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Materials for engineering, 3rd Edition - (Malestrom)

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Metals and alloys 79<br />

On being held up by a precipitate, a dislocation can continue in its path<br />

across the crystal in two possible ways. If the particles are very close together,<br />

the dislocation may cut through each particle, but if the particles are further<br />

apart, the dislocation may loop between the particles. During the ageing<br />

process, as the particles grow, the stress increment required to make the<br />

dislocations cut them also rises (Fig. 3.6, curve C). The increase in shear<br />

stress due to precipitate cutting, ∆τ c , is given by an equation of the <strong>for</strong>m:<br />

∆τ c = Af 1/2 r 1/2 [3.4]<br />

where r is the particle radius, f the volume fraction of precipitate, and A a<br />

material constant.<br />

As ageing proceeds, the particles gradually increase in size and, because<br />

they are fewer in number, the average spacing between the particles also<br />

increases. The stress increment to cause dislocation looping ( ∆τ l ) decreases<br />

as the inter-particle spacing increases (curve L, Fig. 3.6), depending on the<br />

precipitate size and volume fraction according to:<br />

∆τ 1 = BGbf 1/2 r –1 [3.5]<br />

where B is a constant dependent upon precipitate particle shape.<br />

As ageing continues, the measured yield stress would there<strong>for</strong>e be expected<br />

to follow the <strong>for</strong>m of the dotted curve in Fig. 3.6 and this general pattern of<br />

C<br />

∆τ<br />

L<br />

Ageing time<br />

3.6 Showing change in yield stress (∆τ) with ageing time <strong>for</strong> a<br />

precipitation-hardened alloy. Curve C is followed if the precipitates<br />

are cut by dislocations, and curve L is followed if the dislocations<br />

loop between the particles. The response is given by the dashed<br />

curve.

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