_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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Principles ofOrganometallicChemistry
P. POWELLPrinciples ofOrganometallicChemistrySecondeditionSpringer -Sciencet B usiness Media, B. V.
Page 4 and 5: © 1988 P. PowellOriginally publish
Page 6 and 7: Contentsvi3.5 Beryllium 543.6 Calci
Page 8 and 9: Contents12.4 Chemistry based on syn
Page 10 and 11: PrefaceIn the 20 years since 'Princ
Page 12 and 13: Periodic table ofthe elementsThe pe
Page 14 and 15: Periodic table of elementsGroup Gro
Page 16 and 17: General surveysyntheses. They are a
Page 18 and 19: General surveypacked hexagonal, nic
Page 20 and 21: Table 1.1. Mean metal-carbon bond d
Page 22 and 23: General survey(c) COMPLEXES OF UNSA
Page 24 and 25: General survey4008.0o1E...,300.=; 2
Page 26 and 27: General surveyelements are rapidly
Page 28 and 29: General surveyCollman, J.P., Hegedu
Page 30 and 31: 100o-100o Si110111Ql-200 . 1L. :1o
Page 32 and 33: The main group elementsFor R = alky
Page 34 and 35: The main group elementsweakly exoth
Page 36 and 37: The main group elementselement and
Page 38 and 39: The main group elements(a) HYDROSIL
Page 40 and 41: The main group elementsinsertion:-
Page 42 and 43: The rnain group elernentsElectrophi
Page 44 and 45: The first three periodic groupsTabl
Page 46 and 47: The first three periodic groupstran
Page 48 and 49: The first three periodic groups(o)(
Page 50 and 51: The first three periodic groups( b)
Page 52 and 53:
The first three periodic groupsTabl
Page 54 and 55:
The first three periodic groupsorga
Page 56 and 57:
The first three periodic groupsMe M
Page 58 and 59:
The first three periodic groupsH HE
Page 60 and 61:
The first three periodic groupsThis
Page 62 and 63:
The first three periodic groupsHere
Page 64 and 65:
The first three periodic groupselec
Page 66 and 67:
The first three periodic groupsEt~5
Page 68 and 69:
The first three periodic groupscond
Page 70 and 71:
The first three periodic groupsThe
Page 72 and 73:
1 2·65 1 9-...:..... _;.;;.-c 1·4
Page 74 and 75:
The first three periodic groupsCycl
Page 76 and 77:
The first three periodic groups3. 7
Page 78 and 79:
The first three periodic groupsYe\
Page 80 and 81:
The first three periodic groupsor o
Page 82 and 83:
Table 3.6 Some hydroborating agents
Page 84 and 85:
RCf:0~HH~RCHO2 2Hi~OH-"' 18-C-R/ 1o
Page 86 and 87:
Page 88 and 89:
The first three periodic groups(c)
Page 90 and 91:
The first three periodic groupsTHF.
Page 92 and 93:
Page 94 and 95:
The first three periodic groupspuls
Page 96 and 97:
The first three periodic groupsROH/
Page 98 and 99:
The first three periodic groupsthe
Page 100 and 101:
The first three periodic groupsThe
Page 102 and 103:
The first three periodic groupsin p
Page 104 and 105:
The first three periodic groupsSilv
Page 106 and 107:
The first three periodic groupso-RR
Page 108 and 109:
The first three periodic groups(a)(
Page 110 and 111:
The first three periodic groups5. W
Page 112 and 113:
4Organometallic compoundsof element
Page 114 and 115:
The main Groups IV and Vachieved e.
Page 116 and 117:
The main Groups IV and Ve.g. alipha
Page 118 and 119:
The main Groups IV and VDimethyltin
Page 120 and 121:
The main Groups IV and V4.3.3 React
Page 122 and 123:
The main Groups IV and Villustrates
Page 124 and 125:
The main Groups IV and Vof methylco
Page 126 and 127:
The main Groups IV and VTable 4.1.
Page 128 and 129:
The main Groups IV and Vanes) are s
Page 130 and 131:
The main Groups IV and Vconcentrati
Page 132 and 133:
The main Groups IV and VTable 4.2.
