29.06.2013 Views

a) b - École Polytechnique de Montréal

a) b - École Polytechnique de Montréal

a) b - École Polytechnique de Montréal

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

⎛ π ⎞<br />

Equation 2-39. Pc = 1−<br />

2Sin⎜<br />

⎟<br />

⎝18⎠<br />

Calculation of Pc for a square lattice was an open question for more than 20 years and was finally<br />

resolved by Harry Kesten. For three-dimensional systems, Pc’s are unknown and cannot be<br />

calculated for now, although the most interesting thing to do is not calculating the Pc.<br />

The percolation threshold has a significant application in universality systems. For example,<br />

Utracki et al.(Utracki, 1991) used the percolation threshold to predict the phase inversion point<br />

based on emulsion theory as follows:<br />

Equation 2-40.<br />

η ⎛φm<br />

φ ⎞<br />

1 − 2 =<br />

η ⎜<br />

φm<br />

φ ⎟<br />

2 ⎝ − 1 ⎠<br />

In this mo<strong>de</strong>l, m and η refer to the volume fraction of the component at percolation threshold<br />

and intrinsic viscosity, respectively.<br />

The universality principle <strong>de</strong>scribes that the value of Pc is connected to the local structure of the<br />

graph, while the behavior of clusters below, at and above Pc are invariants of the local structure,<br />

and therefore, in some sense are more natural quantities to consi<strong>de</strong>r.<br />

2.2.1 Universality Systems<br />

Systems which tend to be chaotic often have a large number of interacting parts. They are called<br />

universality systems. Systems display universality in a scaling limit, when a large number of<br />

interacting parts come together. As a matter of fact, universality originated in the study of phase<br />

transitions in a statistical science, especially in statistical mechanics. The transformation of a<br />

thermodynamic system from one phase to another is a phase transition. When the properties of a<br />

material change in a dramatic way, a phase transition happens. For example, when a magnet is<br />

heated, its magnetism is lost. In this case, the phase transition is characterized by the<br />

[ η ] φm<br />

42

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!