the yield stress of a single crystal<br />

of similar composition and dislocation density.<br />

The control of grain-size in crystalline materials may be achieved in<br />

several ways:<br />

From the molten state<br />

As discussed in Chapter 1, when molten metal is cast, the final grain size

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