2009 APPLIED SUPERCONDUCTIVITYPhthalocyanine doping to improve critical curr<strong>en</strong>t d<strong>en</strong>sities in MgB 2 tapesCarbohydrates show a promin<strong>en</strong>t capability in the criticalcurr<strong>en</strong>t, J c − B, <strong>en</strong>hancem<strong>en</strong>t of MgB 2 . It is claimed thatthese materials can decompose at relatively low temperature,and g<strong>en</strong>erate a lot of reactivate carbon atoms beforethe MgB 2 phase formation. The reactivate carbon atomsand small sized impurities are favorable for good superconductingproperties of MgB 2 . Compared to nano-sized C orSiC, carbohydrate doping can achieve a uniform dispersionwithin the MgB 2 matrix. As the insulated MgO particles arevery harmful to the MgB 2 grain connectivity, oxyg<strong>en</strong>-freecarbon compounds, which will not produce MgO by reactionwith MgB 2 , are preferable to use as MgB 2 dopants.In this work, we tried phthalocyanine (C 32 H 18 N 8 ), whichhas carbon 72.8-76.6%, nitrog<strong>en</strong> 21.1-22.3%, and no oxyg<strong>en</strong>cont<strong>en</strong>t, as MgB 2 doping material. The relationshipsbetwe<strong>en</strong> the critical curr<strong>en</strong>t properties, crystallinity, irreversibilityfield (H irr ) and upper critical field (H c2 ) werestudied as a function of the doping level of phthalocyanine.Figure 148 shows the field dep<strong>en</strong>d<strong>en</strong>ce of transport J cat 4.2 K for undoped and phthalocyanine-doped MgB 2 /Fetapes. Clearly, the in-field J c properties of MgB 2 tapes weremuch improved by the phthalocyanine doping, suggestingthat H c2 was <strong>en</strong>hanced. The best J c − B properties were obtainedin 2.2 wt% phthalocyanine-doped samples. At 4.2 Kand 10 T, a J c value higher than 1.6 × 10 4 A cm −2 wasachieved, which is almost an order of magnitude higherthan that for pure ones. On the other hand, wh<strong>en</strong> the phthalocyaninedoping amount increased to 3 wt%, the J c valuesstarted to decrease, while the field dep<strong>en</strong>d<strong>en</strong>ce was almostnot affected. This suggests that the excess phthalocyanineaddition will have a negative effect on the grainconnectivity and thus the coupling of MgB 2 grains, dueto the non-superconducting and g<strong>en</strong>erally insulating secondphases introduced by phthalocyanine addition.Figure 148: Transport J c − B properties of Fe-sheathed undopedand doped tapes heated at 800 ◦ C for 1 hour. The measurem<strong>en</strong>tswere performed in magnetic fields parallel to the tape surface at4.2 K.The normalized temperature dep<strong>en</strong>d<strong>en</strong>ce of H c2 and H irrfor all samples is shown in figure 149. Although the actualcarbon cont<strong>en</strong>ts in phthalocyanine-doped samples aresmall, the H c2 and H irr values of MgB 2 have be<strong>en</strong> greatly<strong>en</strong>hanced. For example, the H c2 and H irr of the 3 wt%phthalocyanine-doped sample at 24 K are 8.7 and 6 T, respectively,which is markedly higher than those of the undopedsamples.Figure 149: Normalized temperature dep<strong>en</strong>d<strong>en</strong>ce of H irr and H c2for undoped and phthalocyanine-doped samples sintered at 800 ◦ C.H c2 and H irr were defined as H c2 = 0.9R (T c ) and H irr = 0.1R (T c )from the R versus T curve.E. MossangX. Zhang, Y. Ma, D.Wang, , Z. Gao, L. Wang, Y. Qi (Institute of Electrical Engineering, Chinese Academy of Sci<strong>en</strong>ces,Beijing, China) S. Awaji, K. Watanabe (Institute for Materials Research, Tohoku University, S<strong>en</strong>dai, Japan)103
APPLIED SUPERCONDUCTIVITY 2009Critical curr<strong>en</strong>t measurem<strong>en</strong>ts on Bi-2212High critical temperature superconductors (HTS) op<strong>en</strong> extremelyinteresting perspectives for high magnetic field applicationssuch as high field magnets for NMR or SMES,nuclear fusion, or future colliders. The demand is high for25−50 T magnets which is beyond the possibilities offeredby low critical temperature superconductors, i.e. Nb 3 Sn.The possibility of precisely measuring the rather elevatedcritical curr<strong>en</strong>ts of superconductors in a high magnetic field<strong>en</strong>vironm<strong>en</strong>t is crucial for the developm<strong>en</strong>t of HTS magnets.(l<strong>en</strong>gth 30 mm) can be se<strong>en</strong> in figure 1. The results havebe<strong>en</strong> checked by performing cross characterizations at theSACM, CEA Saclay.Complete characterization of Bi-2212 and YBaCuO wiresand tapes at high magnetic fields and low temperatures(from 4.2 to 80 K) can be performed using this new VTI,which will be a very useful tool for the studies of HTS inthe frame of the SUPER-SMES project.Interest for Bi-2212 round wire for high magnetic field applicationsincreased rec<strong>en</strong>tly due to the wires outstandingperformance concerning their intrinsic transport properties.The critical curr<strong>en</strong>t d<strong>en</strong>sity is higher than 1000 MA/m 2at 4.2 K and 45 T. Equally the second g<strong>en</strong>eration (2G)of YBaCuO coated HTS conductors, show very promisingperformances