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Introduction to Soil Chemistry

Introduction to Soil Chemistry

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soil solids 31<br />

the name taken from the concept that material from the surface falls <strong>to</strong> the<br />

bot<strong>to</strong>m of the cracks, resulting in inversion of the soil.<br />

In the field when soil containing 2:1 clays become wet, they swell shut and<br />

water movement through them is extremely slow. In a soil profile wetting<br />

and swelling of this type of clay will prevent downward movement of water<br />

and associated contaminants. For this reason swelling clays are used <strong>to</strong> seal<br />

both landfills and ponds <strong>to</strong> prevent leaching or leaking.<br />

The crystals of 2:1 swelling clays are typically smaller than either kaolinite<br />

or fine grained mica and thus have higher adsorption and cation exchange<br />

capacities. However, surface adsorption will be of the same chemistry as that<br />

in the fine micas.<br />

2.1.3.3 Amorphous Clays<br />

In addition <strong>to</strong> the crystalline clays described above, there are some materials<br />

that act like clays but do not have a crystalline structure. Amorphous clays do<br />

not have a definite X-ray diffraction pattern and are differentiated from the<br />

crystalline clays on this basis. They are composed of mixtures of aluminum,<br />

silicon, and other oxides and generally have high sorptive and cation exchange<br />

capacities. Few soils contain large amounts of amorphous clays [2].<br />

2.1.4. <strong>Soil</strong> Texture<br />

Sand, silt, and clay are the three components of soil texture. Various relative<br />

compositions, expressed on a percentage bases, are used <strong>to</strong> give soils a textural<br />

name such as sandy loam, or loamy clay. For soils containing significant<br />

amounts of silt, the term loam is used, although with high levels (>88% silt,<br />

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