Protocol for the Derivation of Environmental and Human ... - CCME

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Part D, Section 1 Section 1 Derivation of the Final Soil Quality Guideline 1.1 Final Guideline Derivation The final recommended soil quality guideline (SQG F ) is to protect both ecological and human health. The preliminary human health soil quality guideline, which have been modified to ensure protection of human health with respect to the check mechanisms outlined in Part C and relevant appendicies, become the recommended human health-based soil quality guidelines (SQG HH ). Appropriate annotations will accompany any SQG HH that are based on modified PSQG HH . The lower of the two guidelines obtained through the environmental procedure (SQG E ) (Part B), or human health based procedure (SQG HH ) (Part C), will be recommended as the final soil quality guideline (SQG F ) for each land use subject to restrictions discussed in Section 1.2 (Part D) below. A general overview of the entire guidelines derivation process outlining the major steps leading to derivation of the final soil quality guideline is illustrated in Figure 24. 1.1.1 Evaluation Against Plant Nutritional Requirement, Geochemical Background and Analytical Detection Limits The SEQCCS believes that guidelines should be reasonable, workable and usable. Guidelines are developed by applying scientifically derived information, backed by professional judgement where data gaps occur. Occasionally, defined exposure-based procedures produce numerical guidelines that conflict with one or more of the following: • plant nutritional requirements; • geochemical background; • analytical detection limits; When a conflict of this type occurs, guidelines must be adjusted as described below: Some chemicals (e.g., copper and zinc) considered hazardous at high levels also provide minimum nutritional requirements for the maintenance of plant growth at lower levels. The SEQCCS acknowledges that the SQG F determined for these chemicals may fall below the nutritional requirements. For agricultural and residential/parkland land uses maintenance of nutritional requirements is critical to sustaining the primary activity on these lands (i.e., growing crops, grass, trees). Accordingly, SEQCCS recommends that the SQG F for these land use categories be compared to minimum plant nutritional requirements. If the SQG F is below acceptable minimum plant nutritional requirement levels, then insufficient nutritional requirements for plant growth may result at the value of the SQG F . The SQG EE should therefore default to the soil concentration required for minimum plant nutrition. This value 102
does not apply to the commercial or industrial land use categories, because it is anticipated that the resulting SQG F will be above plant nutritional requirements. 103
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A Protocol for the Derivation of En
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Readers' Comments The Canadian Coun
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Overview In response to growing pub
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mechanisms for migration of soil co
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procédures d'élaboration des reco
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• être absorbés par les plantes
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PART B Section 1 Derivation of Envi
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Section 2 Investigation of Contamin
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PART D Section 1 Derivation of the
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List of Figures 1 National Framewor
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Acknowledgements The CCME Subcommit
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Document Organization This document
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Bioaccumulation: The process by whi
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Denitrification: The gaseous loss o
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GGG Guidelines: Generic numerical l
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Mutagenicity: The ability of a chem
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xxxiv human exposure. Risk estimati
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Soil: Normally defined as the uncon
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VVV Volatilization: The chemical pr
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Section 1 The National Contaminated
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Part A, Section 1 6
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Part A, Section 1 1.2.2.2 Remediati
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Part A, Section 1 of, and establish
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Part A, Section 2 Section 2 Nationa
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Part A, Section 2 2.2 Limitations o
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Part A, Section 2 17
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Part A, Section 2 Industrial: where
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• the sensitivity of the test con
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Part A, Section 3 23
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Section 2 Level of Ecological Prote
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Part B, Section 2 2.3 Endpoint Defi
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Part B, Section 2 There is consiste
