(15) Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesi<strong>de</strong>s, G. M. Chemical Reviews 2005, 105, 1103. (16) Hammond, P. T. Advanced Materials 2004, 16, 1271. (17) Decher, G.; Hong, J. D.; Schmitt, J. Thin Solid Films 1992, 210-211, 831. (18) Paul, D. R.; Barlow, J. W. 1980, 18, 109 (19) Bourry, D.; Favis, B. D. Journal of Polymer Science Part B: Polymer Physics 1998, 36, 1889. (20) Gubbels, F.; Jerome, R.; Teyssie, P.; Vanlathem, E.; Deltour, R.; Cal<strong>de</strong>rone, A.; Parente, V.; Bredas, J. L. Macromolecules 1994, 27, 1972. (21) Wang, Y.; Rubner, M. F. Macromolecules 2002, 25, 3284. (22) Sumita, M.; Sakata, K.; Hayakawa, Y.; Asai, S.; Miyasaka, K.; Tanemura, M. Colloid & Polymer Science 1992, 270, 134. (23) Levon, K.; Margolina, A.; Patashinsky, A. Z. Macromolecules 2002, 26, 4061. (24) Zhang, J.; Ravati, S.; Virgilio, N.; Favis, B. D. Macromolecules 2007, 40, 8817. (25) Torza, S.; Mason, S. G. J. Coll. Interface Sci. 1970, 33, 67. (26) Hobbs, S. Y.; Dekkers, M. E. J.; Watkins, V. H. Polymer 1988, 29, 1598. (27) Zhenhua Yuan, B. D. F. AIChE Journal 2005, 51, 271. (28) Sarazin, P.; Favis, B. D. Biomacromolecules 2003, 4, 1669. (29) Decher, G.; Hong, J. D. European Conference on Organized Organic Thin Films 1991, 321. (30) Clark, S. L.; Montague, M. F.; Hammond, P. T. Macromolecules 1997, 30, 7237. (31) Shiratori, S. S.; Rubner, M. F. Macromolecules 2000, 33, 4213. (32) Sui, Z.; Salloum, D.; Schlenoff, J. B. Langmuir 2003, 19, 2491. (33) Ferreira, M.; Rubner, M. F. Macromolecules 1995, 28, 7107. (34) Schoeler, B.; Kumaraswamy, G.; Caruso, F. Macromolecules 2002, 35, 889. (35) Decher, G. Science 1997, 277, 1232. (36) Caruso, F.; Caruso, R. A.; Mohwald, H. Science 1998, 282, 1111. (37) Roy, X.; Sarazin, P.; Favis, B. D. Advanced Materials 2006, 18, 1015. (38) Cheung, J. H.; Stockton, W. B.; Rubner, M. F. Macromolecules 1997, 30, 2712. (39) Fou, A. C.; Rubner, M. F. Macromolecules 2002, 28, 7115. (40) Kim, H. S.; Sohn, B. H.; Lee, W.; Lee, J. K.; Choi, S. J.; Kwon, S. J. Thin Solid Films 2002, 419, 173. (41) Liang, Z.; Cabarcos, O. M.; Allara, D. L.; Wang, Q. Advanced Materials 2004, 16, 823. (42) Ram, M. K.; Salerno, M.; Adami, M.; Faraci, P.; Nicolini, C. Langmuir 1999, 15, 1252. (43) Ferreira, M.; Cheung, J. H.; Rubner, M. F. Thin Solid Films 1994, 244, 806. (44) Dautzenberg, H.; Jaeger, W.; Kotz, J.; Phillip, B.; C., S.; Stscherbina, D. Carl Hanser Verlag: Munich, Germany 1994. (45) Harris, J. J.; Bruening, M. L. Langmuir 2000, 16, 2006. (46) Dubas, S. T.; Schlenoff, J. B. Macromolecules 2001, 34, 3736. (47) Braga, G. S.; Paterno, L. G.; Lima, J. P. H.; Fonseca, F. J.; <strong>de</strong> Andra<strong>de</strong>, A. M. Materials Science and Engineering C 2008, 28, 555. (48) Paloheimo, J.; Laakso, K.; Isotalo, H.; Stubb, H. Synthetic Metals 1995, 68, 249. (49) Reignier, J.; Favis, B. D. Macromolecules 2000, 33, 6998. (50) Yasuda, K.; Armstrong, R.; Cohen, R. Rheologica Acta 1981, 20, 163. (51) Virgilio, N.; Favis, B. D.; Pepin, M.-F.; Desjardins, P.; L'Esperance, G. Macromolecules 2005, 38, 2368. 170
