_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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IndexEthylene glycol. see Ethane-1.2-diol2-Ethylhexanol. 388Ethyne, see AlkynesFeedstocks, for industrial processes,360-2, 373-4, 383-5. 391. 393Ferricenium ion, 282Ferrocenebonding in, 199-205. 281'open-chain', 302reactions, 281-6structure, 2 79-80Fischer-Tropsch reaction, 3 9 3-5Fluorenyl complexes, 194Fragment analysis, 206-11Fragments, isolobal. 210, 348-9Friedel Crafts reaction, 102. 126. 26S,269, 271. 283Frontier orbitals. 33 7. 348, sec alsoFragment analysisFungicides, 109, 132Galliumalkyls and aryls, 23, 34, 82-7arene complexes, 93-4arsenide, 83, 84thermochemical data, 6, lOGermaniumalkyls, 99catenated derivatives, 120cyclopentadienyls, 122divalent compounds, 123multiple bonding to. 111organohalides, 102, 116thermochemical data, 6, 1 O. 215Glucose, determination in blood, 282Gold complexes, 39, 213-14clusters, 3 54-5Green's rules, 326-30Grignard reagentsdiscovery, l. 50preparation. 17, 50-1reactions, 22, 59, 60, 99, 21Sstructure. 51-4Hapto number (li'). 191Heck reaction, 182. 229Hein's phenylchromium complexes, 314Hexamethyldisilane, 118Hexamethyldisiloxane, 111HOMO. 157Hiickel energies of ligand orbitals.199-202Hydroboration. 66-72Hydrocarbon anions. 4, 49Hydroformylation, see CatalysisHydrogencomplexes, see Dihydrogen, complexesstorage, 93transferCI.-. 11. 35. 220-3fî-. 11, 35, 54, 66, 81.217-20y- and b- . 223Hydrogenation, see CatalysisHydrosilation, 24, 11 5Hydrostannation, 24, 108Hydrozirconation, 290-1Indiumalkyls and aryls. 34-5, 86-7arene complexes, 93-4cyclopentadienyls, 92Tnfrared spectra ofboron compounds. 78, 343carbonyl hydrides, 1 72metal carbonyls, 158-62tin compounds, 108l nsertion ofC 2 H 4 , 2 5, 48. 80, 182, 229, 364,371-3CO. migratory, 225-7. 242. 297. 395MCI, 26. 6 3-5MH (Main Group). 22-4. 54. 66-9.76. 108. 116MH (transition metal), 184, 290, 362,387-91MN. 25. 108lonic character of M-C bonds, 2-4, 49Iridium complexescarbonyls, 153. 1 54in C-H bond activation. 186. 224-5see also Vaska's compoundIron complexesalkene, 238, 240-3alkyl. 240-3alkyne, 245allyl. 265. 271azulene, 3 31carbonyls. 153-4. 158-9. 168, 169.170-1. 172. 1 7 3carborane, 344. 346. 34 7cyclobutadiene. 269-70409
IndexIron complexes contd.cyclohexadienyl. 303-4cyclo-octadiene, 2 3 8cyclo-octatetraene, 19 3cyclopentadienyl, 240-3, 295-9, seealso Ferrocenediene, 263-6pentadienyl, 302trimethylenemethane, 2 71Isomerization of alkenes, see CatalysisIsoprene, 48, 82lsotactic polymers, 3 72Job-Cassels reaction, 214Knoevenagel condensation, 284/3-Lactams, 242Lanthanides, 399cyclo-octatetraene complexes, 402-3cyclopentadienyls, 400-2Lanthanum, see LanthanidesLeadalkyls, 27, 100, 121arene complexes, 9 3bis(cyclopentadienyl). 122-lead bonded derivatives, 120organohalides, 102-4plumbonic acids, 117thermochemical data, 5, 6, 10, 215Lewisite, 134Ligand-acceptor/donor properties, 149, 151classification, 191-4substitution, mechanisms of, 16 7-8Lithiumalkyls and aryls, 17, 39-43addition to alkenes, 46association, 36-8attack on ethers, 41complexes, 3 6-8reactions, 22, 44-9, 215ferrocenyl. 284-5triphenylsilyl, 119LUMO. 157Lurgi process. 383, 384Lutetium, see LanthanidesMagnesium, 35, see also Grignardreagentsarene complexes, 9 3bis(cyclopentadienyl), 90-1Manganese complexesacyl, 225-7alkyl, 173, 225-7allyl, 253-6arene, 321-6carbonyls, 153, 154, 166, 172-3cyclopentadienyl. 294, see alsoManganocenesindenyl. 294Manganocenes, 274, 280, 281Mass spectraof boron compounds, 79of metal carbonyls, 162-3Matrix isolation, 9, 122, 166, 270Mercurationof alkenes and alkynes, 63of aromatic compounds, 62of ferrocene, 284Mercuryalkyls, 17, 19, 20, 26, 27, 35, 44, 49,56alkyl halides, 60aryl halides, 27. 60cyclopentadienyls, 91-2methyl metal, 60thermochemistry, 6, 10, 19trihalomethyls, 61uses in organic synthesis, 60-5Metal atom synthesis, 18, 166, 313Metal carbonyl anions, 166, 170-2, 216Metal carbonyl complexes, seeCyclopentadienyl metal carbonylcomplexes; Metal carbonyl anionsbond dissociation energies, 16 3, 164bonding in, 156-8bond lengths, 163, 165clusters, 167, 351-3mass spectra, 162-3polynuclear, 16 7preparation, 165-7reactions, 16 7-7 3structures, 152-6vibrational spectra, 158-62Metal carbonyl halides, 16 7, 173Metal-halogen exchange, 40Metal-hydrogen exchange, 40-3Metallacyclobutanes, 3 7 5Metalloboranes, 344-8Metallocarboranes, 344-8Metallocenes, 2 79-9 2bonding~. 199-205,281magnetic properties, 280410
