_P.-Powell-auth.-Principles-of-Organometallic-Chemistry-Springer-Netherlands-1988

Index
Iron complexes contd.
cyclohexadienyl. 303-4
cyclo-octadiene, 2 3 8
cyclo-octatetraene, 19 3
cyclopentadienyl, 240-3, 295-9, see
also Ferrocene
diene, 263-6
pentadienyl, 302
trimethylenemethane, 2 71
Isomerization of alkenes, see Catalysis
Isoprene, 48, 82
lsotactic polymers, 3 72
Job-Cassels reaction, 214
Knoevenagel condensation, 284
/3-Lactams, 242
Lanthanides, 399
cyclo-octatetraene complexes, 402-3
cyclopentadienyls, 400-2
Lanthanum, see Lanthanides
Lead
alkyls, 27, 100, 121
arene complexes, 9 3
bis(cyclopentadienyl). 122
-lead bonded derivatives, 120
organohalides, 102-4
plumbonic acids, 117
thermochemical data, 5, 6, 10, 215
Lewisite, 134
Ligand
-acceptor/donor properties, 149, 151
classification, 191-4
substitution, mechanisms of, 16 7-8
Lithium
alkyls and aryls, 17, 39-43
addition to alkenes, 46
association, 36-8
attack on ethers, 41
complexes, 3 6-8
reactions, 22, 44-9, 215
ferrocenyl. 284-5
triphenylsilyl, 119
LUMO. 157
Lurgi process. 383, 384
Lutetium, see Lanthanides
Magnesium, 35, see also Grignard
reagents
arene complexes, 9 3
bis(cyclopentadienyl), 90-1
Manganese complexes
acyl, 225-7
alkyl, 173, 225-7
allyl, 253-6
arene, 321-6
carbonyls, 153, 154, 166, 172-3
cyclopentadienyl. 294, see also
Manganocenes
indenyl. 294
Manganocenes, 274, 280, 281
Mass spectra
of boron compounds, 79
of metal carbonyls, 162-3
Matrix isolation, 9, 122, 166, 270
Mercuration
of alkenes and alkynes, 63
of aromatic compounds, 62
of ferrocene, 284
Mercury
alkyls, 17, 19, 20, 26, 27, 35, 44, 49,
56
alkyl halides, 60
aryl halides, 27. 60
cyclopentadienyls, 91-2
methyl metal, 60
thermochemistry, 6, 10, 19
trihalomethyls, 61
uses in organic synthesis, 60-5
Metal atom synthesis, 18, 166, 313
Metal carbonyl anions, 166, 170-2, 216
Metal carbonyl complexes, see
Cyclopentadienyl metal carbonyl
complexes; Metal carbonyl anions
bond dissociation energies, 16 3, 164
bonding in, 156-8
bond lengths, 163, 165
clusters, 167, 351-3
mass spectra, 162-3
polynuclear, 16 7
preparation, 165-7
reactions, 16 7-7 3
structures, 152-6
vibrational spectra, 158-62
Metal carbonyl halides, 16 7, 173
Metal-halogen exchange, 40
Metal-hydrogen exchange, 40-3
Metallacyclobutanes, 3 7 5
Metalloboranes, 344-8
Metallocarboranes, 344-8
Metallocenes, 2 79-9 2
bonding~. 199-205,281
magnetic properties, 280
410