(52) Guo, H. F.; Packirisamy, S.; Gvozdic, N. V.; Meier, D. J. Polymer 1997, 38, 785. (53) Ravati, S.; Favis, B. D. Macromolecules 2010, Submitted. (54) Li, J.; Ma, P. L.; Favis, B. D. Macromolecules 2002, 35, 2005. (55) Li, J.; Favis, B. D. Polymer 2001, 42, 5047. (56) Klitzing, R. v.; Espert, A.; Asnacios, A.; Hellweg, T.; Colin, A.; Langevin, D. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1999, 149, 131. (57) Picart, C.; Lavalle, P.; Hubert, P.; Cuisinier, F. J. G.; Decher, G.; Schaaf, P.; Voegel, J. C. Langmuir 2001, 17, 7414. (58) Dubas, S. T.; Schlenoff, J. B. Langmuir 2001, 17, 7725. (59) Tjipto, E.; Quinn, J. F.; Caruso, F. Journal of Polymer Science, Part A (Polymer Chemistry) 2007, 45, 4341. (60) Lavalle, P.; Gergely, C.; Cuisinier, F. J. G.; Decher, G.; Schaaf, P.; Voegel, J. C.; Picart, C. Macromolecules 2002, 35, 4458. (61) Schlenoff, J. B.; Dubas, S. T. Macromolecules 2001, 34, 592. (62) Ha, B. Y.; Thirumalai, D. Macromolecules 1995, 28, 577. (63) Klitzing, R.; Moehwald, H. Langmuir 1995, 11, 3554. (64) Jaber, J. A.; Schlenoff, J. B. Langmuir 2007, 23, 896. (65) Solonin, S. M.; Chernyshev, L. I. Soviet Pow<strong>de</strong>r Metallurgy and Metal Ceramics (English translation of Poroshkovaya Metallurgiya) 1975, 14, 806. (66) Montes, J. M.; Cuevas, F. G.; Rodriguez, J. A.; Herrera, E. J. Pow<strong>de</strong>r Metallurgy 2005, 48, 343. (67) Lifshitz, E. M.; Landau, L. D.; Pitaevskii, L. P. Electrodynamics of Continuous Media, 1984; Vol. 8. (68) Skorokhov, V. V. The Rheological Principles of Sintering Theory; Nauka: Kiev, 1972. (69) Ravati, S., <strong>École</strong> <strong>Polytechnique</strong> <strong>de</strong> <strong>Montréal</strong>, 2010. 171
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© Sepehr Ravati, 2010. UNIVERSITÉ
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DEDICATED To my parents iii
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RÉSUMÉ Cette thèse présente, po
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devenir une structure hiérarchique
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ABSTRACT This thesis presents, for
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system can be increased from 10 -15
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CONDENSÉ EN FRANÇAIS Dans ce trav
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deuxième coquille de PS. Les phase
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structures à percolation multiple
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autre sous-type de morphologie dans
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TABLE OF CONTENTS DEDICATION.......
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xxiii 2.4.1.1.1 Charged Polymer Ads
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5.3.4 Annealing Test ..............
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xxvii REFERENCES ..................
