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Protocol for the Derivation of Environmental and Human ... - CCME

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Appendix D<br />

2.3.5 Site Length<br />

The length <strong>of</strong> a contaminated site in <strong>the</strong> present context is merely <strong>the</strong> surface lateral dimension parallel to<br />

<strong>the</strong> direction <strong>of</strong> groundwater flow. The lower limit could be a retail gas station (with a width as small as<br />

15 m). The upper limit could include local-to-regional contamination phenomena produced by severe<br />

atmospheric deposition (e.g., smelters, automotive emissions). However, <strong>the</strong>se latter sites are rarely, if<br />

ever, addressed through <strong>the</strong> application <strong>of</strong> generic guidelines — more liekly <strong>the</strong>y will be subject to risk<br />

assessment. The practical upper limit <strong>for</strong> <strong>the</strong> application <strong>of</strong> generic guidelines might be represented by a<br />

moderate size industrial site. In <strong>the</strong> absence <strong>of</strong> a systematic review <strong>of</strong> industrial site dimensions <strong>the</strong><br />

upper limit <strong>for</strong> site length is 200 m.<br />

2.4 Uncertainty Analysis<br />

A dilution factor protective <strong>of</strong> groundwater at a majority <strong>of</strong> sites might be estimated by inserting<br />

expected or conservatively chosen values <strong>for</strong> each parameter in equation [9]. As pointed out by<br />

Thompson et al. (1992), however, <strong>the</strong>se procedures provide an unknown but potentially extreme level<br />

<strong>of</strong> conservatism based on improbable or impossible combinations <strong>of</strong> parameters.<br />

As an alternative to this approach uncertainty in <strong>the</strong> parameters <strong>of</strong> <strong>the</strong> dilution expression is evaluated<br />

through a modified Monte Carlo (Latin hypercube sampling) uncertainty analysis. A generic diltuion<br />

factor is recommended by entering <strong>the</strong> cumulative frequency distribution <strong>for</strong> <strong>the</strong> response variable at a<br />

plausible level <strong>of</strong> risk.<br />

Correlations among parameters which, left unaddressed, overestimate <strong>the</strong> uncertainty in <strong>the</strong> result (Smith<br />

et al. 1992) were accommodated using Crystal Ball (Decisioneering Corp. (1993). Results are<br />

reported from simulation runs <strong>of</strong> ten thous<strong>and</strong> iterations. Increasing iterations to twenty thous<strong>and</strong><br />

resulted in less than 1% change in percentiles <strong>of</strong> <strong>the</strong> cumulative frequency distribution.<br />

Parameter Distributions<br />

Few data were available with which to judge <strong>the</strong> appropriate distributions <strong>for</strong> each parameter.<br />

However, in every case sufficient in<strong>for</strong>mation existed to nominate a range <strong>and</strong> suggest an intermediate<br />

value that was expected more <strong>of</strong>ten than ei<strong>the</strong>r end-member. This in<strong>for</strong>mation is sufficient to specify a<br />

triangular distribution. Parameters in <strong>the</strong> uncertainty analysis are presented along with <strong>the</strong>ir ranges <strong>and</strong><br />

modes in Table D.1.<br />

150

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