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Part B, Section 4 Section 4 Potenti
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Part B, Section 4 Figure 4 Simplifi
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Figure 5 Key Receptors and Exposure
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Part B, Section 5 grazing herbivore
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Part B, Section 5 5.2.2 Maintenance
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Part B, Section 5 5.4 Industrial La
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Section 6 Uncertainty in Guidelines
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Section 7 Guidelines Derivation Pro
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Part B, Section 7 (SQG SG = soil qu
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Part B, Section 7 a soil quality gu
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Where: NPER = no to Potential Effec
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Part B, Section 7 7.5.2.1 Using Mic
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Part B, Section 7 data, the Median
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Part B, Section 7 EC 50 LC 50 UF =
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Where: ERL = Effects Range Low, ECL
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Part B, Section 7 Where: EC 50 = Me
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Part B, Section 7 Where the ECL lie
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Part B, Section 7 4. Fewer than thr
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Part B, Section 7 An uncertainty fa
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Part B, Section 7 Therefore, BCF =
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Part B, Section 7 ingestion (SQG I
Page 117 and 118: Section 8 Derivation of the Final E
Page 119 and 120: Part C, Section 1 65
Page 121 and 122: Part C, Section 1 various sites acr
Page 123 and 124: Part C, Section 1 Geographical unce
Page 125 and 126: preferred for the assessment, but s
Page 129 and 130: Part C, Section 2 Environmental con
Page 131 and 132: Part C, Section 2 extent, the steep
Page 133 and 134: Section 3 Exposure to Contaminants
Page 137 and 138: Part C, Section 4 Section 4 Exposur
Page 139 and 140: Part C, Section 4 within limits, th
Page 141 and 142: Part C, Section 4 Figure 19 Concept
Page 143 and 144: Part C, Section 4 4.2 Absorption of
Page 145 and 146: Part C, Section 4 In the case of no
Page 148 and 149: Residential/Parkland Land Use Sensi
Page 150 and 151: Part C, Section 4 Commercial Land U
Page 152: Part C, Section 4 Industrial Land U
Page 155 and 156: Part C, Section 5 these data are av
Page 157 and 158: Part C, Section 5 GEOCHEM (Mattigod
Page 159 and 160: Part C, Section 5 • K oc (sorptio
Page 161 and 162: Part C, Section 5 5.3.3 Evaluation
Page 163 and 164: Part C, Section 5 parameters, and s
Page 165 and 166: Section 6 Derivation of the Final H
Page 167: Part D, Section 1 101
Page 171: Part D, Section 1 105
Page 174 and 175: References Aldenberg, T., and W. Sl
Page 176 and 177: References -dwelling Organisms", Ab
Page 178 and 179: References 112
Page 180 and 181: References Hill, E.F., and D.J. Hof
Page 182 and 183: References Paustenbach, D.J., (1989
Page 184 and 185: References Summers, J.K., H.T. Wils
Page 186 and 187: Appendix A Appendix A Nutrient and
Page 188 and 189: Appendix A Figure A.1 Simplified Te
Page 190 and 191: Appendix A 4.1 Agricultural and Res
Page 192 and 193: Appendix A References Bååth, E.,
Page 194 and 195: The Subcommittee considers that exp
Page 196 and 197: Appendix B P l P r BW = percent pro
Page 198 and 199: Appendix B Substituting equation 5
Page 200 and 201: Appendix B Where no MRL exists, the
Page 202 and 203: Appendix B Then, the remainder (T R
Page 204 and 205: Appendix B For carcinogens, total i
Page 206 and 207: Appendix C Rearranging [2] and subs
Page 208 and 209: Appendix C References Chiou, C.T.,
Page 210 and 211: Appendix D uncontaminated organic m
Page 212 and 213: Appendix D R = recharge, m/yr A = a
Page 214 and 215: Appendix D 2.3.3 Hydraulic Gradient
Page 216 and 217: Appendix D 2.3.5 Site Length The le
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Appendix D Table D.2 Lower Quantile
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Figure D.2 Conceptual Model of Dilu
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Appendix D Figure D.3 Recharge Esti
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Appendix D 159
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Smith, A.E., P.B. Ryan, and J.S. Ev
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Appendix E C K L V is the climate f
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Appendix E contaminant concentratio
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Appendix F Appendix F Multi-media E
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Appendix F example, fish BCFs are t
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Appendix G 2.2 Contaminant Vapour T
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Appendix G Table G.1 Equations Used
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Appendix G at the outset that, rath
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Appendix G 4.4 Application of the R
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Average outdoor summer temperature
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Appendix G References Alberta Envir
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