_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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wUlo2-Fe(C0) 5redu cine;~C 7 H~BF4- Fe(C0) 42 -oc;~ent[Fe5 (Col,4 (fl5 -c>]2-(C0)2[!'e6 (C0)13( Jl-C0)3 (Jl 6-c~ 2 -p.e.c. 48 + 26+6+4+2 =86146 +2 = (14X6)+2=86(closo)[!'e5(C0),5( fl5 -c~2H+p.e.c. =40+30 +4=7414t+4=74(nido)CH4~H2-2Et 5 N(-2H+J2H+(OC) 3 (C0) 3butterfly tetrohedrol clusterp.e.c. = 62(orochno)p.e.c. = 62. (orochno)if CH o Ligond not o cluster atomFig. 11.1 O Chemistry of some deltahedral ironcarbidocarbonyl clusters.
2-1cococoLoc3Loc-3C0/120°/Os COcocoLco1 cocoOssCCOl,e2-bowtie, p.e.c. 78p.e.c. 72co co----OscoL=6 (C0)20P(0Mel3cowp.e.c. 90p.e.c.84U1......octohedron, p.e.c. 86coocj[-~coOC n~\ __ knc COoc coL L1 rnOs 6 (C0)17 L 4Fig. 11.11 Structures of osmium carbonyl complexes. showing the polyhedral electron counts.Os 5 (C0)16L 3OC~'COoc cobicopped tetrohedron1 .rnos 5 (C0) 16Os 6 (C0) 18
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Principles ofOrganometallicChemistr
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© 1988 P. PowellOriginally publish
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Contentsvi3.5 Beryllium 543.6 Calci
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Contents12.4 Chemistry based on syn
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PrefaceIn the 20 years since 'Princ
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Periodic table ofthe elementsThe pe
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Periodic table of elementsGroup Gro
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General surveysyntheses. They are a
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General surveypacked hexagonal, nic
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Table 1.1. Mean metal-carbon bond d
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General survey(c) COMPLEXES OF UNSA
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General survey4008.0o1E...,300.=; 2
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General surveyelements are rapidly
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General surveyCollman, J.P., Hegedu
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100o-100o Si110111Ql-200 . 1L. :1o
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The main group elementsFor R = alky
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The main group elementsweakly exoth
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The main group elementselement and
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The main group elements(a) HYDROSIL
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The main group elementsinsertion:-
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The rnain group elernentsElectrophi
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The first three periodic groupsTabl
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The first three periodic groupstran
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The first three periodic groups(o)(
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The first three periodic groups( b)
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The first three periodic groupsorga
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The first three periodic groupsMe M
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The first three periodic groupsH HE
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The first three periodic groupsThis
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The first three periodic groupsHere
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The first three periodic groupselec
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The first three periodic groupsEt~5
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The first three periodic groupscond
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The first three periodic groupsThe
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1 2·65 1 9-...:..... _;.;;.-c 1·4
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The first three periodic groupsCycl
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The first three periodic groups3. 7
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The first three periodic groupsYe\
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The first three periodic groupsor o
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Table 3.6 Some hydroborating agents
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RCf:0~HH~RCHO2 2Hi~OH-"' 18-C-R/ 1o
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The first three periodic groups(c)
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The first three periodic groupsTHF.
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The first three periodic groupspuls
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The first three periodic groupsROH/
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The first three periodic groupsthe
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The first three periodic groupsThe
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The first three periodic groupsin p
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The first three periodic groupsSilv
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The first three periodic groupso-RR
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The first three periodic groups(a)(
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The first three periodic groups5. W
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4Organometallic compoundsof element
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The main Groups IV and Vachieved e.
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The main Groups IV and Ve.g. alipha
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The main Groups IV and VDimethyltin
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The main Groups IV and V4.3.3 React
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The main Groups IV and Villustrates
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The main Groups IV and Vof methylco
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The main Groups IV and VTable 4.1.
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The main Groups IV and Vanes) are s
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The main Groups IV and Vconcentrati
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The main Groups IV and VTable 4.2.
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The main Groups IV and V4.6.3 Caten
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The main Groups IV and VTreatment o
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The main Groups IV and V4.8 pTC-JJT
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The main Groups IV and VA convenien
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The main Groups IV and Vfu- +( + )[
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The main Groups IV and Vand Me 2 PF
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The main Groups IV and VAcidH 2 PO(
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The main Groups IV and Vin World Wa
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The main Groups IV and VHX(SblPh M
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The main Groups IV and VOn replacem
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The main Groups IV and Varsenic yli
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The main Groups IV and VPh 2 BiBiPh
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The main Groups IV and Vphosphorus
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The main Groups IV and VDimethyltin
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5Some transition metalchemistry rel
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M L--4----f/~1 11 1\ 11 11 1\ 11 11
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Transition metal chemistryeven nega
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co co co cooc~o o co c~co cooc~c~ o
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Transition metal chemistryeach othe
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Transition metal chemistryconsidere
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Transition metal chemistryTable 5.3
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Transition metal chemistryTable 5.5
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Table 5.7. Thermochemical data and
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Transition metal chemistryNickel is
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Transition metal chemistry(o)(OC ln
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Transition metal chemistryCarbonyl
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Transition metal chemistry2Cr(COJ6
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Transition metal chemistry18-electr
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Table 5.8. General reactions of tra
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Transition metal chemistry5. 3.1 Ad
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Transition metal chemistrynot detec
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Transition metal chemistryPd(PPhBu~
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Transition metal chemistryH2 -LL3Rh
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Transition metal chemistryPhosphine
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Transition metal chemistry(d) Comme
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Transition metal chemistryD: 1 Hn.m
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Organometallic compounds of the tra
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No3-electron1] 3 -allyl4-electron17
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Organotransition metal chemistrymel
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Organotransition metal chemistryii)
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Table 7.2. Mechanisms of decomposit
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Organotransition metal chemistry4Ti
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Organotransition metal chemistryM e
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Organotransition metal chemistryIn
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Organotransition metal chemistryThe
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Organotransition metal chemistry~ (
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Organotransition metal chemistryo o
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Organotransition metal chemistry( C
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Organotransition metal chemistryMe
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Organotransition metal chemistry/OM
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Organotransition metal chemistry7.3
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Organotransition metal chemistryexc
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Organotransition metal chemistrysev
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Organotransition metal chemistry)--
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Organotransition metal chemistryR R
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Organotransition metal chemistry-co
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Organotransition metal chemistry4.
