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The Davis Strait - DCE - Nationalt Center for Miljø og Energi

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glaucous gulls, great black-backed gulls, killer whales, pilot whales, Arctic<br />

fox, and polar bears). This is particularly true in relation to biomagnification<br />

of PCBs and DDT. AMAP activities have also shown a decrease in the levels<br />

of some POPs (e.g. PCBs and DDT), resulting from introduction of bans and<br />

restrictions relating to their use in other parts of the world (AMAP 2004,<br />

Muir & de Wit 2010). At the same time, however, use of new persistent pollutants,<br />

currently produced in large quantities, is on the increase (AMAP<br />

2004, Muir & de Wit 2010). <strong>The</strong>se substances have also been detected in animals<br />

from Greenland; such as the brominated flame retardants hexabromocyclododecane<br />

(HBCD) or tetrabromobisphenol (TBBPA), chemicals which<br />

are produced in high volumes. In recent years their presence has been reported<br />

in sediment and biota from the marine environment (Frederiksen et<br />

al. 2007), with concentrations of HBCDs in animals from West Greenland<br />

generally being lower than in the same species from East Greenland. <strong>The</strong><br />

same effect has previously been described <strong>for</strong> other hal<strong>og</strong>enated compounds<br />

such as polybrominated diphenyl ethers (PBDEs) (Vorkamp et al. 2007).<br />

Another, more localised source of pollution is mining activity, e.g. the olivine<br />

mine at Seqi in Niaqunngunaq (Fiskefjord) north of Nuuk. <strong>The</strong> nearest<br />

settlement is Atammik, at the inlet of the fjord. <strong>The</strong> mine was in operation<br />

between 2005 and 2010. Since 2004, environmental monitoring has been<br />

conducted every year in order to assess any impact from mining. During operation<br />

increased levels of some elements, particularly chromium and nickel,<br />

were measured in lichens, blue mussels and seaweed. Generation and<br />

spread of metal-contaminated dust from the roads and the ore-crushing facility<br />

was considered the main source of this contamination. Since closure of<br />

the mine in 2010, the environmental impact has decreased and is presently<br />

considered as being insignificant <strong>for</strong> the Niaquungunaq fjord system (Søndergaard<br />

& Asmund 2011).<br />

7.1.1 Tributyltin (TBT)<br />

<strong>The</strong> antifouling agent, tributyltin (TBT) can be found in many coastal waters<br />

in both industrial and developing countries with the highest levels in harbours<br />

and shipping lanes (Sousa et al. 2009). In remote areas such as the Arctic<br />

environment, TBT levels are usually low, except close to harbours, e. g.<br />

Sisimiut (Villumsen & Ottosen 2006) and shipping lanes (Strand & Asmund<br />

2003, AMAP 2004, Berge et al. 2004). <strong>The</strong> presence of TBT residues in harbour<br />

porpoises from Greenland documents that organotin compounds have<br />

also spread to the Arctic region, though the concentrations are rather low<br />

(Jacobsen & Asmund 2000, Strand et al. 2005).<br />

7.1.2 Petroleum hydrocarbons and Polycyclic Aromatic Hydrocarbons<br />

(PAH)<br />

Petroleum hydrocarbons represent several hundred chemical compounds<br />

originating from crude oil e.g. gasoline, kerosene, and diesel fuel. Of primary<br />

interest <strong>for</strong> assessment of the environmental impacts are the aromatic hydrocarbons<br />

(i.e., benzene, ethylbenzene, toluene, and xylenes). Another important<br />

group is the polycyclic aromatic hydrocarbons (PAHs), which originate<br />

from two main sources: combustion (pyr<strong>og</strong>enic) and crude oil (petr<strong>og</strong>enic).<br />

PAHs represent the most toxic fraction of oil and are released to the<br />

environment through oil spills and discharge of produced water (see also<br />

chapter 10 and 11). Twentythree PAHs are included on the lists of priority<br />

171

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