Inhaltsverzeichnis - Anorganische Chemie
Inhaltsverzeichnis - Anorganische Chemie
Inhaltsverzeichnis - Anorganische Chemie
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74<br />
Table 31: Crystal data and data collection<br />
Empirical formula Cl 10 Hg 3 N 12 S 8<br />
Formula weight 1380.87<br />
Crystal size<br />
Crystal color and habit<br />
Crystal system<br />
Space group<br />
1.00 x 0.10 x 0.01 mm<br />
orange prism<br />
Monoclinic<br />
P2(1)/n<br />
Unit cell dimensions a = 8.882(2) Å α = 90°<br />
b = 9.564(2) Å β = 95.421(4) °<br />
c = 17.112(5) Å γ = 90°<br />
Volume 1447.1(7) Å 3<br />
Z 2<br />
Density (calculated) 3.169 Mg/m 3<br />
Absorption coefficient 17.397 mm -1<br />
F(000) 1244<br />
Diffractometer used<br />
Radiation and wavelength<br />
Scan type<br />
Temperature<br />
Siemens SMART Area-detector<br />
MoKα with λ=0.71073 Å<br />
Hemisphere<br />
193(2) K<br />
2 range for data collection 4.78 to 44.92°<br />
Index ranges -9 h 9 -10 k 7 -18 l 18<br />
Reflections collected 5761<br />
Independent reflections 1738 (R int = 0.0324 )<br />
Observed reflections<br />
Absorption correction<br />
1626 (F>4σ(F))<br />
SADABS<br />
Max. and min. transmission 0.6945 and 0.4187<br />
Experimental details :<br />
1200 frames measured in phi (0-360) with chi=0 and omega=2theta=25<br />
65 frames measured in omega (15-35) with chi=280, 2thetha=29 and phi=0<br />
Crystal mounted in perfluorpolyetheroil
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