The ferrotype and how to make it - The Grian Press
The ferrotype and how to make it - The Grian Press
The ferrotype and how to make it - The Grian Press
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74 THE FERROTYPE.<br />
allowing the sediment <strong>to</strong> fall <strong>to</strong> the bot<strong>to</strong>m before<br />
decanting the liquid.<br />
You have now in the washed precip<strong>it</strong>ate a<br />
grayish powder, which is comparatively pure<br />
metallic silver, which, if you choose, may be<br />
converted in<strong>to</strong> solution again by adding n<strong>it</strong>ric<br />
acid sufficient <strong>to</strong> re-dissolve, or the precip<strong>it</strong>ate<br />
may be dried <strong>and</strong> placed in a crucible w<strong>it</strong>h a<br />
small quant<strong>it</strong>y of n<strong>it</strong>rate of potash, <strong>and</strong> fused<br />
the potash will remove any trace of iron or zinc.<br />
I have by this method converted an old <strong>and</strong> use-<br />
less solution of silver in<strong>to</strong> a good working bath<br />
in a very short time, although <strong>it</strong> is better not <strong>to</strong><br />
do <strong>it</strong> in a hurry.<br />
N<strong>it</strong>rate of silver may also be reduced from<br />
solution by evaporating <strong>to</strong> dryness ; at the last,<br />
the heat should be very gentle, because in the<br />
presence of organic matter the n<strong>it</strong>rate is easily<br />
changed <strong>to</strong> pure silver, which would require <strong>to</strong><br />
be re-dissolved.<br />
<strong>The</strong> fused mass presents a yellowish appear-<br />
ance, <strong>and</strong> readily dissolves in water, leaving the<br />
organic matter <strong>and</strong> residues of cadmium <strong>and</strong> po-<br />
tassium in a thick, pasty mass of a dark color,<br />
but which also contains some silver, <strong>and</strong> on that<br />
account should be saved w<strong>it</strong>h other wastes.<br />
It has been said that the fusion of the residues<br />
of pho<strong>to</strong>grapher's old silver solutions is attended<br />
w<strong>it</strong>h some danger from the not improbable<br />
formation of fulminating silver, a most power-<br />
fully explosive compound. Some idea of <strong>it</strong>s ex-<br />
;