Introduction to Soil Chemistry
Introduction to Soil Chemistry
Introduction to Soil Chemistry
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120 titrimetric measurement<br />
<strong>Soil</strong> Sample<br />
Subsample Subsample Subsample<br />
Steam Distill<br />
Titrate<br />
Inorganic<br />
Ammonia<br />
Digest<br />
Sulfuric Acid<br />
Catalyst<br />
Steam Distill<br />
Titrate<br />
Inorganic<br />
Ammonia and<br />
Ammonia<br />
from Organic<br />
Matter<br />
Oxidation<br />
Nitrite <strong>to</strong> Nitrate<br />
Reduction <strong>to</strong><br />
Ammonia<br />
Steam Distill<br />
Titrate<br />
Inorganic<br />
Ammonia and<br />
Ammonia from<br />
Nitrite and<br />
Nitrate<br />
Figure 6.7. Flow diagram for determination of ammonia, organic nitrogen, nitrite, and nitrate<br />
using kjeldahl apparati [6].<br />
6.5. KJELDAHL—ORGANIC NITROGEN<br />
Caution: Extreme caution must be exercised in carrying out a kjeldahl<br />
procedure. Digestion involves the use of concentrated sulfuric<br />
acid and in the past selenium and mercury have both been used a catalyst.<br />
Older equipment may be contaminated with these elements and<br />
should be treated with caution. During the digestion process copious<br />
amounts of choking, corrosive, and <strong>to</strong>xic sulfur dioxide fumes are<br />
released. These fumes must be removed by evacuating them using an<br />
aspira<strong>to</strong>r or some other appropriate method. Standard kjeldahl<br />
equipment will come with components and directions for removing<br />
SO 2 safely. Ammonia distillation involves use of highly concentrated<br />
caustic sodium hydroxide solutions, which must be handled with care.<br />
Sodium or potassium hydroxide spilled on skin is best removed with<br />
a dilute solution (1–2%) of acetic acid in water followed by washing<br />
with soap and water.
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