_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

Index
Antimony compounds contd.
thermochemistry, 6, 10
Arenes, from alkynes, 246-7
Arene complexes, 93-4, 311-26
bonding in, 199-206
preparation, 311-14
Arsabenzene, 144
Arsenic compounds
catenated derivatives, 141-3
organohalides, 129-31
pentaphenyl. 13 5
preparation, 19, 13 3
structures and reactions, 131-4
thermochemistry, 6, 10
ylides, 139-40
Aryls, transition metal. 213-32
Asymmetric hydrogenation, see
Hydrogenation
Azulenes, metal derivatives, 3 31
Barium alkyls, 56
Bart reaction, 26, 1 31, 13 3
Benzene complexes, see Arene complexes
Benzene, metallation of, 41
Benzyl complexes, 219
Benzyne, 42-3
complex, 220
Beryllium
alkyls/aryls, 29
preparation, 54
reactions, 55-6
structures, 3 5, 5 5
cyclopentadienyls, 90-1
Bis-1] 3 -allyl complexes, see Allyl
complexes
Bis-1] 6 -benzenechromium
bonding in, 202-6
Bis-1] 5 -cyclopentadienyl complexes, see
Metallocenes
Bismuth compounds
preparation, 19
structures and reactions, 134, 13 5,
141
thermochemical data, 6, 10
Bond
classification, 2-9
energies, 5-6, 112, 118, 164, 215,
see also Thermochemistry
Bonding
bridge ('electron-deficient'), 33-9
general types, 2-9
in complexes of transition elements,
194-211
in metal carbonyls, 1 56-8
n- to Group IVB elements, 111-12
see also Molecular orbitals
Borabenzene complexes, 288
9-Borabicyclo 3.3.1 nonane, 9-BBN.
68-72
Boranes, 3 3 7-40
alkenyl. 72
alkyl, 31. 65-74
alkynyl, 71
amino, 76-7
aryl. 66, 74
complexes, 72-3. 82-3
Borazarenes, 78
Borazines, 77
Borinic acids, 7 4
Boron
coordination chemistry, 72-3
hydrides, 66-72, see also Boranes
-nitrogen compounds, 76-8
-oxygen compounds, 7 4-6
Boronic acids, 7 4
Boroxines, 7 5
Bridge bonding, 4, 31-9
Butadiene
complexes, 263-8
hydrocyanation, 364-5
magnesium, 9 3
oligomerization, 367-70
polymerization, 48, 50, 56
But-1-en-3-yne, 246, 247
Butyraldehydes, 388
Cacodyl, l. 141
Cadmium
alkyl halides, 60
alkyls, 17, 20, 22, 35, 60
thermochemical data, 6, 10, 20
Caesium, 29, 49
Calcium
alkyls and aryls, 56
bis (cyclopentadienyl), 90-1
carbide, 384
Carbene complexes, 232-5, see also
Alkylidene complexes
Carbenes, 26, 40, 61, 232
Carbon disulphide complexes, 181, 183
Carbonium ion stabilization, 285, 318
Carbon monoxide, 71. 152
406