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LIST OF FIGURES xxix Figure 1-1. a)
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Figure 2-12. SEM photomicrograph of
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Figure 2-34. Schematic view of diff
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Figure 4-8. SEM micrographs of vari
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Figure 5-6. a),b) Scanning electron
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and c) triangular concentration dia
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n number of moles p concentration o
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AFM atomic force microscopy LIST OF
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PS-co-PMMA copolymer of PS and PMMA
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1.1 Introduction CHAPTER 1 - INTROD
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Figure 1-2. Human heart, longitudin
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One of the applications for porous
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On the other hand, a novel tri-cont
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2.1 Polymer Blends CHAPTER 2 - LITE
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Based on Sterling’s approximation
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Antonoff’s rule (Equation 2-13) i
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2.1.2.1 Binary Polymer Blends 2.1.2
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Some other studies(Everaert, Aerts,
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where the parameter z is dependent
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“compatibilization” was suggest
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a) λ BC A and B are matrices, b) C
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Reignier & Favis, 2000, 2003a; Reig
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measure the interfacial tension of
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a) b) Figure 2-6. Dependence of the
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Omonov et al. found double percolat
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2.1.2.2.3 Effect of Composition on
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a) b) C B A c) Figure 2-12. SEM pho
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In the case where PS is the matrix,
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Posthuma de Boer, 1999) (Kumin & Ch
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lattice, such as square lattice, wi
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magnetization, which is a function
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Polymers have long been thought of
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epoxy as a function of nanotube wei
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Figure 2-19. Approaching the percol
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Figure 2-21. Transmission electron
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Figure 2-22: Dependence of PE conti
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Figure 2-24. Plot of the total numb
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chain provides the conductive path
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2.3.1.2.1 Polyaniline One of the mo
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CoPA/LLDPE/PANI blend and a poor-qu
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Narkis and co-workers extended and
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Figure 2-31: Conductivity of PVDF/P
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organic thin films, a novel and str
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on the topic have been reported in
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succeeded in creating thin films wi
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Addition of salt to the solution of
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different from that of linear homop
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Figure 2-39. Macromolecule with a)
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polyanion such as hyaluronan (HA)(P
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2.4.1.1.7 Effect of Salt on Multila
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2.4.1.1.8 Overcompensation of the M
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important factors determining the g
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As shown in Figure 2-44, swelling a
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increasing the pH value due to a de
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CHAPTER 3 - ORGANIZATION OF THE ART
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discussed above, HDPE, PS, PMMA, an
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CHAPTER 4 - LOW PERCOLATION THRESHO
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or model which predicts where the p
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concentration threshold for the ons
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chemical and weathering resistance,
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Table 4-1. Material Characteristics
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filled with blend pellets. To facil
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4.3.6 Conductivity Measurements DC
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experimentally in this research gro
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a) b) c) d) Figure 4-4. Schematic i
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microstructure of the quaternary bl
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a) b) c) d) Figure 4-6. SEM microgr
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a) b) PVDF PS PMMA c) d) e) HDPE PS
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- Page 181 and 182: ONION MORPHOLOGY HDPE PVDF PS Contr
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- Page 195 and 196: a) b) c) Figure 5-3. Scanning elect
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- Page 199 and 200: a) b) c) d) e) f) g) h) Figure 5-5.
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- Page 229 and 230: a) c) b) d) e) f) PMMA PMMA HDPE HD
- Page 231 and 232: y Harkins theory, PS will always si
- Page 233 and 234: a) b) c) d) e) f) PS Figure 6-6. a)
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- Page 239 and 240: c) V III II I VII I IV VI Figure 6-
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- Page 243 and 244: Addition of a low concentration of
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- Page 249 and 250: Three examples are shown in Figure
- Page 251 and 252: (9) Mekhilef, N.; Verhoogt, H. Poly
- Page 253 and 254: structures are formed due to the co
- Page 255 and 256: CONCLUSION AND RECOMMENDATIONS In t
- Page 257 and 258: REFERENCES A. K. Gupta, K. R. S. (1
- Page 259 and 260: Caruso, F. (2003). Hollow Inorganic
- Page 261 and 262: Domenech, S. C., Bortoluzzi, J. H.,
- Page 263 and 264: Geuskens, G., Gielens, J. L., Geshe
- Page 265 and 266: Hou, S., Harrell, C. C., Trofin, L.
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Krass, H., Papastavrou, G., & Kurth
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Macdiarmid, A. G., Jin-Chih, C., Ha
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Niziol, J., & Laska, J. (1999). Con
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Reghu, M., Yoon, C. O., Yang, C. Y.
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Shirakawa, H., Louis, E. L., MacDia
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Utracki, L. A. (1991). On the visco
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Yasuda, K., Armstrong, R., & Cohen,
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literature has examined factors inf
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(Reignier & Favis, 2000, 2003a; Rei
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Table A-1.2. Interfacial tensions a
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acquisition of images with a very h
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Table A-1.3. Continuity of the PMMA
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(17) Reignier, J.; Favis, B. D., Ma
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PANI. Theoretically, the extent of
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Equation A-2.7 0( ) 0 1. 5 σ = σ
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Cumulative Mass × 10 5 (g) dipping
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of PANI, and an increase in the con
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Resistance(ohm) 1.0E+12 1.0E+11 1.0
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esistance value. Samples containing
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The results of resistance for PS/PE
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Caruso, F., & Schuler, C. (2000). E