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Principles ofOrganometallicChemistr
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© 1988 P. PowellOriginally publish
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Contentsvi3.5 Beryllium 543.6 Calci
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Contents12.4 Chemistry based on syn
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PrefaceIn the 20 years since 'Princ
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Periodic table ofthe elementsThe pe
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Periodic table of elementsGroup Gro
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General surveysyntheses. They are a
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General surveypacked hexagonal, nic
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Table 1.1. Mean metal-carbon bond d
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General survey(c) COMPLEXES OF UNSA
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General survey4008.0o1E...,300.=; 2
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General surveyelements are rapidly
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General surveyCollman, J.P., Hegedu
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100o-100o Si110111Ql-200 . 1L. :1o
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The main group elementsFor R = alky
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The main group elementsweakly exoth
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The main group elementselement and
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The main group elements(a) HYDROSIL
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The main group elementsinsertion:-
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The rnain group elernentsElectrophi
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The first three periodic groupsTabl
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The first three periodic groupstran
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The first three periodic groups(o)(
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The first three periodic groups( b)
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The first three periodic groupsorga
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The first three periodic groupsMe M
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The first three periodic groupsH HE
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The first three periodic groupsThis
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The first three periodic groupsHere
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The first three periodic groupselec
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The first three periodic groupsEt~5
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The first three periodic groupscond
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The first three periodic groupsThe
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1 2·65 1 9-...:..... _;.;;.-c 1·4
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The first three periodic groupsCycl
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The first three periodic groups3. 7
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The first three periodic groupsYe\
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The first three periodic groupsor o
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Table 3.6 Some hydroborating agents
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RCf:0~HH~RCHO2 2Hi~OH-"' 18-C-R/ 1o
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The first three periodic groups(c)
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The first three periodic groupsTHF.
