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Introduction to Soil Chemistry

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H<br />

O<br />

H<br />

H<br />

O<br />

C<br />

Na +– O<br />

O<br />

H H<br />

O<br />

H H<br />

O<br />

H H<br />

H<br />

O<br />

H<br />

O<br />

O H<br />

coated surfaces 41<br />

O<br />

C<br />

O– Na +<br />

O H H<br />

C<br />

O – Na + C O<br />

O<br />

– Na +<br />

H<br />

O<br />

H H<br />

H H<br />

O<br />

O<br />

H H<br />

O<br />

H H<br />

H H<br />

O<br />

H H O<br />

O<br />

H H<br />

O<br />

O<br />

H H<br />

O<br />

H H<br />

H H<br />

O<br />

C O – Na +<br />

O H<br />

H<br />

O H<br />

H<br />

gen bonding and ion–charge interactions <strong>to</strong> form small conglomerations of<br />

clay particles that will act like micelles also as shown in Figure 2.6 [16].<br />

2.10. COATED SURFACES<br />

O<br />

C<br />

O – Na +<br />

O<br />

H<br />

O<br />

H<br />

H H<br />

The discussion <strong>to</strong> this point assumes that all the surfaces of all the components<br />

in soil are clean and available for reaction. This never happens. All surfaces<br />

are covered by coatings of various types; the number, types, and amounts of<br />

O<br />

H<br />

O<br />

H H<br />

H H<br />

O<br />

H H<br />

O<br />

H<br />

O<br />

H<br />

O<br />

H H<br />

O<br />

H H<br />

Figure 2.6. An upper micelle of sodium octanoate in water lower micelle of 2 :1 clay (center gray<br />

layer is an aluminum octrahedrial sheet; the upper and lower ones are silicon tetrahedrial sheets).

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