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_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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N

o ,.....

6-electron

ry 6 -benzene

Metal atom1c orbitals

with correct symmetry

to overlap with the

M.O.s of ligands

~ ~~~

"*' ~ 1

npx npy

** ~~

np In 1) de (n 1\ d. (rl 1) d

~

~

o

~

(n -1)dx 2 -y'

~l)d"

Fig. 6. 7 Representation of ligand n-molecular orbitals and their possible interactions with metal orbitals. The highest energy benzene m.o

is omitted as it makes little or no contribution to bonding.

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