_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

Allyl and diene complexes
Chemical Relative *Coupling
shift/b intensity Multiplicity constants/Hz
Compound B
1.5 3 doublet 6.0
2.0 3 doublet l.O(Rh)
3.1 1 doublet 2.0
3.6 1 doublet 2.0
4.6 1 quartet (1:3:3:1) 6.0
Compound C
1.8 3 doublet 6.0
2.0 1 doublet 2.0
2.1 3 doublet l.O(Rh)
3.2 1 doublet 2.0
3.5 1 quartet (1:3:3:1) 6.0
*Proton-proton coupling constants, unless otherwise indicated.
(Royal Holloway College)
8. The adduct formed between (IJ'-C,H 5 ) 2Pd and PMe, has been studied by
proton n.m.r. from -109° to - 3°C. Propose a structure for the 'frozen' adduct
6 9 7 2 3
4
-109 oc
-93°
-77°
-61°
....__
1
t
1
/'
-45°
-24°
-30
ii 6 5 4 3 2
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