Protocol for the Derivation of Environmental and Human ... - CCME
Protocol for the Derivation of Environmental and Human ... - CCME
Protocol for the Derivation of Environmental and Human ... - CCME
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Appendix B<br />
Assuming that dairy cattle ingest, on average, 0.9 kg <strong>of</strong> soil per day (Fries <strong>and</strong> Paustenbach. 1990), <strong>and</strong><br />
that chemical intake via vegetation is negligible compared to that with direct soil intake, <strong>the</strong>n <strong>the</strong> daily<br />
intake <strong>of</strong> chemical can be defined as:<br />
daily chemical intake by dairy cattle = C s × 0.9 kg/day [9]<br />
Where C s is <strong>the</strong> concentration (mg/kg) <strong>of</strong> <strong>the</strong> chemical in <strong>the</strong> soil.<br />
Substituting equation 9 into <strong>the</strong> definition <strong>of</strong> B m <strong>and</strong> <strong>the</strong> latter into equation 8, <strong>and</strong> assuming that C s is <strong>the</strong><br />
proposed preliminary soil quality guideline (PSQG HH ), <strong>and</strong> rearranging <strong>the</strong> equation, <strong>the</strong>n <strong>the</strong> potential<br />
concentration <strong>of</strong> <strong>the</strong> organic chemical in milk (C m ) can be defined as:<br />
C m = antilog(-8.1 + log K ow )(day/kg) × PSQG HH (mg/kg) × 0.9(kg/day) [10]<br />
3.4 <strong>Human</strong> Daily Intake <strong>of</strong> Contaminants from Milk<br />
Intake resulting from contaminated milk can be defined as:<br />
I m = (MK h × MK c × B m × PSQG HH ) + (MK s × MK c × MK r ) [11]<br />
BW<br />
Where:<br />
I m = total intake <strong>of</strong> contaminants from milk (mg/kg⋅day)<br />
MK h = percentage milk home produced<br />
MK c = milk consumption rate (kg/day)<br />
B m = biotransfer factor <strong>for</strong> milk<br />
PSQG HH = preliminary human health-based soil quality guideline (mg/kg)<br />
MK s = percentage milk purchased<br />
MK r = average chemical concentration in retail milk (mg/kg)<br />
For non-carcinogens, <strong>the</strong> receptor is assumed to be a 13 kg child consuming 632 g <strong>of</strong> milk (whole, 2%<br />
<strong>and</strong> skim milk) per day. For carcinogens, <strong>the</strong> receptor is assumed to be a 70 kg adult consuming 230 g<br />
per day (Health Canada, 1994). For agricultural l<strong>and</strong> use, 100% <strong>of</strong> all milk is assumed to be produced<br />
on site (Table B.1).<br />
4.0 Soil Guidelines Checking Procedure<br />
The calculated contaminant concentration must be less than <strong>the</strong> required Maximum Residue Limit<br />
(MRL), when available, as specified in <strong>the</strong> Food <strong>and</strong> Drug Act. If <strong>the</strong> calculated concentration is<br />
higher, <strong>the</strong>n <strong>the</strong> preliminary soil quality guideline must be lowered. This checking mechanism applies to<br />
both carcinogenic <strong>and</strong> non-carcinogenic compounds.<br />
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