216 index Path length, 159 Ped(s), 1, 2, 11, 12, 14, 16, 20, 21, 47, 53, 64 Ped formation, 20, 21 Pedon, 1, 2, 18 Penicillium, 56 Percolation, 4–6, 20, 48, 71, 96 Permanganate, 65, 113 pH meter, 82, 94, 97, 99, 100, 105, 111, 113, 114, 118 Phenol, 61, 82 Phenolic, 62, 81, 97 Phosphate, 34, 76, 80, 81, 123, 158, 168, 195, 203–206 Phosphomolybdate, 158 Phosphoric acid, 113, 205, 206 Phosphorus, 19, 34, 55, 59, 168, 203–206 Pho<strong>to</strong>graphic film, 152 Pho<strong>to</strong>multiplier, 152–154 Pho<strong>to</strong>synthetic, 97 pH-sensing bulb, 97 pH-Stat titrations, 124 p bonds, 37 Piezoelectric, 136 Plant available water, 73, 86 Plasma, 147, 154 Platinum, 96, 113, 118 Platy, 11, 12 Pneumatic, 188 PO4 -3 , 80, 81, 168, 203, 206 Polar covalent, 32, 33, 42, 116 Polar regions, 34 Polaragraphy, 105 Polar-polar interactions, 32, 34 Polya<strong>to</strong>mic ions, 33 Polychlorinated biphenyls, 131 Polymer, 57, 62, 178, 204, 205 Polypedon, 2, 18 Polysaccharides, 57 Ponds, 31, 203 Porous block, 86, 107 Potassium, 11, 30, 55, 66, 79, 118, 121, 152, 163, 166, 195, 198 Potassium bromide, 163, 166 Potassium cation, 195 Potassium selective electrode, 11 Potentiometry, 96 Precipitation, 57, 76, 111, 113, 124, 127, 206 Precipitation reactions, 76, 113 Pressure plates, 88, 89 Prismatic, 11 Profile, 1, 2, 7, 8, 10–12, 17, 19–21, 31, 46, 48, 73, 78, 96, 107 Propanone, 34 Proteins, 57, 121, 163, 188, 205 Pro<strong>to</strong>ns, 33, 80, 82, 97, 113, 116, 168 Psychrometers, 86, 89 Quadrupole mass spectrometer, 169, 181, 185 Quantification, 148, 164, 191 Quartz, 156 Quaternary amines, 28 r 2 , 161, 162 Radio frequency (RF), 147 Rate fac<strong>to</strong>rs, 32, 39, 42 Reaction intermediate, 38 Reaction paths, 32, 37, 38, 42 Reactive sites, 39 Reciprocal centimeters, 163 Redox, 97, 101, 103, 104 Reducing conditions, 9, 10, 12, 14, 16, 17, 20, 51, 52, 72, 73, 104, 200 Reduction reactions, 20, 72, 85, 105, 106, 113 Reference electrode, 82, 97, 100, 101, 113, 118 Reference soil, 18 Refractive index, 185, 186 Refract light, 158 Regression analysis, 161, 162 Relative humidity in soil, 108 Resistance, 59, 93, 94, 106, 107, 181 Reverse osmosis, 132 Reverse phase, 185, 187 Reverse phase column, 185 Rf, 189–191 Rhizobia, 51 Rhizosphere, 50, 61, 62 Rice, 51 Rigolith, 15 RNA, 57, 189 Roots, 11–13, 17, 24, 45, 48–51, 61, 65, 67, 72, 73, 82, 85, 204, 205 Rt, 189–191 Saline, 107 Saline-sodic, 107 Saliva, 46 Sample loop, 184 Sand, 1, 4, 11, 13, 15, 16, 23–25, 31, 32, 35, 40, 42, 57, 71, 75, 200, 204 Sandy loam, 31 Selective ion, 97, 118 Selenium, 131 Septum, 128, 177 Septum less, 177 Shrink-swell, 149 Siemens, 106, 107 Sieving, 31, 56, 151
Silica, 7, 24–26, 29, 37, 186–188 Silica gel, 141, 186 Silicon, 24–26, 28, 31, 32, 34–37, 42, 59, 78 Silicon tetrahedra, 26, 28 Silt, 1, 8, 11, 12, 16, 23–25, 31, 32, 35, 40, 57, 200 Silver, 96, 113, 123, 124, 187 Single grained, 15 Skin, 12, 46 Slicken sides, 12 Slits, 154 Smectite, 26, 28, 30, 42 Sodic soils, 107 Sodium, 10, 11, 30, 32, 63, 66, 79, 106, 107, 113, 114, 118, 119, 142, 152, 163, 198 Sodium chloride, 32, 106, 163 Sodium hydroxide, 114, 119, 132, 133 <strong>Soil</strong> air, 23, 71, 72, 76, 89, 182, 183, 197 <strong>Soil</strong> classification, 10 <strong>Soil</strong> clays, 26, 