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M. ERAT et al./ ISEM2016 Alanya – Turkey Sonuçlar Sonuç olarak; RB5 azo boyar maddesinin TiO2 nanopartikülleri varlığında %100 yakın yüksek oranda başarılı, tekrarlanabilir ve yan ürün oluşturmadan giderilebildiği belirlenmiştir. Yaptığımız çalışmalar sonucunda TiO2 nanopartikülleri UV ortamında pH:4.0’da 50 mg/L başlangıç konsantrasyonundaki Reaktif black 5 (RB5) azo boyasının %99.6 oranında giderim kapasitesine sahip olduğu belirlenmiştir. Kaynaklar [1] Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS. Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies. J. Colloid Interf. Sci. 2005; 288:371-376. [2] Gupta VK, Suhas Application of low-cost adsorbents for dye removal -A review. Journal of Environmental Management 2009; 90(8): 2313-2342. [3] Georgiou D, Melidis P, Aivasidis A, Gimouhopoulos K, Degradation of azo-reactive dyes by ultraviolet radiation in the presence of hydrogen peroxide, Dyes Pigm. 2002; 52: 69-78. [4] Nadaroglu, H., Kalkan, E., Celebi, N., Equilibrium, kinetic and thermodynamic studies on adsorption of Reactive Black 5 dye by laccase modified-red mud from aqueous solutions Fresenius Environmental Bulletin 2014;23 (1) 70-83. [5] Gungor AA, Nadaroglu H, Celebi N, Fenton process for Basic red 9 degradation: ımmobilized apolaccase on a nanomagnetite system. Environmental and Experimental Biology 2014; 12: 121-129. [6] Kalkan E, Nadaroglu H, Celebi N, Tozsin G. Removal of textile dye Reactive Black 5 from aqueous solution by adsorption on laccase-modified silica fume. Desalination and Water Treatment 2014; 52 (31-33): 6122-6134. [7] Kalkan E, Nadaroglu H, Celebi N, Celik H, Tasgin E. Experimental study to remediate of acid fuchsin dye using laccase-modified zeolite from aqueous solutions. Polish Journal of Environmental Studies 2015; 24 (1): 115-124. [8] Karaoglu MH, Ugurlu M. Studies on UV/NaOCl/TiO2/Sep photocatalysed degradation of Reactive Red 195. Journal of Hazardous Materials 2009; 174: 864-871. [9] Tian J, Wang J, Dai J, Wang X, Yin Y. N-doped TiO2/ZnO composite powder and its photocatalytic performance for degradation of methyl orange. Surface & Coatings Technology 2009. [10] Aspland JR. Dyeing Blends: Polyester/Cellulose. Textile Chemist and Colorist 1993; 25(8): 21-26. Başer İ, İnancı YB (1991) Boyarmadde Kimyası. Marmara Üniversitesi Teknik Eğitim Fakültesi Tekstil Eğitimi Bölümü Yayını, İstanbul. [11] Vandevivere PC, Bianchi R, Verstreate W (1998) Treatment and Reuse of Wastewater from the Textile Wet Processing Industry: Review of Emerging Technologies. Journal of Chemical Technology and Biotechnology 72: 289-302. [12] Nadaroglu H, Kalkan E, Celebi N, Tasgin E. Removal of Reactive Black 5 from wastewater using natural clinoptilolite modified with apolaccase. Clay minerals 2015; 50: 65- 76. 5 961
M. ERAT et al./ ISEM2016 Alanya – Turkey [13] Gungor, AA, Celebi N, Nadaroglu H. Removal of basic red 9 in wastewater using green fenton reaction, Fresenius Environmental Bulletin 2015; 24 (5b): 1947-1957. [14] Nadaroglu H, Gungor AA, Celebi N. Removal of Basic Red 9 (BR9) in aqueous solution by using silica with nano-magnetite by enzymatic with fenton process. International Journal of Environmental Research 2015; 9(3):991-1000. [15] Nadaroglu H, Kalkan E, Demir N. Removal of copper from aqueous solution using red mud, Desalination 2010; 251 (1-3): 90-95. 6 962
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