Page 134 and 135:
The main Groups IV and V4.6.3 Caten
Page 136 and 137:
The main Groups IV and VTreatment o
Page 138 and 139:
The main Groups IV and V4.8 pTC-JJT
Page 140 and 141:
The main Groups IV and VA convenien
Page 142 and 143:
The main Groups IV and Vfu- +( + )[
Page 144 and 145:
The main Groups IV and Vand Me 2 PF
Page 146 and 147:
The main Groups IV and VAcidH 2 PO(
Page 148 and 149:
The main Groups IV and Vin World Wa
Page 150 and 151:
The main Groups IV and VHX(SblPh M
Page 152 and 153:
The main Groups IV and VOn replacem
Page 154 and 155:
The main Groups IV and Varsenic yli
Page 156 and 157:
The main Groups IV and VPh 2 BiBiPh
Page 158 and 159:
The main Groups IV and Vphosphorus
Page 160 and 161:
The main Groups IV and VDimethyltin
Page 162 and 163:
5Some transition metalchemistry rel
Page 164 and 165:
M L--4----f/~1 11 1\ 11 11 1\ 11 11
Page 166 and 167:
Transition metal chemistryeven nega
Page 168 and 169:
co co co cooc~o o co c~co cooc~c~ o
Page 170 and 171:
Transition metal chemistryeach othe
Page 172 and 173:
Transition metal chemistryconsidere
Page 174 and 175:
Transition metal chemistryTable 5.3
Page 176 and 177:
Transition metal chemistryTable 5.5
Page 178 and 179:
Table 5.7. Thermochemical data and
Page 180 and 181:
Transition metal chemistryNickel is
Page 182 and 183:
Transition metal chemistry(o)(OC ln
Page 184 and 185:
Transition metal chemistryCarbonyl
Page 186 and 187:
Transition metal chemistry2Cr(COJ6
Page 188 and 189:
Transition metal chemistry18-electr
Page 190 and 191:
Table 5.8. General reactions of tra
Page 192 and 193:
Transition metal chemistry5. 3.1 Ad
Page 194 and 195:
Transition metal chemistrynot detec
Page 196 and 197:
Transition metal chemistryPd(PPhBu~
Page 198 and 199:
Transition metal chemistryH2 -LL3Rh
Page 200 and 201:
Transition metal chemistryPhosphine
Page 202 and 203:
Transition metal chemistry(d) Comme
Page 204 and 205:
Transition metal chemistryD: 1 Hn.m
Page 206 and 207:
Organometallic compounds of the tra
Page 208 and 209:
Page 210 and 211:
Page 212 and 213:
Page 214 and 215:
No3-electron1] 3 -allyl4-electron17
Page 216 and 217:
Page 218 and 219:
Page 220 and 221:
Page 222 and 223:
Page 224 and 225:
Page 226 and 227:
Page 228 and 229:
Organotransition metal chemistrymel
Page 230 and 231:
Organotransition metal chemistryii)
Page 232 and 233:
Table 7.2. Mechanisms of decomposit
Page 234 and 235:
Organotransition metal chemistry4Ti
Page 236 and 237:
Organotransition metal chemistryM e
Page 238 and 239:
Organotransition metal chemistryIn
Page 240 and 241:
Organotransition metal chemistryThe
Page 242 and 243:
Organotransition metal chemistry~ (
Page 244 and 245:
Organotransition metal chemistryo o
Page 246 and 247:
Organotransition metal chemistry( C
Page 248 and 249:
Organotransition metal chemistryMe
Page 250 and 251:
Organotransition metal chemistry/OM
Page 252 and 253:
Organotransition metal chemistry7.3
Page 254 and 255:
Organotransition metal chemistryexc
Page 256 and 257:
Organotransition metal chemistrysev
Page 258 and 259:
Organotransition metal chemistry)--
Page 260 and 261:
Organotransition metal chemistryR R
Page 262 and 263:
Organotransition metal chemistry-co
Page 264 and 265:
Organotransition metal chemistry4.
Page 266 and 267:
Organotransition metal chemistry(b)
Page 268 and 269:
r~...I.J::...--Î-..L-.._.,:;.I""'
Page 270 and 271:
Allyl and diene complexessignals ar
Page 272 and 273:
Allyl and diene complexesdoublets.
