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th  - 1988 - 51st ENC Conference

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A New Model for Hartmann-Hahn<br />

Cross Relaxation in NI,iR<br />

Wu Xiaoling , Zhang Shanmin and Wu Xuewen<br />

Department of Physics, East China Normal University,<br />

Shanghai 200062, P.R.China<br />

Ab s tract<br />

It was found out for <strong>th</strong>e first time <strong>th</strong>at Hartmann-I{ahn<br />

cross relaxation between rare and abundant spins in IZ~.~ proceeds<br />

in two stages: first, a fast energy exchange between each rare<br />

spin S and its directly bonded I spins, and <strong>th</strong>en, a much slower<br />

one between <strong>th</strong>ese SI subsystems and remaining I spins. During<br />

n<br />

<strong>th</strong>e cross relaxation, especially in <strong>th</strong>e first stage, <strong>th</strong>e I spin<br />

system is not always in a quasiequilibrium state and so is not<br />

always describable by a single temperature.<br />

122

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