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Introduction to Soil Chemistry

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CHAPTER<br />

3<br />

SOIL BASICS III<br />

THE BIOLOGICAL AND ORGANIC COMPONENTS IN SOIL<br />

It might be assumed that soil is basically a dead, inert, nonliving material,<br />

which it is not. A more accurate view is that soil is living or alive. It has living<br />

organisms, which appear <strong>to</strong> be mostly plants, in and in intimate contact with<br />

it. Plants have two parts, which interact with soil the <strong>to</strong>ps and the roots. Both<br />

are important, although roots have a more intimate and immediate effect on<br />

the biological, physical, and chemical properties of soil. Many other types of<br />

organisms (i.e., microorganisms and animals), both large and small, live in soil.<br />

Microorganisms come in a wide variety of sizes, shapes, and abilities in terms<br />

of the types of environments they live in and the reactions they carry out. It<br />

is common knowledge that worms and prairie dogs live in soil, but these serve<br />

only as representatives of the variety of animals present.<br />

Animals and plants, especially roots and microorganisms, provide biochemical,<br />

bioorganic, and organic compounds in soil. These may be in the<br />

form of cellular components, such as cell walls and membranes, enzymes, and<br />

complex and simple organic compounds. Decomposition of complex cellular<br />

material and biochemicals leads <strong>to</strong> the formation of simpler intermediate<br />

bioorganic and organic compounds. Aerobic decomposition of any organic<br />

matter in soil eventually leads <strong>to</strong> the production of carbon dioxide and water,<br />

anaerobic decomposition leads <strong>to</strong> the same products plus methane, and both<br />

result in the synthesis of humus, which is a dark-colored, high-molecularweight,<br />

and highly complex material. The overall reaction of organic matter in<br />

soil is illustrated in Figure 3.1.<br />

Organic compounds interact with each other and with the inorganic, macro,<br />

micro, and colloidal components in soil. Complex and simple organic molecules<br />

form complexes with inorganic cations and anions and with colloidal<br />

carbon and clay in the soil solution. Some enzyme–soil complexes may have<br />

increased catalytic activity, while others have decreased activity or are completely<br />

inactive. Also, some combinations and complexes may render organic<br />

matter resistant <strong>to</strong> decomposition. Eventually organic matter and complexes<br />

may become stabilized such that they have long residence times in soil.<br />

All of these fac<strong>to</strong>rs are active in all soil at all times and may affect any<br />

analysis. Simpler organic and inorganic molecules, compounds, and ions may<br />

<strong>Introduction</strong> <strong>to</strong> <strong>Soil</strong> <strong>Chemistry</strong>: Analysis and Instrumentation, By Alfred R. Conklin, Jr.<br />

Copyright © 2005 by John Wiley & Sons, Inc.<br />

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