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th  - 1988 - 51st ENC Conference

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THU 10"2S I<br />

NEW TECHNIQUES POR<br />

DYNAMIC NUCLEAR POLARIZATION<br />

W.Th. W<strong>ENC</strong>KEBACH<br />

KAMERLINGH ONNES LABORATORY, P.O.BOX 9506,<br />

2300 RA LEIDEN, THE NETHERLANDS<br />

Two new techniques for dynamic nuclear polarization have recently been<br />

developed: Microwave induced optical nuclear polarization (MIONP) and<br />

nuclear orientation via electron spin lock (NOVEL). In <strong>th</strong>e first technique<br />

photoexcited states wi<strong>th</strong> an electron spin are used to polarize nuclear spins.<br />

As in classical dynamic nuclear polarization <strong>th</strong>e electron spin polarization<br />

k transferred to <strong>th</strong>e nuclear spins using cw microwave irradiation. In <strong>th</strong>e<br />

second technique <strong>th</strong>e electron spin polarization is transferred by means of<br />

pulsed microwave techniquea First <strong>th</strong>e electron spin is locked by a ~-pulse<br />

followed by a ~--phase shift. Then <strong>th</strong>e nuclear spins and <strong>th</strong>e electron spins<br />

are brought to mutual resonance by choosing <strong>th</strong>e Rabi frequency of <strong>th</strong>e<br />

latter equal to Larmor frequency of <strong>th</strong>e former. As a result polarization<br />

tr-~uffer ~ obee~ed.<br />

67

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