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The ferrotype and how to make it - The Grian Press

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DEVELOPEE AND DEVELOPMENT. 87<br />

<strong>The</strong> action of sulphate of iron upon the n<strong>it</strong>rate<br />

of silver solution is <strong>to</strong> change <strong>it</strong>s character by<br />

convertino^ the silver of the solution <strong>to</strong> a metallic<br />

state, in which state <strong>it</strong> is depos<strong>it</strong>ed in the form of<br />

a grayish powder, the character of the depos<strong>it</strong><br />

being somewhat aifected by the acid.<br />

Various acids are used in the developing so-<br />

lution. <strong>The</strong> most prominent are acetic, glacial<br />

acetic, n<strong>it</strong>ric, c<strong>it</strong>ric, gallic, <strong>and</strong> pyrogallic acids.<br />

<strong>The</strong> last three, <strong>how</strong>ever, are more used in the<br />

process of re-development of negatives. <strong>The</strong><br />

first is, for many reasons, the best, <strong>and</strong> is gen-<br />

erally used in solutions for the primary develop-<br />

ment of negatives <strong>and</strong> always for pos<strong>it</strong>ives.<br />

Acetic acid is a product of the oxydation of<br />

alcohol. Spir<strong>it</strong>uous liquors when perfectly pure<br />

are not affected by exposure <strong>to</strong> the air, but if a<br />

portion of yeast or n<strong>it</strong>rogenious organic matter of<br />

any kind be added <strong>it</strong> soon acts as a. ferment, <strong>and</strong><br />

causes the spir<strong>it</strong> <strong>to</strong> un<strong>it</strong>e w<strong>it</strong>h oxygen derived<br />

from the atmosphere, <strong>and</strong> so <strong>to</strong> become sour from<br />

the formation of acetic acid or vinegar. Acetic<br />

acid is also produced on a large scale by heating<br />

wood in a close vessel. A substance distills over,<br />

which is acetic acid contaminated w<strong>it</strong>h empyreu-<br />

matic <strong>and</strong> tarry matter; <strong>it</strong> is termed pyrolig-<br />

neous acid, <strong>and</strong> is much used in commerce.<br />

<strong>The</strong> most concentrated acetic acid may be<br />

obtained by neutralizing common vinegar w<strong>it</strong>h<br />

carbonate of soda, <strong>and</strong> crystallizing out the acetate<br />

of soda so formed. This acetate of soda is then

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