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Single-Particle Electrodynamics - Assassination Science

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wish of them—not least of which being simplicity.<br />

2.7 Classical limit of quantum mechanics<br />

A thorny question is the following: In what sense does classical mechanics<br />

represent the “limit” of quantum mechanics?<br />

The author will not add any new answers to this question. Most physicists<br />

will be familiar with Ehrenfest’s theorem (see, e.g., [150, Ch. VI] and [69,<br />

Sec. 31]): the equation of motion for the expectation value of an operator is<br />

the expectation value of the corresponding classical Hamiltonian equation of<br />

motion.<br />

The rub is that, despite first appearances, the expectation values do not<br />

follow the classical equations of motion, unless the functional dependence of<br />

the Hamiltonian equation of motion is such that the expectation value of the<br />

function is equivalent to the function of the relevant expectation values. This<br />

is only exactly true of a few physical systems (where the Hamiltonian H is a<br />

polynomial of the second degree in the q’s and b’s).<br />

However, regardless of the system being considered, one can generally<br />

construct wave-packets for which the classical equations of motion are a good<br />

approximation—namely, those physical situations for which one may speak<br />

with some validity of complementary variables taking on approximately welldefined<br />

values (limited by the Heisenberg uncertainty principle) [69]. In such<br />

cases, the difference between the taking the expectation of a function of<br />

the conjugate variables, and taking the function of the expectations of the<br />

conjugate variables, is small compared to the motion of the wave-packet as<br />

a whole.<br />

It is simple enough to review Ehrenfest’s theorem in theory, as we have<br />

briefly done above. It is far more difficult to decide, for any given physical<br />

application, just how well the classical equations equations of motion will<br />

describe the gross motion of the particles under consideration. Clearly, the<br />

90

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