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Protocol for the Derivation of Environmental and Human ... - CCME

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Part B, Section 7<br />

There<strong>for</strong>e,<br />

BCF = concentration in plants<br />

concentration in soil<br />

Using pr<strong>of</strong>essional judgment, BCF values from soil to plants can be estimated with available literature<br />

data. A technical draft report has been prepared by Environment Canada (1994c) <strong>and</strong> provides<br />

guidance on estimation <strong>of</strong> appropriate soil-to-plant BCF values <strong>for</strong> guidelines derivation.<br />

7.6.7 Calculation <strong>of</strong> <strong>the</strong> Soil Quality Guideline <strong>for</strong> Ingestion<br />

An animal may be exposed to a contaminant by more than one route (i.e. through contaminated food,<br />

direct soil ingestion, dermal exposure, inhalation <strong>of</strong> air <strong>and</strong> dust, <strong>and</strong> drinking water) (Figure 15). The<br />

effects from <strong>the</strong> sum <strong>of</strong> <strong>the</strong>se exposures should not exceed <strong>the</strong> DTED. Contributions from each media<br />

(also called apportionment factors) to <strong>the</strong> total exposure <strong>for</strong> livestock <strong>and</strong> wildlife are discussed below.<br />

Water<br />

The U.S. EPA <strong>and</strong> Health <strong>and</strong> Welfare Canada agree that 20% <strong>of</strong> a human's estimated daily intake<br />

(EDI) is contributed from water. It is assumed that <strong>the</strong> remaining 80% originates from soil, air, <strong>and</strong><br />

food. Due to <strong>the</strong> lack <strong>of</strong> sufficient data to estimate an inter-species apportionment factor <strong>for</strong> water, an<br />

apportionment factor <strong>of</strong> 20% shall be used <strong>for</strong> livestock <strong>and</strong> wildlife. If apportionment in<strong>for</strong>mation is<br />

available <strong>for</strong> <strong>the</strong> species in question it should be used in place <strong>of</strong> <strong>the</strong> human value.<br />

Dermal Absorption <strong>and</strong> Inhalation<br />

Insufficient in<strong>for</strong>mation exists to account <strong>for</strong> dermal absorption <strong>and</strong> inhalation <strong>of</strong> contaminants in<br />

livestock. It is assumed that <strong>the</strong>se two routes <strong>of</strong> exposure toge<strong>the</strong>r do not contribute significantly to <strong>the</strong><br />

total contaminant exposure to livestock (i.e. approximately 5%). However, if contaminant specific<br />

in<strong>for</strong>mation is available <strong>for</strong> dermal absorption <strong>and</strong> inhalation (e.g. volatiles), it will be used in place <strong>of</strong> <strong>the</strong><br />

default 5% apportionment factor.<br />

Ingestion<br />

The proportion <strong>of</strong> <strong>the</strong> total exposure attributed to ingestion is <strong>the</strong> product <strong>of</strong> <strong>the</strong> dry matter intake rate<br />

(DMIR) <strong>and</strong> contaminant concentration in that medium. Assuming that water <strong>and</strong> dermal<br />

absorption/inhalation account <strong>for</strong> 25% <strong>of</strong> <strong>the</strong> total exposure <strong>the</strong>n <strong>the</strong> remaining 75% <strong>of</strong> <strong>the</strong> total<br />

exposure is from food <strong>and</strong> soil ingestion. Walker <strong>and</strong> MacDonald (1992) recommended an<br />

apportionment factor <strong>of</strong> 75% in <strong>the</strong> calculation <strong>of</strong> tissue residue guidelines <strong>for</strong> <strong>the</strong> protection <strong>of</strong> wildlife<br />

consumers <strong>of</strong> aquatic life to account <strong>for</strong> contributions <strong>of</strong> food to <strong>the</strong> total exposure.<br />

There<strong>for</strong>e, in order to provide protection to <strong>the</strong> animal, maximum exposure from ingestion <strong>of</strong> soil <strong>and</strong><br />

food combined should not exceed 75% <strong>of</strong> <strong>the</strong> DTED. The soil quality guideline <strong>for</strong><br />

70

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