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S.B. TOSUN/ ISEM2016 Alanya – Turkey [10]ALTUĞ, Yılmaz, Yabancıların Hukuki Durumu, İsmail Akgün Matbaası, İstanbul 1966, s.101 [11]AYBAY Rona, Amerikan, İngiliz ve Türk Hukuk Sistemlerinde Yurt Dışına Çıkma Ve Yurda Girme Özgürlüğü, Orta Doğu Teknik Üniversitesi, Ankara 1975, s.93 [12]http://www.eu4journalists.eu, “Göçmenlik ve sığınma”, http://www.eu4journalists.eu/index.php/dossiers/turkish/C45/198/, E.T. 10.11.2014 [13] [EURACTIV, Göç: AB İçin Hem Sorun, Hem Çözüm, http://www.euractiv.com.tr/abningelecegi/link-dossier/goc-ab-icin-hem-sorun-hem-cozum, E.T. 10.06.2016 [14] BRAGUE Remi, Avrupa: Roma Yolu, Çev., Betül Çotuksöken, Kabalcı Yayınevi İstanbul, 1995, s.125 [15]CİHANGİR Damla, AB’nin Bölgesel Politikası ve Bölgesel Yönetimler, İKV Değerlendirme Notu, Aralık 2010, s.2 [16] MARCHESİN Philippe, “Yeni Tehditler Karşısında Avrupa”, Dünden Bugüne Avrupa Birliği, Der. Beril Dedeoğlu, Boyut Yayınları, İstanbul 2003, s.428-429 [17] DİNÇ Cengiz, “Avrupa Kimliği: Çatışan Perspektifler, Güncel Değerlendirmeler ve Endişeler”, Gazi Üniversitesi, Akademik Bakış Dergisi, Cilt:5, Sayı:9, Yıl:2001, s.31-58 [18]BİLMEN Ceki, Avrupa kimliği ve Türkiye, Şalom Gazetesi, http://arsiv.salom.com.tr/news/print/1763-Avrupa-kimligi-ve-Turkiye.aspx E.T. 12.11.2015 [20]KILINÇ, İsmail , Ankara Barosu Dergisi, Çöp Geri Dönüşüm ve Hukuk, Sayı 2, 2014, s.468 - 470 [21]http://bigumigu.com/haber/londra-sokaklarinda-yerlere-cop-atmama-oyunu/ E.T.20.06.2016 [19]http://berlinturk.com/index.php/component/k2/item/38211-%C3%A7evre-ya-dado%C4%9Fa-koruma-g%C3%B6%C3%A7menler-i%C3%A7in-bir-konu-de%C4%9Filmi.html,E.T.20.06.2016 [22]http://berlinturk.com/index.php/component/k2/item/38211-%C3%A7evre-ya-dado%C4%9Fa-koruma-g%C3%B6%C3%A7menler-i%C3%A7in-bir-konu-de%C4%9Filmi.html,E.T.20.06.2016 [23]http://berlinturk.com/index.php/component/k2/item/38211-%C3%A7evre-ya-dado%C4%9Fa-koruma-g%C3%B6%C3%A7menler-i%C3%A7in-bir-konu-de%C4%9Filmi.html,E.T.20.06.2016 [24]KILINÇ, İsmail , Ankara Barosu Dergisi, Çöp Geri Dönüşüm ve Hukuk, Sayı 2, 2014, s.468 – 470 [25]KILINÇ, İMGA, Orçun, Çevre Sorunlarının Çözümüne Yönelik Alternatif Bir Politika Arayışı:Murray Bookchin ve Sosyal Ekoloji, Alternatif Politika, Cilt 1, Sayı 1, Nisan 2009, s.88 [26]KILINÇ, İMGA, Orçun, Çevre Sorunlarının Çözümüne Yönelik Alternatif Bir Politika Arayışı:Murray Bookchin ve Sosyal Ekoloji, Alternatif Politika, Cilt 1, Sayı 1, Nisan 2009, s.88 684
ISEM2016, 3 rd International Symposium on Environment and Morality, 4-6 November 2016, Alanya-Antalya/Turkey Karadeniz Rize Bölgesi Bakır Sülfür Cevherlerinin Anodik Oksidasyon Prosesi ile Liçi ve Çevre Açısından Önemi 1 Figen Özboz, 1 Muhammet Kartal, * 1 Ahmet Alp 1 Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü, Sakarya Üniversitesi, Türkiye Özet Sülfürlü cevherlerden bakır üretimi çoğunlukla pirometalurjik işlemlerle elde edilmektedir. Ancak, enerji verimliliği, daha az yatırım maliyeti, çevreye daha duyarlı oluşu ve bakır cevheri içerisindeki bakır dışında diğer elemenlerin eldesi gibi sebeplerden dolayı hidrometalurjik olarak bakır üretimi son yıllarda dünyada önem kazanmıştır. Bu çalışmada Karadeniz Rize bölgesindeki bakır sülfür cevherlerinin anodik oksidasyon liç işlemi incelenmiştir. Konsantre edilmiş bakır cevheri gezegensel değirmen içersinde, optimum koşullarda mekanik aktive edilmiştir. Akabinde aktive edilmiş ve aktive edilmemiş numuneler H 2SO 4 çözeltisi içerisinde farklı koşullarda (hava ile, havasız) liç edilmiştir. Ayrıca, sıcaklığın ve potansiyelin anodik oksidasyon liç işlemine etkileri çalışılmıştır. Daha sonra çözeltiler AAS ve titrasyon işlemleri ile analiz edilmiş ve bakır kazanım verimliliği farklı liç koşullarına göre hesaplanmıştır. Anahtar kelimeler: Konsantre edilmiş bakır cevheri, mekanik aktivasyon, anodik oksidasyon, hidrometalurjik proses, elektrometalurjik proses Abstract Copper production from sulfide ores are mostly carried out with pyrometallurgical processes. However, for the reasons such as energy efficiency, less investment cost, more friendly environmental process and extraction of other elements except copper in ore, hydrometallurgically copper extraction has gained importance in the world in recent years. In this study, anodic oxidation leaching process of Rize region complex copper sulfide ores on Black Sea were investigated. Concentrated copper ore was mechanically activated in a planetary mill for optimum conditions and then non-activated and activated samples were leached in H 2SO 4 solution in different conditions (with air and without air). And also the effects of temperature and voltage in anodic oxidation leaching process were studied. Afterwards, solutions was analyzed with AAS and titrimetric processes and the copper extraction efficiency was calculated in different leach conditions. Keywords: Concentrated copper ore, mechanically activation, anodic oxidation, hydrometallurgical process, electrometallurgical process 1. Giriş Dünyada bakır üretimi, sülfürlü ve oksitli bakır cevherlerinin madencilik yöntemleri ile çıkarılması, zenginleştirilmesi ve değerlendirilmesi ile yapılmaktadır. Dünya geneline bakıldığında bakır üretiminin yaklaşık %80’i pirometalurjik yöntemler ile gerçekleşmekte ve %20 civarında ise hidrometalurjik yöntemler kullanılmaktadır [1]. Sülfürlü cevher ve konsantrelerden bakır üretimi genellikle yüksek sıcaklıkta gerçekleştirilen izabe *Corresponding author: Address: Faculty of Engineering, Department of Metallurgical and Materials Engineering Sakarya University, 54187, Sakarya TURKEY. E-mail address: alp@sakarya.edu.tr, Phone: +902642955765 685
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