in terms of critical curr<strong>en</strong>ts under very highmagnetic fields. In addition, their mechanical properties areexcell<strong>en</strong>t for the ion beam assisted deposition (IBAD) route.The mechanical performances are of great importance forvery high field magnets. Significant progress has also be<strong>en</strong>achieved in terms of l<strong>en</strong>gths, to the point where it it is nowpossible fabricate HTS magnets. The possibility to operateat higher temperatures than 4.2 K improves considerablythe stability of the magnet due to the rapid increase of thespecific heat at higher temperatures. The stability is one ofthe limitations of LTS magnets in term stored magnetic <strong>en</strong>ergyper unit mass. On the other hand the protection of themagnet is much more difficult since the propagation velocitiesare low, leading to a difficult detection of any qu<strong>en</strong>ch.HTS magnet protection has be<strong>en</strong> id<strong>en</strong>tified as an issue fortheir developm<strong>en</strong>t.The HTS wires (BiSrCaCuO PIT or YBaCuO coated conductor)are produced by Nexans or other providers (suchas OST). The typical cross section of the tapes is 4 ×0.1/0.2 mm 2 and a diameter of 1 mm for the round wires.The critical curr<strong>en</strong>t is of the order of ∼ 500 A in theself-field at 4.2 K. In the frame of the ANR “SUPERSMES” contract, a new Variable Temperature Insert hasbe<strong>en</strong> built in collaboration betwe<strong>en</strong> LNCMI and the NéelInstitute. The available space has be<strong>en</strong> optimized to maximizethe sample l<strong>en</strong>gth: a 34 mm long sample can betested in the 39 mm diameter field bore. An investigationof the sample anisotropy is possible, since the sample canbe rotated through 90 ◦ . Critical curr<strong>en</strong>ts are measured atthe LNCMI under fields up to 20 T. The sample holderhas be<strong>en</strong> <strong>des</strong>igned to <strong>en</strong>able measurem<strong>en</strong>ts on a VAMASlikecoil sample. Preliminary measurem<strong>en</strong>ts performed onBi-2212 VAMAS sample (l<strong>en</strong>gth 1 m) and short samplesFigure 150: (a) Transport I c versus magnetic field at differ<strong>en</strong>ttemperatures in parallel ori<strong>en</strong>tation for a VAMAS Bi-2212 tape.(b) Transport I c versus magnetic field at differ<strong>en</strong>t temperatures inparallel ori<strong>en</strong>tation for a short Bi-2212 sample.E. Mossang, F. Debray, J.P. Domps, S. DufresnesP. Brosse-Maron, O. Exshaw, P. Gandit, L. Porcar, P. Tixador (Institut Néel, CNRS, Gr<strong>en</strong>oble, France), J.M. Rey(DSM-DAPNIA-SACM, CEA Saclay, France)104
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LABORATOIRE NATIONAL DES CHAMPS MAG
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TABLE OF CONTENTSPreface 1Carbon Al
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Coexistence of closed orbit and qua
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2009PrefaceDear Reader,You have bef
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2009 CARBON ALLOTROPESInvestigation
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2009 CARBON ALLOTROPESPropagative L
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2009 CARBON ALLOTROPESEdge fingerpr
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2009 CARBON ALLOTROPESObservation o
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2009 CARBON ALLOTROPESImproving gra
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2009 CARBON ALLOTROPESHow perfect c
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2009 CARBON ALLOTROPESTuning the el
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2009 CARBON ALLOTROPESElectric fiel
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2009 CARBON ALLOTROPESMagnetotransp
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2009 CARBON ALLOTROPESGraphite from
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2009Two-Dimensional Electron Gas25
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TWO-DIMENSIONAL ELECTRON GAS 2009Di
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TWO-DIMENSIONAL ELECTRON GAS 2009Sp
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TWO-DIMENSIONAL ELECTRON GAS 2009Cr
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TWO-DIMENSIONAL ELECTRON GAS 2009Re
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TWO-DIMENSIONAL ELECTRON GAS 2009In
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TWO-DIMENSIONAL ELECTRON GAS 2009Ho
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TWO-DIMENSIONAL ELECTRON GAS 2009Te
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2009 SEMICONDUCTORS AND NANOSTRUCTU
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2009 SEMICONDUCTORS AND NANOSTRUCTU
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2009 SEMICONDUCTORS AND NANOSTRUCTU
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2009 SEMICONDUCTORS AND NANOSTRUCTU
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2009 SEMICONDUCTORS AND NANOSTRUCTU
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