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(GP/GT) for Additional Water Supply in the Lower Rio Grande

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A <strong>the</strong>rmodynamic review of <strong>the</strong> system <strong>in</strong>dicates <strong>the</strong> number of effects to be between<br />

twelve and sixteen, based upon <strong>the</strong> water recovery. The implementation of freon (or<br />

CFC-free refrigerant) charged condensers <strong>in</strong>stead of product water charged condensers<br />

will optimize <strong>the</strong> per<strong>for</strong>mance and reduce <strong>the</strong> actual number of stages required. It<br />

should be noted that <strong>the</strong>re is an approximate 3.0-5.0· F temperature drop across each<br />

stage, based upon <strong>the</strong> vacuum applied and system <strong>in</strong>sulat<strong>in</strong>g capacity. For <strong>the</strong><br />

purposes of this review, a 5.0· F temperature drop was considered <strong>in</strong> <strong>the</strong> prelim<strong>in</strong>ary<br />

design.<br />

With a basic concept of <strong>the</strong> most applicable type of system to utilize, an evaluation of<br />

<strong>the</strong> system feed water was per<strong>for</strong>med. Utiliz<strong>in</strong>g a modified commercially available<br />

physical-chemistry saturation computer model (Dh-SAT, French Creek Software). <strong>the</strong><br />

system was first modeled at <strong>the</strong> wellhead parameters, at a pressure of 1000 PSI.<br />

Follow<strong>in</strong>g this evaluation, an evaluation was per<strong>for</strong>med of <strong>the</strong> br<strong>in</strong>e (reject) stream at<br />

<strong>the</strong> 75% water recovery level (concentration factor 4.0). at a pressure of 0 PSI.<br />

The results of both were evaluated, with graphical representations attached <strong>in</strong><br />

Appendix A. The Dh-SAT program calculates <strong>in</strong>dicators of scale potential <strong>for</strong> <strong>the</strong><br />

follow<strong>in</strong>g:<br />

barium sulfate Barite<br />

barium carbonate Wi<strong>the</strong>rite<br />

calcium carbonate Calcite<br />

calcium sulfate Gypsum<br />

strontium sulfate Celestite<br />

• calcium phosphate Hydroxyapatite and<br />

Tricalcium Phosphate<br />

iron hydroxide Amorphous Iron Hydroxide<br />

iron phosphate Strengite<br />

iron carbonate Siderite<br />

silica Amorphous Silica<br />

calcium fluoride Fluorite<br />

• magnesium hydroxide Brucite<br />

In addition, several scal<strong>in</strong>g <strong>in</strong>dices are calculated, <strong>in</strong>clud<strong>in</strong>g <strong>the</strong> follow<strong>in</strong>g:<br />

• Langelier Index<br />

• Stiff-Davis Index<br />

• Ryznar Index<br />

• Oddo-Tomson Index<br />

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