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Scientific and Technical Aerospace Reports Volume 39 April 6, 2001

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colliding drops. The viscous resistivity tensor can be used together with a description of the van der Waals attractions between<br />

the particles to specify the interparticle forces. We must then solve Newton’s laws of motion for the dynamic encounter of pairs<br />

of coagulating drops. The fine particles under consideration have radii much smaller than the Kolmogorov length scale. Exploiting<br />

this fact, we will conduct numerical simulations in which pairs of particles are subjected to a temporally fluctuating linear flow<br />

field, whose statistics are chosen to reproduce results from previous direct numerical simulations for the Lagrangian correlation<br />

functions of the strain <strong>and</strong> rotation rates in isotropic turbulence. Ensemble <strong>and</strong> time averages of these stochastic flow simulations<br />

will provide the rate constant for turbulent coagulation. In addition to simulations corresponding to the ideal case of turbulent<br />

coagulation of non-Brownian particles in microgravity, we will also consider mixed turbulent/sedimentation <strong>and</strong> turbulent/Brownian<br />

simulations.<br />

Author (revised)<br />

Monte Carlo Method; Aerosols; Coagulation; Microgravity; Turbulence; Accumulations<br />

<strong>2001</strong>0024980 Cincinnati Univ., OH USA<br />

Microscopic Flow Visualization in Demixing Fluids During Polymeric Membrane Formation in Low-G<br />

Krantz, W. B., Cincinnati Univ., USA; Greenberg, A. R., Colorado Univ., USA; Todd, P., Space Hardware Optimization Technology,<br />

Inc., USA; Proceedings of the Fifth Microgravity Fluid Physics <strong>and</strong> Transport Phenomena Conference; December 2000, pp.<br />

1368-1377; In English; See also <strong>2001</strong>0024890; No Copyright; Avail: CASI; A02, Hardcopy; A10, Microfiche<br />

Macrovoids (MVs) are large (10-50 micron) pores often found in polymeric membranes prepared via phase-inversion techniques.<br />

They are generally considered undesirable since they can adversely affect the performance of polymeric membranes.<br />

However, MVs can be useful in certain thin-film applications in which vapor transmission is necessary or for use as reservoirs<br />

for enzymes or liquid membrane material. The goal of this research is to determine the mechanism of formation for MVs in order<br />

to control their formation. The hypothesis to be tested in this research is that MV growth is determined by an interplay of solutocapillary<br />

convection, viscous drag, <strong>and</strong> buoyancy forces. The results of preliminary ground-based experiments employing flow-visualization<br />

videomicroscopy to study polymeric membrane formation via dry-casting (evaporative casting) are presented. These<br />

experiments establish the viability of this real-time noninvasive technique for studying the MV formation process. Moreover, they<br />

indicate that surface-active agents can significantly influence MV formation during the dry-casting process. This flow-visualization<br />

videomicroscopy technique will be adapted to studying polymeric membrane formation via the wet-cast (precipitation bath)<br />

process in both ground-based as well as KC-135 flight experiments in order to assess the role of both buoyancy as well as surfacetension<br />

forces on MV formation.<br />

Author (revised)<br />

Flow Visualization; Membranes; Photomicrography; Voids; Diffusion; Convection<br />

<strong>2001</strong>0024981 Florida Univ., Chemical Engineering Dept., Gainesville, FL USA<br />

Microgravity Driven Instabilities in Gas-Fluidized Beds<br />

Ladd, Anthony J. C., Florida Univ., USA; Weitz, David A., Pennsylvania Univ., USA; Proceedings of the Fifth Microgravity Fluid<br />

Physics <strong>and</strong> Transport Phenomena Conference; December 2000, pp. 1378-1379; In English; See also <strong>2001</strong>0024890; No Copyright;<br />

Abstract Only; Available from CASI only as part of the entire parent document<br />

A dense pack of solid particles can be fluidized by an upward flow of liquid, which counterbalances the gravitational force<br />

on the particles. The resulting suspension is stable for sufficiently small fluid velocities, although the particle dynamics are complex<br />

<strong>and</strong> still not fully understood. A packed particle bed can also be fluidized by a gas flow, but in this case a stable suspension<br />

of moving particles cannot be produced in earth’s gravitational field. As the gas flow is increased, a stable ”exp<strong>and</strong>ed” bed can<br />

be produced that has a lower solids concentration than the packed bed, but recent Diffusing Wave Spectroscopy (DWS) experiments<br />

have shown that the particles are stationary. At slightly higher gas flows, necessary to set the particles in motion, the bed<br />

is immediately unstable, with bubbles (large regions essentially void of particles) transporting a significant fraction of the gas<br />

through the solid phase. A kinetic theory of gas-fluidized beds predicts that the bed is always unstable to particle inertia, which<br />

is several orders of magnitude larger than fluid inertia in this case. In order to study the onset of this particle-induced instability,<br />

the minimum fluidization velocity must be reduced by several orders of magnitude; we believe that this can be most successfully<br />

accomplished in a reduced gravity environment. These microgravity experiments will offer the first opportunity to experimentally<br />

study the effects of low-Reynolds number hydrodynamic interactions in a suspension where there is no liquid, <strong>and</strong> the particle<br />

motion is predominantly ballistic. We expect that in a microgravity environment we can explore the transition between stable <strong>and</strong><br />

unstable flow regimes in gas-fluidized beds, <strong>and</strong> contrast the behavior of particle inertia (gas-fluidized) <strong>and</strong> fluid inertia (liquid<br />

fluidized) driven instabilities. In this work we plan to investigate the effects of small amounts of inertia on the stability of fluidized<br />

beds. We will compare <strong>and</strong> contrast the stability conditions <strong>and</strong> flow patterns arising from increasing fluid inertia (Re > 1,St about<br />

Re) <strong>and</strong> increasing particle-inertia (Re is less than 1,St is greater than 1). In particular we will discover if the progression of instabi-<br />

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