33, 150, 164 <strong>Soil</strong> color, 15–17, 20 <strong>Soil</strong> forming fac<strong>to</strong>rs, 1, 3, 7, 21 <strong>Soil</strong> matrix, 16, 46, 127, 128, 130, 142, 148 <strong>Soil</strong> orders, 17, 18 <strong>Soil</strong> profile, 7, 11, 12, 17, 19–21, 31, 46, 48, 73, 78, 96, 107 <strong>Soil</strong> taxonomy, 17, 18 <strong>Soil</strong> texture, 14 <strong>Soil</strong> thin layer, 187 <strong>Soil</strong> water, 64, 71–74, 76, 77, 86–89, 94, 107, 108 <strong>Soil</strong> water content, 73, 74, 76, 86, 89, 94, 107, 108 Solid phase extraction, 128, 138–140, 175 Solid phase microextraction, 128, 138, 141 Solubilization, 57 Solvation, 33 Solvents, 85, 130–133, 135, 138, 142, 150, 156, 165, 166, 168, 175, 203 Sonication, 136 Sorption cleanup methods, 140 South America, 19 Soxhlet, 134–136 Soxhlet extraction, 135 Sparging, 128 Speciation, 7, 168, 195, 197, 198, 204, 206 Species changes, 206, 207 Spectral overlap, 148 Spectrometer, 128, 152, 155, 156, 159, 163, 169, 170, 181, 184, 185 Spectropho<strong>to</strong>meter, 158–160, 166, 170 Spectropho<strong>to</strong>metric, 139, 142, 159, 191 Spectroscopic, 32, 58, 142, 148, 153, 154, 169, 170, 175, 190 index 217 Spectroscopy a<strong>to</strong>mic, 152 infrared, 163 mass, 169 NMR, 167 UV-Vis, 156 Vis, 158 X-ray fluorescence, 150 Spodic horizon, 49, 78 Spodosols, 13, 19, 20, 49 Stationary phase, 141, 175, 176, 178, 180, 185, 186, 188 Steam distillation, 119, 121, 122 Steric hindrances, 37, 39 Stripping voltammetry, 105 Subangular blocky, 11 Subordinate horizon, 10 Sugars, 56, 61, 124, 187, 205 Sulfides, 14, 20 Sulfur, 14, 52, 55, 66, 77 Sulfur cycle, 55 Sulfuric acid, 66, 113, 118, 121, 187 Supercritical fluid extraction, 134, 137 Surface areas, 24–26, 28, 35, 96, 151, 206 Surface phenomenon, 151 Surface tension, 74 Surfactant, 129 Suspended particle removal, 140 Syringe, 128, 140, 177, 182–184, 186, 188 Syringe plunger, 177 Teflon, 177 Tensiometers, 86, 88 Termites, 46 Terpenes, 156 Tertiary excitation, 152 Tetrachloroethylene, 164 Tetramethylsilane (TMS), 168, 169 Textural name, 31 Textural triangle, 31 Texture, 2, 4, 9, 11, 14, 20, 31, 64, 71 Thalidomide, 197 Thermal conductivity, 181 Thermocouple psychrometer, 86, 89 Thermodynamic, 39 Thermophilic, 52 Thin layer chroma<strong>to</strong>graphy (TLC), 175, 186, 187, 190 Thomson thermocouple, 107 Time domain reflectrometry, 86, 89 Time of flight (TOF), 169 Titanium, 78 Titrant, 111–114, 123, 124 Titration, 65, 111–114, 116–119, 122, 124, 125, 205, 206
- Page 1:
Introduction to Soil Chemistry Anal
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CHEMICAL ANALYSIS A SERIES OF MONOG
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Copyright © 2005 by John Wiley & S
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CONTENTS PREFACE xiii CHAPTER 1 SOI
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contents ix 4.14. Conclusion 89 Pro
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contents xi CHAPTER 10 SPECIATION 1
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xiv preface Moisture levels can cha
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CHAPTER 1 SOIL BASICS I MACROSCALE
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soil basics i 3 Mollisol Ap 0 - 17.