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The first three periodic groupspuls
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The first three periodic groupsROH/
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The first three periodic groupsthe
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The first three periodic groupsThe
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The first three periodic groupsin p
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The first three periodic groupsSilv
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The first three periodic groupso-RR
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The first three periodic groups(a)(
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The first three periodic groups5. W
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4Organometallic compoundsof element
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The main Groups IV and Vachieved e.
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The main Groups IV and Ve.g. alipha
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The main Groups IV and VDimethyltin
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The main Groups IV and V4.3.3 React
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The main Groups IV and Villustrates
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The main Groups IV and Vof methylco
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The main Groups IV and VTable 4.1.
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The main Groups IV and Vanes) are s
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The main Groups IV and Vconcentrati
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The main Groups IV and VTable 4.2.
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The main Groups IV and V4.6.3 Caten
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The main Groups IV and VTreatment o
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The main Groups IV and V4.8 pTC-JJT
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The main Groups IV and VA convenien
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The main Groups IV and Vfu- +( + )[
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The main Groups IV and Vand Me 2 PF
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The main Groups IV and VAcidH 2 PO(
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The main Groups IV and Vin World Wa
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The main Groups IV and VHX(SblPh M
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The main Groups IV and VOn replacem
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The main Groups IV and Varsenic yli
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The main Groups IV and VPh 2 BiBiPh
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The main Groups IV and Vphosphorus
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The main Groups IV and VDimethyltin
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5Some transition metalchemistry rel
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M L--4----f/~1 11 1\ 11 11 1\ 11 11
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Transition metal chemistryeven nega
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co co co cooc~o o co c~co cooc~c~ o
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Transition metal chemistryeach othe
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Transition metal chemistryconsidere
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Transition metal chemistryTable 5.3
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Transition metal chemistryTable 5.5
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Table 5.7. Thermochemical data and
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Transition metal chemistryNickel is
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Transition metal chemistry(o)(OC ln
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Transition metal chemistryCarbonyl
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Transition metal chemistry2Cr(COJ6
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Transition metal chemistry18-electr
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Table 5.8. General reactions of tra
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Transition metal chemistry5. 3.1 Ad
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Transition metal chemistrynot detec
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Transition metal chemistryPd(PPhBu~
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Transition metal chemistryH2 -LL3Rh
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Transition metal chemistryPhosphine
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Transition metal chemistry(d) Comme
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Transition metal chemistryD: 1 Hn.m
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Organometallic compounds of the tra
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No3-electron1] 3 -allyl4-electron17
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Organotransition metal chemistrymel
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Organotransition metal chemistryii)
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Table 7.2. Mechanisms of decomposit
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Organotransition metal chemistry4Ti
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Organotransition metal chemistryM e
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Organotransition metal chemistryIn
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Organotransition metal chemistryThe
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Organotransition metal chemistry~ (
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Organotransition metal chemistryo o
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Organotransition metal chemistry( C
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Organotransition metal chemistryMe
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Organotransition metal chemistry/OM
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Organotransition metal chemistry7.3
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Organotransition metal chemistryexc
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Organotransition metal chemistrysev
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Organotransition metal chemistry)--
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Organotransition metal chemistryR R
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Organotransition metal chemistry-co
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Organotransition metal chemistry4.
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Organotransition metal chemistry(b)
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r~...I.J::...--Î-..L-.._.,:;.I""'
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Allyl and diene complexessignals ar
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Allyl and diene complexesdoublets.
