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APPLIED SUPERCONDUCTIVITY 2009Superconductivity of C and TiC doped multi-filam<strong>en</strong>tary MgB 2 wiresRec<strong>en</strong>tly a great deal of both fundam<strong>en</strong>tal and technical researchhas be<strong>en</strong> carried out on carbide-doped MgB 2 dueto its high upper critical field (H c2 ) which pres<strong>en</strong>ts considerableinterest for the fabrication of practical magnets, especiallythe GM-cryocooled MRI magnet. For <strong>en</strong>gineeringapplications, it is necessary to make MgB 2 superconductorsinto multi-filam<strong>en</strong>tary wires or tapes. The in-situ and exsitupowder-in-tube (PIT) processes have become the dominantor standard methods due to their commercial pot<strong>en</strong>tialfor large-scale and low-cost production of MgB 2 wires andtapes.Figure 145: Cross section of the differ<strong>en</strong>t multi-filam<strong>en</strong>tMgB 2 /NbCu wires.In this work, various multi-filam<strong>en</strong>t MgB 2 /NbCu roundwires with carbon or TiC doping have be<strong>en</strong> fabricated byin-situ PIT method at the Northwest Institute for NonferrousMetal Research (NIN). The typical diameter of the finalwire is 1 mm. The MgB 2 coil was fabricated using thewind and react method with a 1.5 m long wires and a heattreatm<strong>en</strong>t at 680 ◦ C for 1.5 h. The transport critical curr<strong>en</strong>tof the MgB 2 coils was measured with magnetic fields upto 10 T at various temperatures using a standard four probemethod. The critical curr<strong>en</strong>t d<strong>en</strong>sity, J c , of the coil was calculatedfrom the measured critical curr<strong>en</strong>t I c divided by thecross sectional area of the MgB 2 core.Figure 145 shows the 6-, 12- and 36-filam<strong>en</strong>taryMgB 2 /NbCu wires with amorphous carbon doping. Thevolume of MgB 2 in whole wires is around 20%, 14% and14%, respectively. Figure 146 shows the transport criticalcurr<strong>en</strong>t d<strong>en</strong>sity J c values as a function of applied field at20 K for the multi-filam<strong>en</strong>tary MgB 2 coils with amorphouscarbon or TiC doping. The 6-filam<strong>en</strong>t wires with carbondoping has the largest J c , as high as 4.5×10 4 A/cm 2 at 2 T.The large value of J c in this sample may be due to the goodgrain connectivity and strong flux pinning force. This resultindicates that carbon doping is b<strong>en</strong>eficial for the fabricationof high performance long l<strong>en</strong>gth multi filam<strong>en</strong>tary MgB 2wires.Figure 146: Transport critical curr<strong>en</strong>t d<strong>en</strong>sity of differ<strong>en</strong>t multi–filam<strong>en</strong>tary MgB 2 coils at T = 20 K.Figure 147 shows the result of the transport J c versus Hmeasurem<strong>en</strong>ts at temperatures from 4.2 to 30 K measuredfor 6-filam<strong>en</strong>t wires with carbon doping. This value islower than the best values found in the literature, but webelieve that the transport J c could be improved by optimizingvarious processing parameters.In summary, the J c of multi-filam<strong>en</strong>tary long l<strong>en</strong>gth MgB 2wires were <strong>en</strong>hanced by amorphous carbon doping. Thehighly reactive amorphous carbon can easily substitute intothe lattice of MgB 2 ev<strong>en</strong> with a heat-treatm<strong>en</strong>t at lower temperature.On the other hand, the lower heat-treatm<strong>en</strong>t temperatureresults in a smaller MgB 2 grain size, which introduceda high d<strong>en</strong>sity of flux-pinning c<strong>en</strong>ters.Figure 147: Transport critical curr<strong>en</strong>t d<strong>en</strong>sity of a 6-filam<strong>en</strong>tMgB 2 coil at various temperatures.E. MossangQ.Y. Wang, G. Yan (Northwest Institute for Non-Ferrous Metal Research, Xi’an, China), A. Sulpice (Institut Neel,Gr<strong>en</strong>oble102

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