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a) b - École Polytechnique de Montréal

a) b - École Polytechnique de Montréal

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a) b) c)<br />

d) e) f)<br />

PS<br />

Figure 6-6. a) Schematic representations Distance<br />

of bi-continuous/dispersed phase morphology with<br />

small droplets of white phase, b) FIB-AFM image of 50/40/10 HDPE/PS/PMMA showing bicontinuous/dispersed<br />

phase morphology with small droplets of PMMA. Scan size is 8μm×8μm,<br />

(c) FIB-AFM image of 50/25/25 HDPE/PS/PMMA showing bi-continuous/dispersed phase<br />

morphology with droplets of PMMA. Scan size is 4μm×4μm, d) schematic representations of bicontinuous-dispersed<br />

phase morphology with small droplets of black phase, e) FIB-AFM image<br />

of 10/30/60 HDPE/PS/PMMA showing bi-continuous/dispersed phase morphology with<br />

droplets of HDPE. Scan size is 11.7μm×11.7μm, and f) SEM micrograph of 10/30/60<br />

HDPE/PS/PMMA after extraction of PS. Small droplets of HDPE are distributed in PS<br />

Note that in the schematics, black represents the HDPE phase, grey represents the PS phase and<br />

white represents the PMMA phase.<br />

6.4.5 Triangular Composition/Morphology Diagram<br />

Thirty different samples comprised of various compositions of HDPE/PS/PMMA (Figure 6-8a))<br />

were prepared to better un<strong>de</strong>rstand the composition <strong>de</strong>pendance of the various morphological<br />

187

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