Page 274 and 275:
Allyl and diene complexes111.5°. A
Page 276 and 277:
Allyl and diene complexesThe pallad
Page 278 and 279:
Allyl and diene complexesFe(C0} 5-F
Page 280 and 281:
Allyl and diene complexes~4,neutrat
Page 282 and 283:
Allyl and diene complexesThis indic
Page 284 and 285:
Allyl and diene complexesonly with
Page 286 and 287:
Allyl and diene complexesderivative
Page 288 and 289:
Allyl and diene complexesvolatile,l
Page 290 and 291:
Allyl and diene complexesChemical R
Page 292 and 293:
9Five electron ligands9.1 lntroduct
Page 294 and 295:
Five electron ligandsTable 9.1 The
Page 296 and 297:
Five electron ligandsthe ferriceniu
Page 298 and 299:
Five electron ligandsFerrocene unde
Page 300 and 301:
Five electron ligands---v~···Fe,
Page 302 and 303:
Five electron ligandsDihalogenometh
Page 304 and 305:
Five electron ligands(c) TITANOCENE
Page 306 and 307:
Five electron ligandsa pair of non-
Page 308 and 309:
Five electron ligands9. 3.1 Mononuc
Page 310 and 311:
Five electron ligandsslowly oxidize
Page 312 and 313:
~ o coo,... ...,C,, /....-:;.' //Fe
Page 314 and 315:
Five electron ligandsn-system of ea
Page 316 and 317:
Five electron ligandsFig. 9.15 Mole
Page 318 and 319:
Five electron ligandsNucleophilic r
Page 320 and 321:
Five electron ligands(a) Sketch the
Page 322 and 323:
lCH2=CHC2H5Five electron ligands(i)
Page 324 and 325:
Five electron ligands( 6 A 1 g) and
Page 326 and 327:
Complexes of arenesFor chromium thi
Page 328 and 329:
Complexes of arenesW(C 6 H 6 ) 2
Page 330 and 331:
Complexes of arenesgas phase (5.01
Page 332 and 333:
Complexes of arenes(Q)-RCr cr(C0)
Page 334 and 335:
Complexes of arenes- BH 3~jCr(C0) 3
Page 336 and 337:
Complexes of arenesif"••d•R"x
Page 338 and 339:
wNfoi::>.~7trienyl Cr(C0) 3~·trien
Page 340 and 341:
Complexes of arenesmethyl iodide. T
Page 342 and 343:
Complexes of arenesin the whole mol
Page 344 and 345:
Complexes of arenesproposed above,
Page 346 and 347:
Complexes of arenesProblems1. Ferro
Page 348 and 349:
Complexes of arenes(<) ~PlMe~MeMe~M
Page 350 and 351:
Table 11.1. Electron counting in cl
Page 352 and 353:
Cluster compounds455TrigonalOctahed
Page 354 and 355:
Cluster compoundsFig. 11.4 Closo, a
Page 356 and 357:
Cluster compoundsmixture of the mor
Page 358 and 359:
Cluster compoundsIt is extremely st
Page 360 and 361:
Cluster compounds2- 2-~ m1 11O GQ8-
Page 362 and 363:
Cluster compounds(IJ 5 -C,B,H 6 )Mn
Page 364 and 365:
wUlo2-Fe(C0) 5redu cine;~C 7 H~BF4-
Page 366 and 367:
Cluster compoundsdensations' do not
Page 368 and 369:
Cluster compoundsA 3 A 78 78 12A 3c
Page 370 and 371:
Cluster compoundsstructures of the
Page 372 and 373:
Mechanisms of industrial processesT
Page 374 and 375:
Table 12.2.Process Feedstock Cataly
Page 376 and 377:
Mechanisms of industrial processesF
Page 378 and 379:
Mechanisms of industrial processes1
Page 380 and 381:
chaingrowth(alkeneinsertion)CH 3 CH
Page 382 and 383:
r!~~NiJy ~ ' ,. -;,,.,~,;, ..'Ni'+2
Page 384 and 385:
ţ/Ph)o-cPd =:) )cH0-C'-....Ph 2~-8
Page 386 and 387:
Mechanisms of industrial processesH
Page 388 and 389:
H2 C=CH2H2C=CH2[Ti]-R + C2H4coordin
Page 390 and 391:
o[~] o ~ [f!- ~7:Jlinear[w]=CH~poly
Page 392 and 393:
Me3 CCH2Li3HCI/WCL 6 W(=CBut)(CH2 B
Page 394 and 395:
Mechanisms of industrial processesW
Page 396 and 397:
Mechanisms of industrial processesT
Page 398 and 399:
••~'"'"'" 7 ~;~13 :H~ r--------
Page 400 and 401:
Mechanisms of industrial processesc
Page 402 and 403:
Mechanisms of industrial processesO
Page 404 and 405:
Mechanisms of industrial processesc
Page 406 and 407:
Mechanisms of industrial processesH
Page 408 and 409:
a)oIIIc1c1o1H /H'-cH2 ,l!--1 --H'.
Page 410 and 411:
Mechanisms of industrial processesB
Page 412 and 413:
Mechanisms of industrial processes5
Page 414 and 415:
Lanthanides and actinidesA few exam
Page 416 and 417:
Lanthanides and actinidesCp~LuCH 3
Page 418 and 419:
IndexOrganometallic compounds are i
Page 420 and 421:
IndexCarbon monoxide contd.bonding
Page 422 and 423:
IndexEthylene glycol. see Ethane-1.
Page 424 and 425:
IndexMetallocenes contd.reactions,
Page 426 and 427:
IndexSilicon contd.-silicon bonded
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_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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