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soil basic i 5 Spodosol Oi 0 - 2.5
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horizonation 7 or basic.Thus, the t
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horizonation 9 Table 1.2. Major-Min
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peds 11 As would be expected, only
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peds 13 Figure 1.7. Peds isolated f
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P soil color 15 B P = pores B = bri
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soil naming 17 Under most condition
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soil chemistry, analysis, and instr
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ibliography 21 thus increased oxida
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CHAPTER 2 SOIL BASICS II MICROSCOPI
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O O Si O O d - d H H + d + O soil s
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d - Si O O O Al O O H d+ O O HO OH
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O HO O O O HO O O Si O Al O Si O O
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soil solids 31 the name taken from
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onding considerations 33 The two op
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surface features 35 Because differe
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energy considerations 37 side-by-si
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In Figure 2.5 the path to the right
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H O H H O C Na +- O O H H O H H O H
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eferences 43 2.7. Explain how the r
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CHAPTER 3 SOIL BASICS III THE BIOLO
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animals 47 C Figure 3.2. An ant col
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plants 49 Grasses and other similar
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plants 51 Rhizosphere Figure 3.4. I
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microorganisms 53 Table 3.1. Design
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microorganisms 55 microaerophilic,
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ioorganic 57 activity may be increa
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organic compounds 59 and may contai
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organic compounds 61 Table 3.3. Fun
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R 2C R organic compounds 63 O C - O
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analysis 65 3.7.1. Analysis for Ani
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problems 67 oxide by components in
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eferences 69 6. Bais HP, Park S-W,
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CHAPTER 4 SOIL BASICS IV THE SOIL A
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water 73 The soil atmosphere also c
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D C water 75 B Figure 4.3. A wide-d
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compounds in solution 77 tion is li
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+ NH4 + NH4 H H O + NH4 H H H + NH
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organic ions in solution 81 consequ
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distribution between soil solids an
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oxidative and reductive reactions i
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measuring soil water 87 soil is rep
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problems 89 blocks, and thermocoupl
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eferences 91 8. Bohn HL, McNeal BL,
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94 electrical measurements Figure 5
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96 electrical measurements 1200 100
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98 electrical measurements Referenc
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100 electrical measurements Standar
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102 Table 5.1. Ion-Selective Electr
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104 electrical measurements In addi
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106 electrical measurements along w
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108 electrical measurements cools w
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110 electrical measurements Science
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112 titrimetric measurement pH 13 1
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114 titrimetric measurement Table 6
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116 titrimetric measurement H 3 O +
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118 titrimetric measurement Because
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120 titrimetric measurement Soil Sa
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122 titrimetric measurement 6.6. NI
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124 titrimetric measurement - + X +
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126 titrimetric measurement REFEREN
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128 extraction Organic compounds, i
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130 extraction 3. What is the distr
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132 extraction All nonaqueous solve
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134 extraction Table 7.2. Character
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136 extraction Figure 7.3. Solution
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138 extraction Figure 7.5. A microw
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140 extraction serious interference
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142 extraction taining one to sever
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144 extraction Cohen DR, Shen XC, D
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146 extraction ultrasound; Applicat
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148 spectroscopy although technical
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150 spectroscopy Incident X-rays q
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152 spectroscopy with cellulose or
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154 spectroscopy extract components
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156 spectroscopy 8.6. ULTRAVIOLET A
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158 spectroscopy placed in the samp
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160 spectroscopy to scratch them. W
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162 spectroscopy Data Concentration
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164 spectroscopy these make analysi
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