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Protocol for the Derivation of Environmental and Human ... - CCME

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Appendix G<br />

Appendix G<br />

Development <strong>of</strong> a Relationship to Describe Migration <strong>of</strong><br />

Contaminated Vapours into Buildings<br />

1.0 Introduction<br />

A study (OAEI 1994) leading to <strong>the</strong> development <strong>of</strong> a relationship to describe <strong>the</strong> migration <strong>of</strong><br />

contaminant vapours into buildings was commissioned by Health Canada. The objective <strong>of</strong> <strong>the</strong> study<br />

was to develop a simplified relationship between subsurface contaminant concentrations <strong>and</strong> indoor air<br />

concentrations, arising from <strong>the</strong> migration <strong>of</strong> contaminant vapours into buildings. The purpose <strong>of</strong> <strong>the</strong><br />

relationship is to assess, at a screening level, <strong>the</strong> relative significance <strong>of</strong> vapour transport <strong>and</strong> inhalation<br />

as an exposure scenario in <strong>the</strong> context <strong>of</strong> <strong>the</strong> establishment <strong>of</strong> soil quality guidelines. The results <strong>of</strong> <strong>the</strong><br />

study are presented here.<br />

2.0 Background<br />

2.1 General<br />

Health risk assessment has been used increasingly in <strong>the</strong> last few years to develop soil <strong>and</strong> groundwater<br />

remediation guidelines, both on a site-specific basis <strong>and</strong> as regulatory guidelines. The risk assessment<br />

procedure normally involves four main steps: hazard identification; toxicity assessment; exposure<br />

assessment; <strong>and</strong> risk characterization. Exposure assessment is <strong>the</strong> process <strong>of</strong> determining <strong>the</strong> point-<strong>of</strong>exposure<br />

contaminant concentrations as a function <strong>of</strong> source concentrations <strong>for</strong> <strong>the</strong> relevant exposure<br />

pathways, to estimate intake. The exposure pathways commonly considered include:<br />

• ingestion <strong>of</strong> groundwater;<br />

• ingestion <strong>of</strong> soil;<br />

• dermal contact with soil <strong>and</strong> water;<br />

• inhalation <strong>and</strong> incidental ingestion <strong>of</strong> airborne particulates;<br />

• inhalation <strong>of</strong> vapours from soil <strong>and</strong> groundwater.<br />

For volatile organic compounds, inhalation <strong>of</strong> vapours is <strong>of</strong>ten a dominant exposure pathway. In spite<br />

<strong>of</strong> this, <strong>the</strong> risk-based guidelines that have been developed by regulatory agencies to date are <strong>of</strong>ten<br />

based only on <strong>the</strong> direct pathways <strong>of</strong> ingestion, dermal contact, <strong>and</strong> intake <strong>of</strong> particulates. The Alberta<br />

MUST (Management <strong>of</strong> Underground Storage Tanks) guidelines, which prescribe guidelines specifically<br />

<strong>for</strong> petroleum contaminated soil <strong>and</strong> groundwater, are based primarily on exposure via vapour inhalation<br />

(Alberta Environment, 1991; 1994).<br />

The purpose <strong>of</strong> <strong>the</strong> present study is to develop a screening tool that will facilitate <strong>the</strong> identification <strong>of</strong><br />

situations in which <strong>the</strong> inhalation <strong>of</strong> vapours originating in contaminated soil <strong>and</strong> groundwater is a<br />

significant pathway.<br />

160

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