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ISBN 9786054735846

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K. ALTUNTAS et al./ ISEM2016 Alanya – Turkey<br />

Adsoption Capacity, mg/g<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

50 mg/l 100 mg/l 200 mg/l 400 mg/l<br />

0<br />

0 20 40 60 80 100 120<br />

Time, min<br />

Figure 3. Change in Adsorption Capacity by Contact Time and Adsorbent Concentration<br />

As the maximum adsorption capacity of activated carbon was changing between 6 – 39 mg/g for<br />

copper ion removal [18-20], the maximum adsorption capacity of AC-nZVI was obtained at 790<br />

mg/g. In Figure 4, adsorption capacity in the effect of adsorbent concentration can be seen for<br />

nZVI and AC-nZVI. The experiments were conducted for 30 minutes at same adsorbent<br />

concentration and 50 mg/L copper ion concentration. While adsorption capacity of nZVI for 100<br />

mg/L adsorbent concentration is 414 mg/g, it was 510 mg/g for AC-nZVI. Adsorption capacity is<br />

increase by supporting activated carbon with nZVI.<br />

Adsorption Capacity, mg/g<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

AC-nZVI nZVI<br />

50 100 200 400<br />

Adsorbent Concentration, mg/L<br />

Figure 4. Difference of Adsorption Capacities of nZVI and AC-nZVI<br />

3.3. Adsorption Isotherm<br />

R 2 (Determination Coefficient) is a positive value between 0 and 1; and the closer the value 1<br />

shows that the distribution is consistent. Isotherm plots belong to Freundlich and Langmuir<br />

508

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