_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

Contents
7.3 Complexes of alkenes
7.4 Complexes of alkynes
7. 5 References
Problems
237
243
248
249
8. Allyl and diene complexes of the transition elements 253
8.1 Allyl (-enyl) complexes 253
8.2 Diene complexes 263
8.3 References 272
Problems 2 7 2
9. Five electron ligands 278
9.1 Introduction 278
9.2 Bis(cyclopentadienyl) complexes- the metallocenes 279
9.3 Cyclopentadienylmetal carbonyls 292
9.4 Open-chain (acyclic) pentadienyl complexes 301
9.5 Cyclohexadienyltricarbonyliron salts 303
9.6 References 304
Problems 30 5
1 O. Complexes of arenes 311
10.1 Bis( arene )complexes 311
10.2 Arene(tricarbonyl)chromium complexes 316
10.3 Chemistry of some arene complexes of iron 320
10.4 Nucleophilic attack on organotransition metal complexes 321
10.5 tJ 6 -Cycloheptatriene and ry 7 -tropylium complexes 330
10.6 References 331
Problems 3 32
11. Cluster compounds 3 3 5
11.1 Introduction 335
11.2 11.3 11.4 11.5 11.6 11.7
Structure and bonding
Carboranes
Metallocarboranes and metalloboranes
Transition metal clusters
Clusters and catalysis
335
344
348
352
355
355
References
Problems
340
12. Mechanisms of industrial processes clarified by studies of
homogeneous catalysis by complexes of transition elements
12.1 Introduction
12.2 Resources
12.3 Catalysis of reactions of alkenes by transition metal
complexes
357
357
361
361
vii