Inhaltsverzeichnis - Anorganische Chemie
Inhaltsverzeichnis - Anorganische Chemie
Inhaltsverzeichnis - Anorganische Chemie
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93<br />
Table 50 Crystal data and data collection<br />
Empirical formula C 12 H 10 Cl 1.50 Cu 0.50 P 0.50<br />
Formula weight 254.63<br />
Crystal size<br />
Crystal color and habit<br />
Crystal system<br />
Space group<br />
0.40 x 0.40 x 0.30 mm<br />
red prism<br />
Monoclinic<br />
P2(1)/n<br />
Unit cell dimensions a = 9.1639(9) Å α = 90°<br />
b = 19.275(2) Å β = 108.018(2)°<br />
c = 13.411(1) Å γ = 90°<br />
Volume 2252.7(4) Å 3<br />
Z 8<br />
Density (calculated) 1.502 Mg/m 3<br />
Absorption coefficient 1.405 mm -1<br />
F(000) 1036<br />
Diffractometer used<br />
Siemens SMART Area-detector<br />
Radiation and wavelength MoK with λ=0.71073 Å<br />
Scan type<br />
Temperature<br />
Hemisphere<br />
193(2) K<br />
2θ range for data collection 3.82 to 58.50°<br />
Index ranges -11 h 11 -24 k 24 -17 l 16<br />
Reflections collected 12855<br />
Independent reflections 4467 (R int = 0.0310 )<br />
Observed reflections<br />
Absorption correction<br />
3490 (F>4σ(F))<br />
SADABS<br />
Max. and min. transmission 0.5339 and 0.4368<br />
Experimental details :<br />
1200 frames measured in phi (0-360) with chi=0 and omega=2theta=25<br />
65 frames measured in omega (15-35) with chi=280, 2theta=29 and phi=0<br />
Crystal mounted in perfluorpolyetheroil
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