Introduction to Soil Chemistry
Introduction to Soil Chemistry
Introduction to Soil Chemistry
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154 spectroscopy<br />
extract components such that the metal is protected from the heat source.<br />
Other interferences such as changes in the viscosity of the extract that can<br />
affect the accuracy of analysis are also possible, although they are less<br />
common.<br />
Whenever soil samples are being analyzed by any a<strong>to</strong>mic spectroscopic<br />
method, it is essential <strong>to</strong> make sure that no interfering, overlapping wavelength<br />
elements are present in the soils. If they are then steps must be taken <strong>to</strong> correct<br />
for these interferences.<br />
8.5.1. Excitation for A<strong>to</strong>mic Emission<br />
For the alkali-earth metals, as noted above, a simple flame of almost any type<br />
can be used <strong>to</strong> excite the metals. However, in order <strong>to</strong> determine a wide range<br />
of metals, it is common <strong>to</strong> use either an acetylene-air or acetylene-nitrous<br />
oxide flame as the source of energy <strong>to</strong> excite the a<strong>to</strong>ms. The burner is long<br />
with a slot in the <strong>to</strong>p and produces a long narrow flame that is situated endon-end<br />
<strong>to</strong> the optics receiving the emitted light.<br />
Light given off by the excited electrons falling back <strong>to</strong> ground state is passed<br />
through slits, isolated using a grating, adjusted <strong>to</strong> the analytical wavelength,<br />
and the amount of light is measured using a pho<strong>to</strong>multiplier or other light<br />
detecting device. The wavelength of the light specifies the element present<br />
while its intensity is directly related <strong>to</strong> the amount present.<br />
<strong>Introduction</strong> of sample in<strong>to</strong> the flame is accomplished by Bernoulli’s principle.<br />
A capillary tube is attached <strong>to</strong> the burner head such that gases entering<br />
the burner will create suction. The sample is thus aspirated in<strong>to</strong> the burner,<br />
mixed with the gases, and passed in<strong>to</strong> the flame. Heating in the flame excites<br />
electrons that emit light of distinctive wavelengths as they fall back <strong>to</strong> their<br />
original positions in the elements’ orbitals. Because a number of electrons can<br />
be excited and there are a number of orbitals in<strong>to</strong> which they can fall, each<br />
element emits a number of different wavelengths of light particular <strong>to</strong> that<br />
element. In the case of a<strong>to</strong>mic emission, one of these, usually the most prominent<br />
or strongest, is chosen as the primary analytical wavelength.<br />
Generally the higher the temperature of the sample, the more sensitive will<br />
be the analysis. Thus, in addition <strong>to</strong> the two types of flames discussed above,<br />
a third excitation source, which is not a flame but a plasma from an inductively<br />
coupled plasma (ICP) <strong>to</strong>rch, is used (see Figure 8.5). Argon support gas is<br />
seeded with free electrons that interact with a high-frequency magnetic field<br />
of an induction coil gaining energy and ionizing argon.The reversing magnetic<br />
field causes collisions that produce more ions and intense thermal energy<br />
resulting in high-temperature plasma in<strong>to</strong> which the sample is introduced.<br />
While the first two flames are used both for emission and absorption spectroscopy,<br />
ICP is used for emission spectroscopy. The three are arranged in<br />
order of increasing temperature. Both acetylene—air and acetylene—nitrous<br />
oxide can be used in the same instrument and the flames can be adjusted <strong>to</strong><br />
be oxidizing or reducing <strong>to</strong> allow for increased sensitivity for the element