Protocol for the Derivation of Environmental and Human ... - CCME
Protocol for the Derivation of Environmental and Human ... - CCME
Protocol for the Derivation of Environmental and Human ... - CCME
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Appendix D<br />
2.3.5 Site Length<br />
The length <strong>of</strong> a contaminated site in <strong>the</strong> present context is merely <strong>the</strong> surface lateral dimension parallel to<br />
<strong>the</strong> direction <strong>of</strong> groundwater flow. The lower limit could be a retail gas station (with a width as small as<br />
15 m). The upper limit could include local-to-regional contamination phenomena produced by severe<br />
atmospheric deposition (e.g., smelters, automotive emissions). However, <strong>the</strong>se latter sites are rarely, if<br />
ever, addressed through <strong>the</strong> application <strong>of</strong> generic guidelines — more liekly <strong>the</strong>y will be subject to risk<br />
assessment. The practical upper limit <strong>for</strong> <strong>the</strong> application <strong>of</strong> generic guidelines might be represented by a<br />
moderate size industrial site. In <strong>the</strong> absence <strong>of</strong> a systematic review <strong>of</strong> industrial site dimensions <strong>the</strong><br />
upper limit <strong>for</strong> site length is 200 m.<br />
2.4 Uncertainty Analysis<br />
A dilution factor protective <strong>of</strong> groundwater at a majority <strong>of</strong> sites might be estimated by inserting<br />
expected or conservatively chosen values <strong>for</strong> each parameter in equation [9]. As pointed out by<br />
Thompson et al. (1992), however, <strong>the</strong>se procedures provide an unknown but potentially extreme level<br />
<strong>of</strong> conservatism based on improbable or impossible combinations <strong>of</strong> parameters.<br />
As an alternative to this approach uncertainty in <strong>the</strong> parameters <strong>of</strong> <strong>the</strong> dilution expression is evaluated<br />
through a modified Monte Carlo (Latin hypercube sampling) uncertainty analysis. A generic diltuion<br />
factor is recommended by entering <strong>the</strong> cumulative frequency distribution <strong>for</strong> <strong>the</strong> response variable at a<br />
plausible level <strong>of</strong> risk.<br />
Correlations among parameters which, left unaddressed, overestimate <strong>the</strong> uncertainty in <strong>the</strong> result (Smith<br />
et al. 1992) were accommodated using Crystal Ball (Decisioneering Corp. (1993). Results are<br />
reported from simulation runs <strong>of</strong> ten thous<strong>and</strong> iterations. Increasing iterations to twenty thous<strong>and</strong><br />
resulted in less than 1% change in percentiles <strong>of</strong> <strong>the</strong> cumulative frequency distribution.<br />
Parameter Distributions<br />
Few data were available with which to judge <strong>the</strong> appropriate distributions <strong>for</strong> each parameter.<br />
However, in every case sufficient in<strong>for</strong>mation existed to nominate a range <strong>and</strong> suggest an intermediate<br />
value that was expected more <strong>of</strong>ten than ei<strong>the</strong>r end-member. This in<strong>for</strong>mation is sufficient to specify a<br />
triangular distribution. Parameters in <strong>the</strong> uncertainty analysis are presented along with <strong>the</strong>ir ranges <strong>and</strong><br />
modes in Table D.1.<br />
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