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K. ALTUNTAS et al./ ISEM2016 Alanya – Turkey on removal rate belong to 200 mg/L and 400mg/L AC-nZVI concentration was negligible. 200mg/L AC-nZVI concentration was determined to be sufficient for %96 removal rate. While the copper ion adsorption capacity of activated carbon was 6-39 mg/g according to literature, the adsorption capacities belong to nZVI and AC-nZVI is 414 mg/g and 510 mg/g, respectively. This shows the effect of nZVI supported on activated carbon to remove copper from the solution. Adsorption capacity of activated carbon is increased by supporting nZVI on activated carbon. This gives an advantage of lower adsorbent concentration and higher removal rate in the removal of copper metal ions. Langmuir isotherm give the best fit and the maximum adsorption capacity according to Langmuir isotherm is calculated as 588,24 mg/g. References [1] Nano–Adsorbents For Remediation of Aquatic Environment: Local and Practical Solutions For Global Water Pollution Problems. Kurniawana T. A., Sillanpääa M. E., Sillanpää M. Critical Reviews in Environmental Science and Technology. 2011; 42:1233-1295. [2] Nobel Metal Nanoparticles For Water Purification: A Critical Review. Pradeep T., Anshup.Thin Solid Films.2009; 517:6441-6478. [3] Ulucan, K., Noberi, C., Coşkun, T., Üstündağ, C. B., Debik, E., & Kaya, C. Disinfection By-Products Removal by Nanoparticles Sintered in Zeolite. Journal of Clean Energy Technologies, 2013; 1(2): 120-123. [4] Lu Lin, Xuesong Xu, CharalambosPapelis, Tzahi Y. Cath, Pei Xu. Sorption of metals and metalloids from reverse osmosis concentrate on drinking water treatment solids. Separation and Purification Technology.2014; 134:37–45 [5] HakanDemiral, CihanGüngör. Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse. Journal of Cleaner Production. 2016. 124:103–113 [6] Harun AkifKabuk, Yasar Avsar, FatihIlhan, and Kubra Ulucan.Comparison of pH Adjustment and Electrocoagulation Processes on Treatability of Metal Plating Wastewater.Separation Science and Technology. 2014. 49:613-618 [7] S. LeventKuzu, ArslanSaral, SelamiDemir, GülsümSummak, GökselDemir. A detailed investigation of ambient aerosol composition and size distribution in an urban atmosphere. Environ SciPollut Res. 2013. 20:2556–2568 [8] Brian N. Papas, Jerry L. Whitten. Adsorption of copper on a γ-alumina support.Surface Science. 2016; 651:22–27 [9] Eom, T.-H.; Lee, C.H.; Kim, J-H.; Lee, C-H.Development of an ion exchange system for plating wastewater treatment.Desalination. 2005. 180: 163–172. [10] Harun Elcik, Suna O. Celik, Mehmet Cakmakci& Bestamin Özkaya.Performance of nanofiltration and reverseosmosis membranes for arsenic removal fromdrinking water.Desalination and Water Treatment. 2016; DOI: 10.1080/19443994.2015.1111812 [11] Varank, G., Demir, A., Bilgili, M., Top, S., Sekman, E., Yazıcı, S., &Erkan, H. S. Equilibrium and kinetic studies on the removal of heavy metal ions by natural low-cost adsorbents. Environment Protection Engineering.2014; 40(3): 43-61. 510
K. ALTUNTAS et al./ ISEM2016 Alanya – Turkey [12] NevzatBeyazit. Copper(II), Chromium(VI) and Nickel(II) Removal from Metal Plating Effluent by Electrocoagulation. Int. J. Electrochem. Sci.. 2014; 9:4315 – 4330 [13] Zhu, HJ.,Jia, YF., Wu, X. ve Wang, H.Removal of arsenic from water by supported nano zero-valent iron on activated carbon. Journal of Hazardous Materials, 2009, 172:1591- 1596. [14] LN., Shi, X., Zhang veZL., Zhen.Removal of Chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron.Water Research 2011, 45: 886-892. [15] Geng B., Jin Z., Li T., Qi X.Kinetics of hexavalent chromium removal from water by chitosan-Fe-0 nanoparticles. Chemosphere, 2009, 75: 825-830. [16] Kakavandi, B, Kalantary RR, Farzadkia M., Mahvi A.H., Esrafili A., Azari A., Yari A.R., Javid A.B. Enhanced chromium (VI) removal using activated carbon modified by zero valent iron and silver bimetallic nanoparticles. Journal of Environmental Health Science and Engineering, 12:115, 2014 [17] MaliheFouladgar, MasoudBeheshti, Hassan Sabzyan. Singleandbinaryadsorption of nickelandcopperfromaqueoussolutionsby γ-aluminananoparticles: Equilibriumandkineticmodeling.Journal of MolecularLiquids 2015. 211:1060-1073 [18] M. Kobya, E. Demirbas, E. Senturk, M. Ince. Adsorption of heavy metal ionsfromaqueoussolutionsbyactivatedcarbonpreparedfromapricotstone. BiosourceTechnology. 2005. 36(13):1518-1521 [19] M. Imamoglu, O. Tekir, Removal of copper (II) andlead (II) ionsfromaqueoussolutionsbyadsorption on activatedcarbonfrom a newprecursorhazelnuthusks. Desalination. 2008; 228:1-3:108-113 [20] Semra Balci. Nano Sıfır Değerlikli Demir Ve Aktif Karbon Üzerine Nano Sıfır Değerlikli Demir Kaplanmış Adsorbanlar İle Nikel Gideriminin İncelenmesi (UndergraduateThesis). Yildiz Technical University, EnvironmentalEngineeringDepartment. 2015 511
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ISBN 9786054735846

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