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Ö.Uygun et al./ ISEM2016 Alanya – Turkey Yeşil tedarik zinciri yönetimi uygulayan firmaların, bu konuda ne durumda olduklarını tespit edebilecekleri ve ne zaman istenilen seviyeye ulaşacaklarını öğrenebilecekleri; kısaca YTZY konusunda yol gösterici sayısal bir çalışma bulunmamaktadır. Bu çalışmanın amacı belirlenen firmaları yeşil tedarik zinciri yönetimi açısından değerlendirmek ve ne kadar süre sonra dengeye ulaşacaklarını belirlemektir. Bu karmaşık yapının çözümlenebilmesi için bulanık bilişsel haritalar yönteminden faydalanılmıştır. Bu çalışmada 3 firma yeşil tedarik zinciri yönetimi açısından değerlendirilmiştir. Değerlendirmeler sonucunda 2. firmanın 1. firmaya göre daha kısa sürede dengeye ulaşıp, YTZY açısından istenilen duruma geleceği görülmüştür. Bunun sebebi olarak da mevcut YTZY ve analize göre de en önemli çıkan yeşil pazarlama değerinin daha yüksek olması gösterilebilir. Bunun yanında YTZY’ye negatif etkisi olan gelenekselci yaklaşım kriterinin de 1. firmaya göre oldukça küçük olmasıdır. 3. firmanın ise YTZY açısından çok kötü bir durumda olduğu görülmüş ve bu şekilde devam ederse hiçbir zaman YTZY’de iyi bir konuma gelemeyeceği kanısına varılmıştır. KAYNAKÇA [1] Akıncı, H.M., 2013. Bulanık Bilişsel Haritalar Yardımıyla İnsan Duygularının Modellenmesi. Fen Bilimleri Enstitüsü. [2] Martha C. Cooper, Lisa M. Ellram, 1993. Characteristics of Supply Chain Management and the Implications for Purchasing and Logistics Strategy. Int. J. Logist. Manag. 4, 13–24. doi:10.1108/09574099310804957 [3] Erdem, G., 2013. Tedarik zinciri yönetimi uygulamalarının benimsenmesinin, tedarik zinciri ve işletme performansına etkisi (Thesis). [4] Hokey Min, William P. Galle, 2001. Green purchasing practices of US firms. Int. J. Oper. Prod. Manag. 21, 1222–1238. doi:10.1108/EUM0000000005923 [5] Büyüközkan, G., Vardaloğlu, Z., 2008. Yeşil tedarik zinciri yönetimi. Lojistik Derg. 8, 66–73. [6] Bolat, H.B., Bayraktar, D., Öztürk, M., Turan, N., 2011. Yeşil Lojistik Zincirinde Araç Rotalama Problemi İçin Bir Model Önerisi. İstanbul Ticaret Üniversitesi. [7] Nakiboğlu, G., 2007. TERSİNE LOJİSTİK: ÖNEMİ VE DÜNYADAKİ UYGULAMALARI. Iktis. Ve İdari Bilim. Fakültesi Derg. 9, 1–16. [8] B. Kosko, “Fuzzy cognitive maps,” Int. J. Man-Mach. Stud., vol. 24, no. 1, pp. 65–75, Jan. 1986. [9] E. I. Papageorgiou, A. T. Markinos, and T. A. Gemtos, “Fuzzy cognitive map based approach for predicting yield in cotton crop production as a basis for decision support system in precision agriculture application,” Appl. Soft Comput., vol. 11, no. 4, pp. 3643–3657, Jun. 2011. [10] P. P. Groumpos, “Fuzzy Cognitive Maps: Basic Theories and Their Application to Complex Systems,” in Fuzzy Cognitive Maps, M. Glykas, Ed. Springer Berlin Heidelberg, 2010, pp. 1–22. 1035
ISEM2016, 3 rd International Symposium on Environment and Morality, 4-6 November 2016, Alanya – Turkey The Production of Polyurethane from Waste Vegetable Oil-Based Polyols and Modelling of Rheological Properties * Ercan AYDOĞMUŞ, Fethi KAMIŞLI Department of Chemical Engineering, Faculty of Engineering, Fırat University, 23119, Elazığ Abstract Polyols in polyurethane production is of great importance. The future will increase the production of polyols from renewable sources. The result of the reduction of fossil fuels will be important in the use of renewable resources. Especially important alternative which will expand polyols production from vegetable oils. Polyols derived from vegetable oil will be produced by epoxidation, hydroxylation and purification. In this study, the waste vegetable oil based polyols were produced the polyurethane with the catalysts. The thermal conductivity, density and mechanical properties of polyurethane were investigated. Also the produced polyols compared with commercial polyols with rheological properties as viscosity, temperature, shear stress, shear rate. The rheological properties of the polyols were modelling with developed equations based on experimental data. Key Words: Waste Vegetable Oil, Polyols, Polyurethane, Rheological Modelling. 1. Introduction Polyurethane, low thermal conductivity, easy to use, flexibility, high mechanical strength, it is preferred in many fields. Polyols are the most important of the polyurethane industry. But the world's oil supply is decreasing rapidly with each passing day. Therefore, an inquiry from renewable sources that can replace the petroleum-based polyol. The common view is that the natural plant and animal oils of alternative raw materials. Studies in the literature have epoxidized oil-based polyether polyol instead of soy-based polyols were produced using the vegetable oil. Compared to petroleum-based polyols in polyurethane production from vegetable oil polyol produced with a smaller amount of isocyanate used. The polyurethane produced with the polyol produced from vegetable oil decreased compression resistance [8]. The polyurethane material in the work they added crystallized calcium carbonate and silica particles. It has been shown to becomes smaller the size of filler by adding the closed spherical cells. Mechanical properties of polyurethane materials were modeled. Moreover, the effect of the particle size of the filler was investigated [11]. 1036
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ISBN 9786054735846

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