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Allyl and diene complexes111.5°. A
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Allyl and diene complexesThe pallad
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Allyl and diene complexesFe(C0} 5-F
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Allyl and diene complexes~4,neutrat
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Allyl and diene complexesThis indic
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Allyl and diene complexesonly with
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Allyl and diene complexesderivative
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Allyl and diene complexesvolatile,l
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Allyl and diene complexesChemical R
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9Five electron ligands9.1 lntroduct
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Five electron ligandsTable 9.1 The
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Five electron ligandsthe ferriceniu
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Five electron ligandsFerrocene unde
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Five electron ligands---v~···Fe,
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Five electron ligandsDihalogenometh
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Five electron ligands(c) TITANOCENE
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Five electron ligandsa pair of non-
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Five electron ligands9. 3.1 Mononuc
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Five electron ligandsslowly oxidize
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~ o coo,... ...,C,, /....-:;.' //Fe
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Five electron ligandsn-system of ea
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Five electron ligandsFig. 9.15 Mole
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Five electron ligandsNucleophilic r
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Five electron ligands(a) Sketch the
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lCH2=CHC2H5Five electron ligands(i)
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Five electron ligands( 6 A 1 g) and
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Complexes of arenesFor chromium thi
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Complexes of arenesW(C 6 H 6 ) 2
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Complexes of arenesgas phase (5.01
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Complexes of arenes(Q)-RCr cr(C0)
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Complexes of arenes- BH 3~jCr(C0) 3
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Complexes of arenesif"••d•R"x
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wNfoi::>.~7trienyl Cr(C0) 3~·trien
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Complexes of arenesmethyl iodide. T
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Complexes of arenesin the whole mol
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Complexes of arenesproposed above,
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Complexes of arenesProblems1. Ferro
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Complexes of arenes(<) ~PlMe~MeMe~M
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Table 11.1. Electron counting in cl
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Cluster compounds455TrigonalOctahed
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Cluster compoundsFig. 11.4 Closo, a
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Cluster compoundsmixture of the mor
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Cluster compoundsIt is extremely st
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Cluster compounds2- 2-~ m1 11O GQ8-
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Cluster compounds(IJ 5 -C,B,H 6 )Mn
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wUlo2-Fe(C0) 5redu cine;~C 7 H~BF4-
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Cluster compoundsdensations' do not
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Cluster compoundsA 3 A 78 78 12A 3c
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Cluster compoundsstructures of the
Page 372 and 373: Mechanisms of industrial processesT
Page 374 and 375: Table 12.2.Process Feedstock Cataly
Page 376 and 377: Mechanisms of industrial processesF
Page 378 and 379: Mechanisms of industrial processes1
Page 380 and 381: chaingrowth(alkeneinsertion)CH 3 CH
Page 382 and 383: r!~~NiJy ~ ' ,. -;,,.,~,;, ..'Ni'+2
Page 384 and 385: ţ/Ph)o-cPd =:) )cH0-C'-....Ph 2~-8
Page 386 and 387: Mechanisms of industrial processesH
Page 388 and 389: H2 C=CH2H2C=CH2[Ti]-R + C2H4coordin
Page 390 and 391: o[~] o ~ [f!- ~7:Jlinear[w]=CH~poly
Page 392 and 393: Me3 CCH2Li3HCI/WCL 6 W(=CBut)(CH2 B
Page 394 and 395: Mechanisms of industrial processesW
Page 396 and 397: Mechanisms of industrial processesT
Page 398 and 399: ••~'"'"'" 7 ~;~13 :H~ r--------
Page 400 and 401: Mechanisms of industrial processesc
Page 402 and 403: Mechanisms of industrial processesO
Page 404 and 405: Mechanisms of industrial processesc
Page 406 and 407: Mechanisms of industrial processesH
Page 408 and 409: a)oIIIc1c1o1H /H'-cH2 ,l!--1 --H'.
Page 410 and 411: Mechanisms of industrial processesB
Page 412 and 413: Mechanisms of industrial processes5
Page 414 and 415: Lanthanides and actinidesA few exam
Page 416 and 417: Lanthanides and actinidesCp~LuCH 3
Page 418 and 419: IndexOrganometallic compounds are i
Page 420 and 421: IndexCarbon monoxide contd.bonding
Page 424 and 425: IndexMetallocenes contd.reactions,
Page 426 and 427: IndexSilicon contd.-silicon bonded
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_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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