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Organotransition metal chemistry(b)
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r~...I.J::...--Î-..L-.._.,:;.I""'
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Allyl and diene complexessignals ar
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Allyl and diene complexesdoublets.
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Allyl and diene complexes111.5°. A
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Allyl and diene complexesThe pallad
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Allyl and diene complexesFe(C0} 5-F
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Allyl and diene complexes~4,neutrat
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Allyl and diene complexesThis indic
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Allyl and diene complexesonly with
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Allyl and diene complexesderivative
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Allyl and diene complexesvolatile,l
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Allyl and diene complexesChemical R
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9Five electron ligands9.1 lntroduct
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Five electron ligandsTable 9.1 The
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Five electron ligandsthe ferriceniu
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Five electron ligandsFerrocene unde
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Five electron ligands---v~···Fe,
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Five electron ligandsDihalogenometh
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Five electron ligands(c) TITANOCENE
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Five electron ligandsa pair of non-
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Five electron ligands9. 3.1 Mononuc
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Five electron ligandsslowly oxidize
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~ o coo,... ...,C,, /....-:;.' //Fe
Page 314 and 315: Five electron ligandsn-system of ea
Page 316 and 317: Five electron ligandsFig. 9.15 Mole
Page 318 and 319: Five electron ligandsNucleophilic r
Page 320 and 321: Five electron ligands(a) Sketch the
Page 322 and 323: lCH2=CHC2H5Five electron ligands(i)
Page 324 and 325: Five electron ligands( 6 A 1 g) and
Page 326 and 327: Complexes of arenesFor chromium thi
Page 328 and 329: Complexes of arenesW(C 6 H 6 ) 2
Page 330 and 331: Complexes of arenesgas phase (5.01
Page 332 and 333: Complexes of arenes(Q)-RCr cr(C0)
Page 334 and 335: Complexes of arenes- BH 3~jCr(C0) 3
Page 336 and 337: Complexes of arenesif"••d•R"x
Page 338 and 339: wNfoi::>.~7trienyl Cr(C0) 3~·trien
Page 340 and 341: Complexes of arenesmethyl iodide. T
Page 342 and 343: Complexes of arenesin the whole mol
Page 344 and 345: Complexes of arenesproposed above,
Page 346 and 347: Complexes of arenesProblems1. Ferro
Page 348 and 349: Complexes of arenes(<) ~PlMe~MeMe~M
Page 350 and 351: Table 11.1. Electron counting in cl
Page 352 and 353: Cluster compounds455TrigonalOctahed
Page 354 and 355: Cluster compoundsFig. 11.4 Closo, a
Page 356 and 357: Cluster compoundsmixture of the mor
Page 358 and 359: Cluster compoundsIt is extremely st
Page 360 and 361: Cluster compounds2- 2-~ m1 11O GQ8-
Page 362 and 363: Cluster compounds(IJ 5 -C,B,H 6 )Mn
Page 366 and 367: Cluster compoundsdensations' do not
Page 368 and 369: Cluster compoundsA 3 A 78 78 12A 3c
Page 370 and 371: Cluster compoundsstructures of the
Page 372 and 373: Mechanisms of industrial processesT
Page 374 and 375: Table 12.2.Process Feedstock Cataly
Page 376 and 377: Mechanisms of industrial processesF
Page 378 and 379: Mechanisms of industrial processes1
Page 380 and 381: chaingrowth(alkeneinsertion)CH 3 CH
Page 382 and 383: r!~~NiJy ~ ' ,. -;,,.,~,;, ..'Ni'+2
Page 384 and 385: ţ/Ph)o-cPd =:) )cH0-C'-....Ph 2~-8
Page 386 and 387: Mechanisms of industrial processesH
Page 388 and 389: H2 C=CH2H2C=CH2[Ti]-R + C2H4coordin
Page 390 and 391: o[~] o ~ [f!- ~7:Jlinear[w]=CH~poly
Page 392 and 393: Me3 CCH2Li3HCI/WCL 6 W(=CBut)(CH2 B
Page 394 and 395: Mechanisms of industrial processesW
Page 396 and 397: Mechanisms of industrial processesT
Page 398 and 399: ••~'"'"'" 7 ~;~13 :H~ r--------
Page 400 and 401: Mechanisms of industrial processesc
Page 402 and 403: Mechanisms of industrial processesO
Page 404 and 405: Mechanisms of industrial processesc
Page 406 and 407: Mechanisms of industrial processesH
Page 408 and 409: a)oIIIc1c1o1H /H'-cH2 ,l!--1 --H'.
Page 410 and 411: Mechanisms of industrial processesB
Page 412 and 413: Mechanisms of industrial processes5
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Lanthanides and actinidesA few exam
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Lanthanides and actinidesCp~LuCH 3
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IndexOrganometallic compounds are i
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IndexCarbon monoxide contd.bonding
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IndexEthylene glycol. see Ethane-1.
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IndexMetallocenes contd.reactions,
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IndexSilicon contd.-silicon bonded
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_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

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